Organosiloxane, curable silicone composition, and semiconductor device
An organosiloxane represented by the following general formula; a curable silicone composition comprising: (A) an organopolysiloxane having at least two alkenyl groups in a molecule; (B) an organohydrogenpolysiloxane having at least two silicon atom-bonded hydrogen atoms in a molecule; (C) an adhesion promoter containing the organosiloxane; and (D) a catalyst for hydrosilylation reaction; and a semiconductor device in which a semiconductor element is encapsulated with a cured product of the composition. A novel organosiloxane, a curable silicone composition that contains the novel organosiloxane as an adhesion promoter and that forms a cured product having excellent adhesion to various base materials, and a semiconductor device that is formed by using the composition and that has excellent reliability are provided.
1. An organosiloxane represented by the general formula:
wherein, R 1 are the same or different monovalent hydrocarbon groups each having from 1 to 12 carbons but having no aliphatic unsaturated bond, R 2 is an alkenyl group having from 2 to 12 carbons, R 3 are the same or different alkyl groups each having from 1 to 3 carbons, X is a group represented by the general formula:
wherein, R 1 are the same as those described above, R 4 are the same or different alkylene groups, p is an integer of 0 to 50, and q is 0 or 1,
wherein, m is an integer of 0 to 50, and n is an integer of 1 to 50.
2. The organosiloxane according to claim 1 , wherein R 4 is an ethylene group or a propylene group.
3. An adhesion promoter comprising the organosiloxane according to claim 1 .
4. A curable silicone composition comprising the organosiloxane according to claim 1 as an adhesion promoter.
5. The curable silicone composition according to claim 4 , wherein the curable silicone composition is cured by a hydrosilylation reaction.
6. The curable silicone composition according to claim 5 , the hydrosilylation reaction curable silicone composition comprising:
(A) 100 parts by mass of an organopolysiloxane having at least two alkenyl groups in a molecule;
(B) an organohydrogenpolysiloxane having at least two silicon atom-bonded hydrogen atoms in a molecule, in an amount such that provides from 0.1 to 10 mol of silicon atom-bonded hydrogen atom per 1 mol total of alkenyl groups contained in components (A) and (C);
(C) from 0.1 to 10 parts by mass of an adhesion promoter containing the organosiloxane; and
(D) a catalyst for hydrosilylation reaction, in an amount that is sufficient to promote curing of the composition.
7. The curable silicone composition according to claim 6 , further comprising (E) a hydrosilylation reaction inhibitor, in an amount from 0.0001 to 5 parts by mass of per 100 parts by mass total of components (A) to (D).
8. A semiconductor device comprising a semiconductor element encapsulated with a cured product of the curable silicone composition according to claim 4 .
9. The semiconductor device according to claim 8 , wherein the semiconductor element is a light emitting element.
10. An adhesion promoter comprising the organosiloxane according to claim 2 .