METHODS FOR PREVENTING OR CONTAINING THERMAL RUNAWAY IN A BATTERY PACK
Processes for preventing or containing a thermal runaway event in a battery cell are provided that include localizing an effective amount of a thermally decomposable flame retardant to a target site on a cell or battery, where the flame retardant is localized so as not to coat the entire cell or large portions of the cell. It was discovered that targeted localization of flame retardant material(s) improves cell safety by preventing thermal runaway under adverse operating conditions.
1 . A process for preventing or containing a thermal runaway event in a battery cell comprising:
providing a secondary battery cell comprising a target site comprising a pressure relief feature; and
localizing an effective amount of a thermally decomposable flame retardant to said target site, said localizing exclusive of non-target site regions surrounding said target site or within said cell.
2 . The process of claim 1 wherein said pressure relief feature comprises a vent plug.
3 . The process of claim 1 or 2 wherein said target site is proximate to or surrounding an ignition source.
4 . The process of claim 1 or 2 wherein said target site is intermediate to one or more tabs and one or more electrodes.
5 . The process of claim 1 or 2 wherein said flame retardant is present at 6 percent to 50 percent by weight relative to said cell.
6 . The process of claim 1 or 2 wherein said target site experiences a temperature of 100° C. or greater upon overcharge of greater than 200% the state of charge (SOC).
7 . The process of any one of claim 1 or 2 wherein said cell is a prismatic cell, button cell, pouch cell, or a cylindrical cell.
8 . The process of any one of claim 1 or 2 wherein said thermally decomposable flame retardant is capable of decomposing to form a gaseous halogen-bearing species upon reaching a temperature of 200° C. or greater.
9 . The process of any one of claim 1 or 2 wherein said flame retardant is a heat conductor.
10 . A process for measuring thermal runaway in a secondary cell comprising:
localizing a thermally decomposable flame retardant to a target site of a secondary battery cell, said localizing exclusive of non-target site regions surrounding or within said cell;
subjecting said cell to an overcharge condition; and
activating an ignition source to ignite electrolyte vapor produced by said overcharge condition.
11 . The process of claim 10 wherein said flame retardant is localized to a screen or other porous surface suspended above said target area.
12 . The process of claim 10 or 11 wherein said flame retardant is localized to a pressure relief feature on said cell.
13 . The process of any one of claims 10 - 11 wherein said cell is overcharged to greater than 100% SOC.
14 . The process of any one of claims 10 - 11 further comprising wrapping or otherwise containing said cell in a thermally insulating environment.
15 . The process of any one of claims 10 - 11 wherein said cell is a prismatic cell, button cell, pouch cell, or a cylindrical cell.
16 . An apparatus for testing thermal runaway in a battery, said apparatus comprising:
a base
a top plate comprising a passage, said top plate fixedly associated with said base by a plurality of supports, said top plate associated with said base with sufficient force to hold a battery therebetween under conditions of thermal runaway;
a screen suspended at least partially above said top plate above said passage; and
a chimney on said top plate above said passage.
17 . The apparatus of claim 1 axially surrounded by an inner structure.
18 . The apparatus of claim 17 wherein said inner structure is axially surrounded by an outer structure.
19 . The apparatus of claim 18 wherein a space between said inner structure and said outer structure is filled with an insulating material.