Thermal conductive compositions having good impact performance
View Patent ↗In various aspects, the disclosure relates to thermally conductive thermoplastic compositions comprising a polymer matrix, an impact modifier composition having a chemically reactive impact modifier, and, optionally, a chemically non-reactive impact modifier, and a thermally conductive filler. The disclosed thermally conductive thermoplastic compositions exhibit good thermal conductivity and improved impact and ductile properties.
1. A thermally conductive thermoplastic composition, comprising:
a. from about 30 wt % to about 80 wt % of a polycarbonate component;
b. from about 0.5 wt % to about 10 wt % of a chemically reactive impact modifier comprising one or more of ethylene-propylene polymer (MAH-g-EPM), ethylene-propylene-diene terpolymer (MAH-g-EPDM), ethylene-octene copolymer (MAH-g-POE), and ethylene-butene copolymer (MAH-g-EBR);
c. from about 10 wt % to about 50 wt % of a thermally conductive inorganic filler; and
d. from greater than 0 wt % to 15 wt % of a chemically non-reactive impact modifier comprising a polycarbonate-siloxane copolymer,
wherein the thermally conductive thermoplastic composition exhibits a through-plane thermal conductivity equal to or greater than 0.4 W/mK, an in-plane thermal conductivity equal to or greater than 1.0 W/mK, and wherein the thermally conductive thermoplastic composition exhibits a notched IZOD impact strength measured accordingly to ASTM D256 higher than that of an identical reference composition in the absence of the chemically reactive impact modifier.
2. The thermally conductive thermoplastic composition of claim 1 , wherein the polycarbonate component comprises a bisphenol A polycarbonate polymer.
3. The thermoplastic polymer blend composition of claim 1 , wherein the thermally conductive inorganic filler comprises one or more of aluminum nitride (AlN), aluminum carbide (Al4C3), aluminum oxide (Al2O3), boron nitride (BN), aluminum oxynitride (AlON), magnesium silicon nitride (MgSiN2), silicon nitride (SiC), silicon nitride (Si3N4), graphite, expanded graphite, graphene, magnesium hydroxide (Mg(OH)2), talc (H2Mg3(SiO3)4), boehmite aluminum hydroxide (γ-AlO(H)), diaspore aluminum hydroxide (α-AlO(OH)), gibbsite aluminum hydroxide (Al(OH)3), calcium carbonate (CaCO3), mica, barium oxide (BaO), barium sulfate (BaSO4), calcium silicate (CaSiO3), zirconium oxide (ZrO2), silicon oxide (SiO2), glass beads, magnesium aluminum oxide (MgO.xAl2O3), calcium magnesium carbonate CaMg(CO3)2, ceramic-coated graphite, clay, zinc sulfide (ZnS), calcium oxide (CaO), magnesium oxide (MgO), zinc oxide (ZnO), and titanium oxide (TiO2).
4. The thermally conductive thermoplastic composition of claim 1 , wherein the thermally conductive inorganic filler comprises a high thermally conductivity filler having a thermal conductivity equal to or greater than 50 W/mK.
5. The thermally conductive thermoplastic composition of claim 1 , wherein the thermally conductive inorganic filler comprises a medium thermally conductivity filler having a thermal conductivity in the range from about 10 to about 30 W/mK.
6. The thermally conductive thermoplastic composition of claim 1 , wherein the thermally conductive inorganic filler comprises a low thermally conductivity filler having a thermal conductivity less than about 10 W/mK.
7. The thermally conductive thermoplastic composition of claim 1 , wherein the thermally conductive inorganic filler is talc, boron nitride, or graphite.
8. The thermally conductive thermoplastic composition of claim 1 , wherein the thermally conductive inorganic filler is present in particulate form, fibrous form, or a combination thereof.
9. The thermally conductive thermoplastic composition of claim 1 , further comprising a reinforcing filler comprising one or more of titanium dioxide, clay, mica, glass fiber, and carbon fiber.
10. The thermally conductive thermoplastic composition of claim 1 , further comprising from greater than 0 to about 2 wt % of one or more of antioxidant, thermal stabilizer, flow promoter, mold release agent, colorants, pigments or any combination thereof.
11. An article formed from the thermally conductive thermoplastic composition of claim 1 .
12. A method of making a thermally conductive thermoplastic composition, comprising:
mixing together a polycarbonate component, a chemically reactive impact modifier comprising one or more of ethylene-propylene polymer (MAH-g-EPM), ethylene-propylene-diene terpolymer (MAH-g-EPDM), ethylene-octene copolymer (MAH-g-POE), and ethylene-butene copolymer (MAH-g-EBR), a thermally conductive inorganic filler, and from greater than 0 wt % to 15 wt % of a chemically non-reactive impact modifier comprising a polycarbonate-siloxane copolymer to create a mixture that does not exceed 100 wt %,
wherein all weight percent values are based on the total weight of the composition, and wherein the thermally conductive thermoplastic composition exhibits a through-plane thermal conductivity equal to or greater than 0.4 W/mK, an in-plane thermal conductivity equal to or greater than 1.0 W/mK, and the formed thermally conductive thermoplastic composition exhibits a notched IZOD impact strength measured accordingly to ASTM D256 higher than that of an identical reference composition in the absence of the chemically reactive impact modifier.
13. A method of making a thermally conductive thermoplastic composition, comprising:
mixing together from about 30 wt % to about 80 wt % of a polycarbonate component, from about 0.5 wt % to about 10 wt % of a chemically reactive impact modifier comprising one or more of ethylene-propylene polymer (MAH-g-EPM), ethylene-propylene-diene terpolymer (MAH-g-EPDM), ethylene-octene copolymer (MAH-g-POE), and ethylene-butene copolymer (MAH-g-EBR), from about 10 wt % to about 50 wt % of a thermally conductive inorganic filler, and from greater than 0 wt % to 15 wt % of a chemically non-reactive impact modifier comprising a polycarbonate-siloxane copolymer to create a mixture that does not exceed 100 wt %,
wherein all weight percent values are based on the total weight of the composition, and wherein the thermally conductive thermoplastic composition exhibits a through-plane thermal conductivity equal to or greater than 0.4 W/mK, an in-plane thermal conductivity equal to or greater than 1.0 W/mK, and the formed thermally conductive thermoplastic composition exhibits a notched IZOD impact strength measured accordingly to ASTM D256 higher than that of an identical reference composition in the absence of the chemically reactive impact modifier.