Polymeric compositions
Water soluble polymeric compositions are provided including at least one polyanionic polymer component (e.g., a copolymer containing maleic and itaconic repeat units), and at least one high molecular weight component selected from copolymers different than the polyanionic polymer and preferably having dicarboxylic repeat units, and a cellulose or cellulose derivative. The compositions are preferably substantially free of hydrocarbons and can be used to coat solid fertilizers in order to reduce fines.
1. A polymeric composition comprising:
at least one polyanionic polymer component comprising a polymer having maleic, itaconic, and sulfonate repeat units; and
at least one high-molecular-weight component, wherein said at least one high molecular weight component is a copolymer different than said polyanionic polymer, said copolymer comprising dicarboxylate repeat units and repeat units selected from the group consisting of straight or branched chain C2-C12 alkylenes, straight or branched chain C1-C8 alkyl vinyl ethers and mixtures thereof, wherein said copolymer contains at least about 25% by mole fraction of said dicarboxylate repeat units,
wherein said polyanionic polymer component is present at a level of from about 1-80% w/w, and said high-molecular-weight component is present at a level of from about 1-40% w/w,
said composition being soluble in water with a water content of about 15-75% w/w.
2. The composition of claim 1 , said composition having a solids content of from about 25-85% w/w.
3. The composition of claim 1 , said polyanionic polymer component being present at a level of from about 5-60% w/w, and said high-molecular-weight component being present at a level of from about 2-20% w/w.
4. The composition of claim 1 , said composition having a hydrocarbon content of no more than about 5% w/w.
5. The composition of claim 1 , said high-molecular-weight component having a viscosity of at least about 100 cps as a 2.0% w/w water solution.
6. The composition of claim 5 , said viscosity being from about 200-2000 cps.
7. The composition of claim 1 , said composition being solubilized in water and having additional ingredients selected from the group consisting of non-aqueous solvents containing hydroxyl groups, mineral particles, biostats, opacifiers, colorants, markers, fillers, pigments, dyes, and compounds to control the freezing point of the composition, and mixtures thereof.
8. The composition of claim 1 , wherein the composition has a viscosity of at least about 200 cps. at 20 ° C., measured as a 1.0% w/w water solution.
9. The composition of claim 1 , wherein the at least one polyanionic polymer component comprises a polymer having maleic, itaconic, and two sulfonate repeat units.
10. The composition of claim 1 , wherein the at least one polyanionic polymer component comprises a tetrapolymer having maleic, itaconic, methallylsulfonic and allylsulfonic repeat units.
11. The composition of claim 1 , wherein the at least one polyanionic polymer component comprises a tetrapolymer having 35-50% maleic; 20-55% itaconic; 1-25% methallylsulfonic acid, and 1-20% allylsulfonic acid repeat units, wherein the total amount of all repeat units in the polymer is taken as 100 mole percent.
12. A polymeric composition comprising:
at least one polyanionic polymer component comprising a polymer having maleic, itaconic and sulfonate repeat units; and
at least one high-molecular-weight component, wherein said at least one high-molecular-weight component is a cellulose or cellulose derivative having at least an average of about 0.9 carboxylate groups per cellulose repeat unit, wherein the cellulose or cellulose derivative has a viscosity of at least about 200 cps. at 20 ° C., measured as a 1.0% w/w water solution,
wherein said polyanionic polymer component is present at a level of from about 1 80% w/w, and said high-molecular-weight component is present at a level of from about 1 40% w/w,
said composition having a viscosity of less than about 1,000 cps at 20 ° C., and
said composition being soluble in water with a water content of about 15-75% w/w.