Rubber composition for heavy-load tire, and pneumatic tire
View Patent ↗An object of the present invention is to provide a rubber composition for a heavy-load tire having excellent low heat build-up when formed into a tire and excellent flowability of the rubber during vulcanization, and a pneumatic tire produced using the rubber composition. The rubber composition for a heavy-load tire contains a diene rubber and a carbon black; the diene rubber containing: a natural rubber; and a modified polymer obtained by modifying a conjugated diene polymer with a nitrone compound; the content of the natural rubber in the diene rubber being not less than 60 mass %; and the content of the modified polymer in the diene rubber being not greater than 40 mass %; and the content of the carbon black being from 30 to 70 parts by mass per 100 parts by mass of the diene rubber.
1. A rubber composition for a heavy-load tire comprising a diene rubber and a carbon black;
the diene rubber comprising: a natural rubber; and a modified polymer obtained by modifying a conjugated diene polymer with a nitrone compound having a carboxy group; a content of the natural rubber in the diene rubber being not less than 60 mass %; and a content of the modified polymer in the diene rubber being not greater than 40 mass %; and a content of the carbon black being from 30 to 70 parts by mass per 100 parts by mass of the diene rubber.
2. The rubber composition for a heavy-load tire according to claim 1 , further comprising a silica;
wherein a content of the silica is from 5 to 20 parts by mass per 100 parts by mass of the diene rubber; and a total content of the carbon black and the silica is from 35 to 70 parts by mass per 100 parts by mass of the diene rubber.
3. The rubber composition for a heavy-load tire according to claim 1 , wherein a nitrogen adsorption specific surface area of the carbon black is from 60 to 150 [×10 3 m 2 /kg].
4. A rubber composition for a heavy-load tire according to claim 1 , further comprising a thermoplastic resin, a content of the thermoplastic resin being from 0.1 to 10 parts by mass per 100 parts by mass of the diene rubber.
5. The rubber composition for a heavy-load tire according to claim 1 , wherein
the nitrone compound having a carboxy group is a compound selected from the group consisting of N-phenyl-α-(4-carboxyphenyl)nitrone, N-phenyl-α-(3-carboxyphenyl)nitrone, N-phenyl-α-(2-carboxyphenyl)nitrone, N-(4-carboxyphenyl)-α-phenylnitrone, N-(3-carboxyphenyl)-α-phenylnitrone, and N-(2-carboxyphenyl)-α-phenylnitrone.
6. The rubber composition for a heavy-load tire according to claim 1 , wherein a degree of modification of the modified polymer is from 0.02 to 4.0 mol %, wherein the degree of modification represents a proportion (mol %) of double bonds modified with the nitrone compound relative to all double bonds originating from conjugated diene of the conjugated diene polymer.
7. A tire tread comprising the rubber composition for a heavy-load tire according to claim 1 .
8. A pneumatic tire comprising the rubber composition for a heavy-load tire described in claim 1 .
9. The rubber composition for a heavy-load tire according to claim 2 , wherein a nitrogen adsorption specific surface area of the carbon black is from 60 to 150 [×10 3 m 2 /kg].
10. A rubber composition for a heavy-load tire according to claim 2 , further comprising a thermoplastic resin, a content of the thermoplastic resin being from 0.1 to 10 parts by mass per 100 parts by mass of the diene rubber.
11. A rubber composition for a heavy-load tire according to claim 3 , further comprising a thermoplastic resin, a content of the thermoplastic resin being from 0.1 to 10 parts by mass per 100 parts by mass of the diene rubber.
12. A rubber composition for a heavy-load tire according to claim 9 , further comprising a thermoplastic resin, a content of the thermoplastic resin being from 0.1 to 10 parts by mass per 100 parts by mass of the diene rubber.
