Low phosphorus low color polyamides
View Patent ↗The present invention provides a low-phosphorus polyamide compound and a process for preparing such a polyamide.
1. A low-color polyamide comprising:
a phosphorus-containing compound, wherein the phosphorus-containing compound contains 25 to 50 ppm of phosphorus and 1,200 to 1,800 ppm of a carboxylic acid,
where the polyamide has a yellowness index (YI) of −4 to −9,
where the polyamide has a relative viscosity (RV) range of 40 to 80, and
where an amount of phosphorous greater than 50 ppm increases the probability of phosphate plate out in equipment used to prepare or process the polyamide.
2. The polyamide according to claim 1 , wherein the carboxylic acid is selected from the group consisting of acetic acid, propionic acid and benzoic acid.
3. The polyamide according to claim 1 , wherein the phosphorus-containing compound is hypophosphorus acid or a salt thereof.
4. The polyamide according to claim 1 , wherein the polyamide has a RV in a range of 40 to 50.
5. The polyamide according to claim 1 , wherein the polyamide is nylon 6,6.
6. The polyamide according to claim 1 , further comprising at least one selected from the group consisting of glass fibers, waxes, minerals, carbon fibers, chain terminators, viscosity modifiers, plasticizers, heat stabilizers, UV stabilizers, colorants, impact modifiers, flame retardants, delusterants, fillers, antimicrobial agents, antistatic agents and optical brighteners.
7. The polyamide according to claim 1 , further comprising a metal stearate present in an amount of 250 to 1500 ppm on a surface of the polyamide.
8. The polyamide according to claim 7 , wherein the metal stearate is selected from the group consisting of aluminum, iron, lead, lithium, magnesium, sodium and potassium stearates.
9. The polyamide according to claim 7 , wherein the metal stearate is aluminum distearate.
10. An article comprising the polyamide according to claim 1 .