Encapsulant of a photovoltaic module
An encapsulant of a photovoltaic module, intended for coating a photovoltaic cell ( 10 ), including: a copolymer of ethylene-alkyl acrylate, the melt flow index (MFI) of the copolymer being 1 g/10 min to 40 g/10 min; and a silane making up 0.1% to 0.5% of the weight of the composition; wherein the encapsulant also includes a cross-linking agent making up 0.1% to 0.5% of the weight of the composition and wherein the copolymer makes up at least 99% of the weight of the composition. Also, a use of such an encapsulant in a photovoltaic module as well as to a photovoltaic module including such an encapsulant.
1. An encapsulant composition of a photovoltaic module, configured to encase a photovoltaic cell, the encapsulant composition comprising:
an ethylene/alkyl acrylate copolymer that has a melt flow index, MFI, between 1 g/10 min and 40 g/10 min, wherein the alkyl acrylate is either methyl acrylate or butyl acrylate;
a silane, representing between 0.1% and 0.5% of the weight of said encapsulant composition;
wherein the encapsulant composition additionally comprises a crosslinking agent, wherein the crosslinking agent either is 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane or belongs to the monoperoxycarbonate family and represents between 0.1% and 0.5% of the weight of the encapsulant composition, wherein said copolymer represents at least 99% of the weight of said encapsulant composition, and
wherein the encapsulant composition possesses a creep measurement less than 4 mm when laminated onto a glass structure and heated at 110° C. for 500 hours.
2. The encapsulant composition as claimed in claim 1 wherein, for the above said copolymer, the weight content of ethylene is between 50% and 85%, and the weight content of alkyl acrylate is between 15% and 50%.
3. The encapsulant composition as claimed in claim 1 , wherein the silane consists of a vinyl silane or (meth)acrylic silanes.
4. The encapsulant composition as claimed in claim 3 , wherein the silane consists of 3-(trimethoxysilyl)propyl methacrylate.
5. The encapsulant composition as claimed in claim 1 , wherein the crosslinking agent represents between 0.1% and 0.3% of the weight of the encapsulant composition.
6. The encapsulant composition as claimed in claim 1 , wherein the copolymer has a melt flow index, MFI, between 2 g/10 min and 10 g/10 min.
7. The encapsulant composition as claimed in claim 1 , wherein the encapsulant composition consists of the copolymer, the abovesaid crosslinking agent and the abovesaid silane.
8. The encapsulant composition as claimed in claim 1 , wherein the encapsulant composition additionally comprises additives intended to confer additional specific properties.
9. A photovoltaic module comprising the encapsulant composition as claimed in claim 1 .
10. A photovoltaic module comprising a structure consisting of a combination of at least one encapsulant and a frontsheet or a backsheet, wherein the at least one encapsulant is an encapsulant composition as claimed in claim 1 .
11. The encapsulant composition as claimed in claim 1 , wherein the crosslinking agent in the encapsulant composition produces an incomplete crosslinking.
12. The encapsulant composition as claimed in claim 1 , wherein no acetic acid formation is detected after exposure of said composition to DHT testing, wherein DHT testing occurs at 85° C. in 85% relative humidity for at least 2000 hours.
13. The encapsulant composition as claimed in claim 1 , wherein said encapsulant does not become yellow after exposure of said composition to DHT testing, wherein DHT testing occurs at 85° C. in 85% relative humidity for at least 2000 hours.
14. The encapsulant composition as claimed in claim 1 , wherein the crosslinking agent does not cause bubbles to form during a lamination step.