Process for the co-production of acetic acid and dimethyl ether
View Patent ↗Catalytic dehydration-hydrolysis process for the co-production of acetic acid and dimethyl ether from a mixture of methanol and methyl acetate and water in which the amount of water fed to the process is controlled by the steps of dehydrating a methanol feed to provide a crude product containing dimethyl ether, unconverted methanol and water, recovering therefrom a stream containing dimethyl ether, water and methanol and a water stream and separating dimethyl ether from the dimethyl-ether containing stream to produce a methanol stream containing methanol and water. At least part of the methanol stream and methyl acetate is supplied to the dehydration-hydrolysis process.
1. A process for the co-production of acetic acid and dimethyl ether by dehydration-hydrolysis of a mixture of methanol and methyl acetate carried out at a temperature of 100 to 350° C. and at atmospheric or greater pressure in the presence of at least one solid acid catalyst and water to generate a reaction product comprising dimethyl ether and acetic acid in which process the amount of water to the dehydration-hydrolysis is controlled by:
dehydrating a methanol feed comprising methanol and water to generate a crude dehydration product comprising dimethyl ether, unconverted methanol and water
recovering from the crude dehydration product i) a dimethyl ether stream comprising dimethyl ether, water and methanol and ii) a water stream;
separating dimethyl ether from the dimethyl ether stream to produce a methanol stream comprising methanol and water; and
supplying to the dehydration-hydrolysis reaction the methanol stream or a part thereof, methyl acetate and optionally one or more recycle streams comprising one or more of methanol, methyl acetate and water.
2. A process according to claim 1 wherein recovery of the water stream from the crude dehydration product is carried out by fractional distillation in a single distillation column equipped with a reboiler to recover the dimethyl ether stream as a heads product from the column and the water stream as a base stream from the column.
3. A process according to claim 2 wherein the amount of water recovered as a base stream from the distillation column is controlled by adjusting one or both of reflux ratio and reboiler duty (boil-up ratio) to the column.
4. A process according to claim 2 wherein distillation is carried out at a reflux ratio of from 0.05 to 1.
5. A process according to claim 4 wherein the distillation is carried out at a boil-up ratio of 0.01 to 5.
6. A process according to claim 2 wherein distillation is carried out at a pressure of 5 to 30 barg (500 to 3000 kPa) and at a heads temperature of 120 to 180° C.
7. A process according to claim 1 wherein the water stream recovered from the crude dehydration product comprises 90 mol % or more water.
8. A process according to claim 7 wherein the dimethyl ether stream recovered as a heads product from the column comprises >0 to 60 mol % methanol, 5 to 45 mol % water and the balance dimethyl ether.
9. A process according to claim 1 wherein the methanol feed to dehydration comprises water in an amount of from >0 to 35 mol %.
10. A process according to claim 9 wherein the methanol feed to dehydration comprises 50 to 99 mol % methanol, >0 to 35 mol % water and 0 to 10 mol % dimethyl ether.
11. A process according to claim 1 wherein the methanol feed to dehydration is derived from conversion of a gaseous mixture of carbon monoxide, hydrogen and optionally carbon dioxide in the presence of a methanol synthesis catalyst.
12. A process according to claim 1 wherein the dehydration is conducted as a vapour phase process at a pressure of atmospheric to 30 barg (atmospheric to 3000 kPa) and at a temperature of 100° C. to 450° C.
13. A process according to claim 1 wherein the dehydration is conducted as a liquid phase process at a pressure of 40 to 100 barg (4000 to 10000 kPa) and at a temperature of 140° C. to 210° C.
14. A process according to claim 1 wherein the dehydration of the methanol feed is carried out in the presence of a solid acid catalyst which solid acid catalyst is a zeolite selected from zeolites having a 2-dimensional or 3-dimensional channel system and at least one channel of which has a 10-membered ring.
15. A process according to claim 1 wherein dimethyl ether is separated from the dimethyl ether stream comprising dimethyl ether, water and methanol to produce a methanol stream comprising methanol and water by distillation in a single distillation column.
16. A process according to claim 1 wherein water is introduced to the dehydration-hydrolysis reaction in an amount of 0.1 to 50 mol % based on the total feed of methyl acetate, water and methanol.
17. A process according to claim 1 wherein the solid acid catalyst for the dehydration-hydrolysis reaction is selected from one or more heteropolyacids and salts thereof and zeolites.
18. A process according to claim 1 wherein the process is operated as a continuous process.