Electrolytic copper foil for lithium secondary battery and lithium secondary battery comprising the same
An electrolytic copper foil for a lithium secondary battery, which is applied as a negative electrode current collector of a lithium secondary battery, wherein when a correlation between a thermal treatment temperature of the electrolytic copper foil for a lithium secondary battery, which corresponds to a variable x, and an elongation increment ratio of the electrolytic copper foil for a lithium secondary battery, which corresponds to a variable y, is expressed as y=ax+b (100≤x≤200) on an x-y two-dimensional graph, the “a” value is in the range of 0.0009 to 0.0610.
1. An electrolytic copper foil for a lithium secondary battery, which is applied as a negative electrode current collector of the lithium secondary battery,
wherein when a correlation between a thermal treatment temperature (° C.) of the electrolytic copper foil, which corresponds to a variable x, and an elongation increment ratio of the electrolytic copper foil, which corresponds to a variable y, is expressed as y=ax+b (100° C.≤x≤200° C.) on an x-y two-dimensional graph, the “a” value is in the range of 0.0009 to 0.0610° C. −1 ,
wherein the elongation increment ratio (y) is defined as follows:
the elongation increment ratio (y)=[elongation of the electrolytic copper foil measured after an accumulative thermal treatment from an initial temperature of 100° C. to the thermal treatment temperature (x)]/[elongation of the electrolytic copper foil measured after a thermal treatment at the initial temperature of 100° C. for 30 minutes],
wherein the correlation is obtained by performing a 5-point thermal treatment which is the accumulative thermal treatment during which the thermal treatment temperature (x) is increased from the initial temperature of 100° C. to 200° C. with an interval of 25° C. and thermal treatment at each thermal treatment temperature (x) is performed for 30 minutes, and
wherein the elongation of the electrolytic copper foil measured after the thermal treatment at the initial temperature of 100° C. for 30 minutes is 3% or above.
2. The electrolytic copper foil for the lithium secondary battery according to claim 1 ,
wherein the electrolytic copper foil for the lithium secondary battery has an anti-corrosion layer containing at least one of chrome (Cr), silane compound and nitride compound, on both surfaces thereof.
3. The electrolytic copper foil for the lithium secondary battery according to claim 1 ,
wherein the electrolytic copper foil for the lithium secondary battery has a thickness of 3 μm to 30 μm.
4. The electrolytic copper foil for the lithium secondary battery according to claim 1 ,
wherein both surfaces of the electrolytic copper foil for the lithium secondary battery have a surface roughness of 3.5 μm or less on the basis of Rz.
5. The lithium secondary battery, to which the electrolytic copper foil for the lithium secondary battery according to claim 1 is applied as a negative electrode current collector.