Toner for developing electrostatic latent image
View Patent ↗Disclosed is a toner for developing an electrostatic latent image, the toner comprising a plurality of toner particles, each toner particle includes: a core particle that contains a binding resin, a coloring agent, and a releasing agent; and an external additive attached to the surface of the core particle, wherein the toner has two endothermic peaks in a heat curve, which is obtained at the time of the secondary temperature rise in differential scanning calorimetry of the toner, and a stepped endothermic curve; and first and second melting temperatures, which are determined to be the locations of vertices of the two endothermic peaks, a glass transition temperature, which is determined to be the midpoint of a linear portion of the stepped endothermic curve, and first and second heat of melting, which are determined to be the areas of the two endothermic peaks, satisfy the condition set forth herein.
1. A toner for developing electrostatic latent images, comprising:
a plurality of toner particles,
each toner particle comprises:
a core particle comprising a binder resin, a colorant, and a releasing agent; and
an external additive adhering to a surface of the core particle, and
wherein the toner exhibits two endothermic peaks and a stepped endothermic curve in a thermogram which is obtained from a secondary temperature rise in differential scanning calorimetry (DSC),
wherein first and second melting temperatures (Tm1 and Tm2) are determined as temperatures at vertices of the two endothermic peaks, respectively, a glass transition temperature (Tg) is determined as a temperature at a midpoint of a linear region of the stepped endothermic curve, and a first heat and a second heat of melting (ΔH1 and ΔH2) are determined as areas of the two endothermic peaks, respectively, and
wherein Tm1, Tm2, Tg, ΔH1 and ΔH2 satisfy the following conditions:
55° C.≤ Tg≤ 65° C. (1)
Tg≤Tm 1≤75° C. (2)
Tm 1≤ Tm 2≤90° C. (3)
0.5<Δ H 1/Δ H 2<1.5 (4).
2. The toner of claim 1 , wherein the first heat of melting ΔH1 and the second heat of melting ΔH2 satisfy the following conditions:
0.1≤Δ H 1≤0.9 J/g (5)
0.1≤Δ H 2≤0.9 J/g (6).
3. The toner of claim 1 , wherein the toner further comprises magnetic carrier particles, wherein an average particle diameter (D50t) of the plurality of toner particles and an average particle diameter (D50c) of the magnetic carrier particles satisfy the following condition:
0.08≤ D 50 t/D 50 c≤ 0.25 (7)
wherein the average particle diameter (D50t) refers to a particle diameter at 50% of cumulative weight in a cumulative particle diameter distribution curve of the toner particles, and the average particle diameter (D50c) of the magnetic carrier particles refers to a particle diameter at 50% of cumulative weight in a cumulative particle diameter distribution of the magnetic carrier particles.
4. The toner of claim 1 , wherein the external additive comprises a combination of silica particles, titanium oxide particles, and iron oxide particles.
5. The toner of claim 1 , wherein [Si], [Ti], and [Fe] as the intensities of silicon, titanium, and iron measured by X-ray fluorescence spectrometry of the toner satisfy the following conditions:
0.005≤[Si]≤0.2 (8)
1≤[Ti]≤30 (9)
2≤[Fe]≤200 (10).
6. The toner of claim 1 , wherein the releasing agent is a combination of a carnauba-based wax and a fatty acid ester-based wax.
7. The toner of claim 1 , wherein the binder resin is a polyester resin.
8. The toner of claim 1 , wherein the toner is used in a non-magnetic two-component development process.