Hot melt silicone and curable hot melt composition
A hot melt silicone that is non-flowable at 25° C. and that has a melt viscosity at 100° C. of 5,000 Pa·s or less, the hot melt silicone being formed by subjecting (A) an alkenyl group-containing organopolysiloxane in which 10 mol % or greater of all of silicon atom-bonded organic groups is a phenyl group, and (B) an organopolysiloxane having at least two silicon atom-bonded hydrogen atoms in a molecule to hydrosilylation reaction in the presence of (C) a hydrosilylation reaction catalyst; and a curable hot melt composition comprising: (I) the hot melt silicone; (II) an organopolysiloxane which has at least two silicon atom-bonded hydrogen atoms in a molecule and in which the amount of silicon atom-bonded hydrogen atom is 0.5 mass % or greater; and (III) a hydrosilylation reaction catalyst. The hot melt silicone is non-flowable at 25° C., has a low surface stickiness, and easily melts by heating. Furthermore, this curable hot melt composition has both hot melt properties and curability.
1. A curable hot melt composition comprising: (I) a hot melt silicone; (II) an organopolysiloxane which has at least two silicon atom-bonded hydrogen atoms in a molecule and in which an amount of silicon atom-bonded hydrogen atom is 0.5 mass % or greater, in an amount such that an amount of the silicon atom-bonded hydrogen atom in component (II) is from 0.5 to 2.0 mol per 1 mol of alkenyl group in component (I); and (III) a hydrosilylation reaction catalyst,
wherein component (I) is non-flowable at 25° C. and has a melt viscosity at 100° C. of 5,000 Pa·s or less, and is formed by subjecting (A) an alkenyl group-containing organopolysiloxane in which 10 mol % or greater of all of silicon atom-bonded organic groups is a phenyl group, and (B) an organopolysiloxane having at least two silicon atom-bonded hydrogen atoms in a molecule, in an amount such that an amount of the silicon atom-bonded hydrogen atoms in component (B) is from 0.2 to 0.7 mol per 1 mol of alkenyl group in component (A), to hydrosilylation reaction in the presence of (C) a hydrosilylation reaction catalyst, in an amount that is sufficient to promote the hydrosilylation reaction of components (A) and (B).
2. The curable hot melt composition according to claim 1 , wherein component (II) is an organopolysiloxane represented by the average composition formula:
R 7 n H o SiO (4-n-o)/2
wherein, R 7 is independently a halogen-substituted or unsubstituted monovalent hydrocarbon group having no aliphatic unsaturated bond, n is a number of 1.0 to 2.5, o is a number of 0.5 to 1.5, and n+o is a number of 1.5 to 3.0.
3. The curable hot melt composition according to claim 1 , further comprising a hydrosilylation reaction inhibitor in an amount of 0.0001 to 5 parts by mass per 100 parts by mass total of components (I) and (II).
4. The curable hot melt composition according to claim 1 , wherein a type D durometer hardness at 25° C. of a cured product obtained by curing the curable hot melt composition is 10 or greater.
5. The curable hot melt composition according to claim 1 , wherein component (I) has a melt viscosity at 50° C. of 3,000 Pa·s or greater.
6. The curable hot melt composition according to claim 1 , wherein component (I) has a melt viscosity at 50° C. greater than or equal to 20 times a melt viscosity at 100° C.
7. The curable hot melt composition according to claim 1 , wherein component (A) is an organopolysiloxane represented by the average composition formula:
R 1 a SiO (4-a)/2
wherein, le is independently a halogen-substituted or unsubstituted monovalent hydrocarbon group, with the proviso that 10 mol % or greater of all le is a phenyl group and at least two of le are alkenyl groups, and a is a number of 0.5 to 2.5.
8. The curable hot melt composition according to claim 7 , wherein component (A) comprises
(A-1) an organopolysiloxane represented by the average unit formula:
(R 2 3 SiO 1/2 ) b (R 2 2 SiO 2/2 ) c (R 2 SIO 3/2 ) d (SIO 4/2 ) e (R 3 O 1/2 ) f
wherein, R 2 are the same or different, halogen-substituted or unsubstituted monovalent hydrocarbon groups, R 3 is a hydrogen atom or an alkyl group, b is a number of 0 to 0.7, c is a number of 0 to 0.7, d is a number of 0 to 0.9, e is a number of 0 to 0.7, f is a number of 0 to 0.1, and d+e is a number of 0.3 to 0.9, and b+c+d+e is 1; and
(A-2) an organopolysiloxane represented by the average unit formula:
(R 4 3 SiO 1/2 ) g (R 4 2 SiO 2/2 ) h (R 4 SiO 3/2 ) i (SiO 4/2 ) j (R 5 O 1/2 ) k
wherein, R 4 are the same or different, halogen-substituted or unsubstituted monovalent hydrocarbon groups, R 5 is a hydrogen atom or an alkyl group, g is a number of 0.01 to 0.3, h is a number of 0.4 to 0.99, i is a number of 0 to 0.2, j is a number of 0 to 0.2, k is a number of 0 to 0.1, and i+j is a number of 0 to 0.2, and g+h+i+j is 1;
wherein a mass ratio of component (A-1) : component (A-2) is from 50:50 to 100:0.
9. The curable hot melt composition according to claim 1 , wherein component (B) is an organopolysiloxane represented by the average composition formula:
R 6 l H m SiO (4-l-m)/2
wherein, R 6 is a halogen-substituted or unsubstituted monovalent hydrocarbon group, I is a number of 1.0 to 2.5, m is a number of 0.01 to 0.9, and I+m is a number of 1.5 to 3.0.