RESIN PRODUCT
A resin product which has a surface water contact angle of at least 90 and a pencil hardness of at least 8H.
1 . A resin product, wherein a surface of the resin product has a water contact angle of 90 degrees or more and a pencil hardness of 8H or more.
2 . The resin product according to claim 1 , comprising a cured film on a surface.
3 . The resin product according to claim 1 , wherein a residual rate of a cured film by a cross-cut peeling test conducted in conformity to ISO 2409: 1992 is 80% or more.
4 . The resin product according to claim 1 , wherein the resin product is a resin product comprising a cured film (A) on the whole or a portion of a surface of a resin substrate and a cured film (B) on a surface facing a surface in contact with the resin substrate of the cured film (A), and
the surface having a water contact angle of 90 degrees or more and a pencil hardness of 8H or more is a surface of the cured film (B).
5 . A resin product comprising:
a cured film (A) on the whole or a portion of a surface of a resin substrate; and
a cured film (B) on a surface facing a surface in contact with the resin substrate of the cured film (A),
wherein
a surface of the cured film (B) has a water contact angle of 90 degrees or more,
a surface of the cured film (B) has a pencil hardness of 7H or more, and
a residual rate of the cured film (A) and the cured film (B) by a cross-cut peeling test conducted in conformity to ISO 2409: 1992 is 80% or more.
6 . The resin product according to claim 4 , wherein the resin product satisfies the following Equations (1) and (2):
3≦ At/Bt≦ 80 (1)
20 μm≦ At≦ 40 μm (2)
wherein At denotes the thickness of the cured film (A) and Bt denotes the thickness of the cured film (B).
7 . The resin product according to claim 1 , wherein a water contact angle decreasing rate calculated by the following Equation (3-1) after a surface of the resin product is excoriated back and forth 1000 times with a paper wiper at a pressure of 110 g/cm2 is 10% or less:
water contact angle decreasing rate(%)=( A 1− B 1)/ A 1×100 (3-1)
where wherein A1 denotes the water contact angle (°) of the surface before excoriation and B1 denotes the water contact angle (°) of the surface after excoriation.
8 . The resin product according to claim 1 , wherein a water contact angle decreasing rate calculated by the following Equation (3-2) after a surface of the resin product is excoriated back and forth 1000 times with #000 steel wool at a pressure of 110 g/cm 2 is 15% or less:
water contact angle decreasing rate(%)=( A 2− B 2)/ A 2×100 (3-2)
where wherein A2 denotes the water contact angle (°) of the surface before excoriation and B2 denotes the water contact angle (°) of the surface after excoriation.
9 . The resin product according to claim 1 , wherein a surface of the resin product has the Martens hardness of 215 N/mm2 or more and nIT calculated by the following Equation (4) is 70% or more.
nIT (%)=(workload of elastic deformation)/(workload of elastic deformation+workload of plastic deformation)×100 (4),
10 . The resin product according to claim 1 , wherein a surface of the resin product has a triolein contact angle of 50 degrees or more.
11 . The resin product according to claim 1 , wherein a surface of the resin product has a water contact angle of 100 degrees or more.
12 . The resin product according to claim 1 , wherein the resin product has antireflection performance.
13 . The resin product according to claim 4 , wherein the cured film (B) is a cured film (B) obtained by curing a curable composition (b) comprising a compound (b1) having a (meth)acryloyloxy group in the molecule, a fluorine-containing compound (b2) having an active energy ray reactive group, and a polymerization initiator (b4).
14 . The resin product according to claim 13 , wherein the compound (b1) having a (meth)acryloyloxy group in the molecule is a compound having three or more (meth)acryloyloxy groups in the molecule.
15 . The resin product according to claim 13 , wherein the compound (b1) having a (meth)acryloyloxy group in the molecule is urethane (meth)acrylate.
16 . The resin product according to claim 13 , wherein the fluorine-containing compound (b2) having an active energy ray reactive group is a perfluoropolyether (meth)acrylate.
17 . The resin product according to claim 13 , wherein the fluorine-containing compound (b2) having an active energy ray reactive group is from 0.1 to 10 parts by mass with respect to 100 parts by mass of the compound (b1) having a (meth)acryloyloxy group in the molecule.
18 . The resin product according to claim 2 , wherein a residual rate of a cured film by a cross-cut peeling test conducted in conformity to ISO 2409: 1992 is 80% or more.
19 . The resin product according to claim 5 , wherein the resin product satisfies the following Equations (1) and (2):
3≦ At/Bt≦ 80 (1)
20 μm≦ At≦ 40 μm (2)
wherein At denotes the thickness of the cured film (A) and Bt denotes the thickness of the cured film (B).
20 . The resin product according to claim 5 , wherein a water contact angle decreasing rate calculated by the following Equation (3-1) after a surface of the resin product is excoriated back and forth 1000 times with a paper wiper at a pressure of 110 g/cm2 is 10% or less:
water contact angle decreasing rate(%)=( A 1− B 1)/ A 1×100 (3-1)
wherein A1 denotes the water contact angle (°) of the surface before excoriation and B1 denotes the water contact angle (°) of the surface after excoriation.
21 . The resin product according to claim 5 , wherein a water contact angle decreasing rate calculated by the following Equation (3-2) after a surface of the resin product is excoriated back and forth 1000 times with #000 steel wool at a pressure of 110 g/cm 2 is 15% or less:
water contact angle decreasing rate(%)=( A 2− B 2)/ A 2×100 (3-2)
wherein A2 denotes the water contact angle (°) of the surface before excoriation and B2 denotes the water contact angle (°) of the surface after excoriation.
22 . The resin product according to claim 5 , wherein a surface of the resin product has the Martens hardness of 215 N/mm 2 or more and nIT calculated by the following Equation (4) is 70% or more.
nIT (%)=(workload of elastic deformation)/(workload of elastic deformation+workload of plastic deformation)×100 (4).
23 . The resin product according to claim 5 , wherein a surface of the resin product has a triolein contact angle of 50 degrees or more.
24 . The resin product according to claim 5 , wherein a surface of the resin product has a water contact angle of 100 degrees or more.
25 . The resin product according to claim 5 , wherein the resin product has antireflection performance.
26 . The resin product according to claim 5 , wherein the cured film (B) is a cured film (B) obtained by curing a curable composition (b) comprising a compound (b1) having a (meth)acryloyloxy group in the molecule, a fluorine-containing compound (b2) having an active energy ray reactive group, and a polymerization initiator (b4).