Granted Patent B2

US 10,246,583 · App. 15/315,550 · Granted Apr 2, 2019

Abstract

Claims (33)

1. A reinforced polymer composite, the reinforced polymer composite comprising:

a polymer matrix, and

a strengthening agent, the strengthening agent including cellulose nanocrystals (CNC) and a stabilizing agent, wherein the stabilizing agent includes Boehmite nanoclay (Boe); and

wherein the strengthening agent is homogenously dispersed in the polymer matrix.

2. The reinforced polymer composite of claim 1 , wherein the cellulose nanocrystals (CNC) have dimensions of about 3 to 5 nm in width and about 100 to 300 nm in length.

3. The reinforced polymer composite of claim 1 , wherein the cellulose nanocrystals (CNC) are highly crystalline.

4. The reinforced polymer composite of claim 1 , wherein the cellulose nanocrystals (CNC) have a density of about 1.6 g/cm3.

5. The reinforced polymer composite of claim 1 wherein the ratio of cellulose nanocrystals (CNC) to Boehmite nanoclay (Boe) is about 1 to 4.

6. The reinforced polymer composite of claim 1 wherein the polymer matrix is a thermoset polymer matrix and the strengthening agent is added to the thermoset polymer matrix to achieve a mixture of about 2weight percent to about 10 weight percent strengthening agent.

7. A reinforced polymer composite, the reinforced polymer composite comprising:

a polymer matrix, and

a strengthening agent, the strengthening agent including cellulose nanocrystals (CNC) and a stabilizing agent, wherein the stabilizing agent includes Cetyltrimethylammonium Bromide (CTAB) and wherein the ratio of cellulose nanocrystals (CNC) to Cetyltrimethylammonium Bromide (CTAB) is about 8 to 1; and

wherein the strengthening agent is homogenously dispersed in the polymer matrix.

8. The reinforced polymer composite of claim 7 wherein the stabilizing agent further includes Boehmite nanoclay (Boe).

9. The reinforced polymer composite of claim 8 wherein the ratio of cellulose nanocrystals (CNC) to Cetyltrimethylammonium Bromide (CTAB) to Boehmite nanoclay (Boe) is about 8 to 1 to 1.

10. A method for preparing a reinforced polymer composite, the method including:

a first step includes providing an aqueous cellulose nanocrystal (CNC) suspension having a net negative charge;

a second step includes adding an appropriate amount of a stabilizer or a combination of stabilizers to the aqueous cellulose nanocrystal (CNC) suspension to achieve charge neutrality;

a third step includes inducing phase separation by processing the stabilized aqueous cellulose nanocrystal (CNC) suspension through at least one cycle of centrifugation, rinse, and redispersion;

a fourth step includes drying the stabilized cellulose nanocrystal (CNC) mixture;

a fifth step includes powderizing the dried stabilized cellulose nanocrystal (CNC) mixture; and

a sixth step includes adding the powderized dried stabilized cellulose nanocrystal (CNC) mixture to an uncured polymer prior to the addition of a hardener and cured.

11. The method of preparing a reinforced polymer composite of claim 10 , wherein the stabilizer is at least one of Boehmite nanoclay (Boe) and Cetyltrimethylammonium Bromide (CTAB).

12. The method of preparing a reinforced polymer composite of claim 10 , wherein drying the stabilized cellulose nanocrystal (CNC) mixture includes one of freeze drying, spray drying, and solvent drying the cellulose nanocrystal (CNC) mixture until a liquid solvent of the stabilized aqueous cellulose nanocrystal (CNC) suspension is sublimated.

13. The method of preparing a reinforced polymer composite of claim 10 , wherein rinsing the stabilized aqueous cellulose nanocrystal (CNC) suspension in the third step is performed with de-ionized water to remove any unbound stabilizer and maintain charge neutrality in the stabilized aqueous cellulose nanocrystal (CNC) suspension.

14. The method of preparing a reinforced polymer composite of claim 10 , wherein the first step further includes analyzing the aqueous cellulose nanocrystal (CNC) suspension using Dynamic Light Scattering (DLS) to determine the appropriate concentration of stabilizer to add in the second step.

15. A reinforced polymer composite, the reinforced polymer composite comprising:

a polymer matrix, and

a strengthening agent, the strengthening agent including highly crystalline cellulose nanocrystals (CNC) and a stabilizing agent, and wherein the crystalline cellulose nanocrystals (CNC) have dimensions of about 3 to 5 nm in width and about 100 to 300 nm in length and a density of about 1.6 g/cm3 and the stabilizing agent includes Boehmite nanoclay (Boe) and Cetyltrimethylammonium Bromide (CTAB); and

wherein the strengthening agent is homogenously dispersed in the polymer matrix and is added to the polymer matrix to achieve a mixture of about 2 weight percent to about 10 weight percent strengthening agent.

16. The reinforced polymer composite of claim 15 , wherein the the ratio of cellulose nanocrystals (CNC) to Boehmite nanoclay (Boe) is about 1 to 4.

17. The reinforced polymer composite of claim 15 wherein the ratio of cellulose nanocrystals (CNC) to Cetyltrimethylammonium Bromide (CTAB) is about 8 to 1.

18. The reinforced polymer composite of claim 15 wherein the ratio of cellulose nanocrystals (CNC) to Cetyltrimethylammonium Bromide (CTAB) to Boehmite nanoclay (Boe) is about 8 to 1 to 1.

Assignments (11)