Flame retardant thermally conductive polymer compositions with good flow property and uses thereof
The invention concerns compositions comprising (a) from about 20 wt % to about 80 wt % of a polymer component; (b) from about 10 wt % to about 70 wt % of a flame retardant component; and (c) from about 0.01 wt % to about 5 wt % of an acid component; wherein the combined weight percent value of all components does not exceed 100 wt %; wherein all weight percent values are based on the total weight of the composition; and wherein the composition has: (i) a thermal conductivity of at least about 1.5 W/mK for through plane thermal conductivity; (ii) flame retardancy of at least VI at 0.8 mm using the UL94 test standard; and (iii) melt volume flow rate of at least 10 g/cm3 using ASTM D 1238.
1. A composition comprising:
a. from about 20 wt % to about 80 wt % of a polymer component;
b. from about 15 wt % to about 70 wt % of a flame retardant component, wherein the flame retardant component comprises Mg(OH) 2 , H 2 Mg 3 (SiO 3 ) 4 , y-AlO(OH), a-AlO(OH), or Al(OH) 3 , or a combination thereof; and
c. from about 0.01 wt % to about 5 wt % of an acid component, wherein the acid component comprises phosphorous acid, boric acid, aluminum diethyl phosphinic acid, or zinc phosphate, or a combination thereof;
wherein the combined weight percent value of all components does not exceed 100 wt %;
wherein all weight percent values are based on the total weight of the composition; and
wherein the composition has:
i. a thermal conductivity of at least about 0.5 W/mK for through plane thermal conductivity;
ii. flame retardancy of at least V1 at 3 mm using the UL94 test standard; and
iii. melt volume flow rate of at least 5 cm 3 /10 min using ASTM D 1238.
2. The composition of claim 1 , wherein the polymer component is present in an amount from about 30 wt % to about 50 wt %.
3. The composition of claim 1 , wherein the flame retardant component is present in an amount from about 50 wt % to about 60 wt %.
4. The composition of claim 1 , wherein the acid component is present in an amount from about 0.1 wt % to about 1 wt %.
5. The composition of claim 1 , wherein the composition has a thermal conductivity (TC) of at least about 1.5 W/mK for through plane thermal conductivity.
6. The composition of claim 1 , wherein the composition has flame retardancy of at least V1 at about 0.8 mm using the UL94 test standard.
7. The composition of claim 1 , wherein the composition has flame retardancy of V0 at about 0.8 mm using the UL94 test standard.
8. The composition of claim 1 , wherein the composition has melt volume flow rate (MVR) of at least 10 cm 3 /10 min using ASTM D 1238.
9. The composition of claim 1 , further comprising from greater than 0 wt % to about 5 wt % of a char-forming agent comprising one or more of an organopolysiloxane and a polydimethylsiloxane.
10. The composition of claim 1 , further comprising from greater than 0 wt % to about 2 wt % of an anti-flame dripping agent, wherein the anti-flame dripping agent comprises multi-functional modified styrene-acrylic oligomers; multi-functional amino or carboxyl chain extenders; a mixture of poly(tetrafluoroethylene) and poly(stryrene-acrylonitrile); or a combination thereof.
11. The composition of claim 1 , further comprising from greater than 0 wt % to about 60 wt % of a filler, wherein the filler comprises AlN, Al 4 C 3 , Al 2 O 3 , BN, AlON, MgSiN 2 , SiC, Si 3 N 4 , graphite, expanded graphite, graphene, carbon fiber; ZnS, CaO, MgO, ZnO, TiO 2 , CaCO 3 , mica, BaO, BaSO 4 , CaSiO 3 , ZrO 2 , SiO 2 , glass beads, glass fiber, MgO.xAl 2 O 3 , CaMg(CO 3 ) 2 , ceramic-coated graphite, or a clay; or a combination thereof.
12. The composition of claim 1 , wherein the polymer component comprises a polypropylene, polyethylene, ethylene based copolymer, polycarbonate, polyamide, polyester, polybutylene terephthalate, polyethylene terephthalate, polycyclohexylenedimethylene terephthalate, liquid crystal polymers, polyphenylene sulfide, polyphenylene ether, polyphenylene oxide-polystyrene blends, polystyrene, high impact modified polystyrene, acrylonitrile-butadiene-styrene terpolymer, acrylic polymer, polyetherimide, polyurethane, polyetheretherketone, poly ether sulphone, or a combination thereof.
13. An article formed from the composition of claim 1 .
14. A method comprising, producing a composition by mixing:
a. from about 20 wt % to about 80 wt % of a polymer component;
b. from about 15 wt % to about 70 wt % of a flame retardant component, wherein the flame retardant component comprises Mg(OH) 2 , H 2 Mg 3 (SiO 3 ) 4 , y-AlO(OH), a-AlO(OH), or Al(OH) 3 , or a combination thereof; and
c. from about 0.01 wt % to about 5 wt % of an acid component, wherein the acid component comprises phosphorous acid, boric acid, aluminum diethyl phosphinic acid, or zinc phosphate, or a combination thereof;
wherein the combined weight percent value of all components does not exceed 100 wt %;
wherein all weight percent values are based on the total weight of the composition; and
wherein the composition has:
i. a thermal conductivity of at least about 0.5 W/mK for through plane thermal conductivity;
ii. flame retardancy of at least V1 at 3 mm using the UL94 test standard; and
iii. melt volume flow rate of at least 5 cm 3 /10 min using ASTM D 1238.
15. The method of claim 14 , wherein the acid component comprises phosphorous acid or boric acid, or both and is present in an amount from about 0.1 wt % to about 1 wt %.
16. The method of claim 14 , wherein the composition has a thermal conductivity (TC) of at least about 1.5 W/mK for through plane thermal conductivity.
17. The method of claim 14 , wherein the composition has flame retardancy of at least V1 at about 0.8 mm using the UL94 test standard and a melt volume flow rate (MVR) of at least 10 cm 3 /10 min using ASTM D 1238.