13. The rubber composition for a heavy-load tire according to claim 2 , wherein
the nitrone compound having a carboxy group is a compound selected from the group consisting of N-phenyl-α-(4-carboxyphenyl)nitrone, N-phenyl-α-(3-carboxyphenyl)nitrone, N-phenyl-α-(2-carboxyphenyl)nitrone, N-(4-carboxyphenyl)-α-phenylnitrone, N-(3-carboxyphenyl)-α-phenylnitrone, and N-(2-carboxyphenyl)-α-phenylnitrone.
14. The rubber composition for a heavy-load tire according to claim 3 , wherein
the nitrone compound having a carboxy group is a compound selected from the group consisting of N-phenyl-α-(4-carboxyphenyl)nitrone, N-phenyl-α-(3-carboxyphenyl)nitrone, N-phenyl-α-(2-carboxyphenyl)nitrone, N-(4-carboxyphenyl)-α-phenylnitrone, N-(3-carboxyphenyl)-α-phenylnitrone, and N-(2-carboxyphenyl)-α-phenylnitrone.
15. The rubber composition for a heavy-load tire according to claim 4 , wherein
the nitrone compound having a carboxy group is a compound selected from the group consisting of N-phenyl-α-(4-carboxyphenyl)nitrone, N-phenyl-α-(3-carboxyphenyl)nitrone, N-phenyl-α-(2-carboxyphenyl)nitrone, N-(4-carboxyphenyl)-α-phenylnitrone, N-(3-carboxyphenyl)-α-phenylnitrone, and N-(2-carboxyphenyl)-α-phenylnitrone.
16. The rubber composition for a heavy-load tire according to claim 9 , wherein
the nitrone compound having a carboxy group is a compound selected from the group consisting of N-phenyl-α-(4-carboxyphenyl)nitrone, N-phenyl-α-(3-carboxyphenyl)nitrone, N-phenyl-α-(2-carboxyphenyl)nitrone, N-(4-carboxyphenyl)-α-phenylnitrone, N-(3-carboxyphenyl)-α-phenylnitrone, and N-(2-carboxyphenyl)-α-phenylnitrone.
17. The rubber composition for a heavy-load tire according to claim 10 , wherein
the nitrone compound having a carboxy group is a compound selected from the group consisting of N-phenyl-α-(4-carboxyphenyl)nitrone, N-phenyl-α-(3-carboxyphenyl)nitrone, N-phenyl-α-(2-carboxyphenyl)nitrone, N-(4-carboxyphenyl)-α-phenylnitrone, N-(3-carboxyphenyl)-α-phenylnitrone, and N-(2-carboxyphenyl)-α-phenylnitrone.
18. The rubber composition for a heavy-load tire according to claim 11 , wherein
the nitrone compound having a carboxy group is a compound selected from the group consisting of N-phenyl-α-(4-carboxyphenyl)nitrone, N-phenyl-α-(3-carboxyphenyl)nitrone, N-phenyl-α-(2-carboxyphenyl)nitrone, N-(4-carboxyphenyl)-α-phenylnitrone, N-(3-carboxyphenyl)-α-phenylnitrone, and N-(2-carboxyphenyl)-α-phenylnitrone.
19. The rubber composition for a heavy-load tire according to claim 12 , wherein
the nitrone compound having a carboxy group is a compound selected from the group consisting of N-phenyl-α-(4-carboxyphenyl)nitrone, N-phenyl-α-(3-carboxyphenyl)nitrone, N-phenyl-α-(2-carboxyphenyl)nitrone, N-(4-carboxyphenyl)-α-phenylnitrone, N-(3-carboxyphenyl)-α-phenylnitrone, and N-(2-carboxyphenyl)-α-phenylnitrone.
20. The rubber composition for a heavy-load tire according to claim 2 , wherein a degree of modification of the modified polymer is from 0.02 to 4.0 mol %, wherein the degree of modification represents a proportion (mol %) of double bonds modified with the nitrone compound relative to all double bonds originating from conjugated diene of the conjugated diene polymer.