Mill blanks based on a polymerized, fracture-tough prosthesis material
The subject matter of the invention is a three-dimensional molded body, in particular a milling blank, made of a polymerizable prosthetic material, which is suitable for milling machining by means of CNC and/or CAD/CAM, having a fracture toughness of greater than or equal to 1.9 Mpa·m 1/2 and a fracture work of greater than or equal to 900 J/m 2 . The milling blank preferably comprises core-shell particles modified by an elastic phase and is optionally based on a content of urethane (meth)acrylate polymerized into the polymer. Moreover, a subject matter of the invention is the use of the milling blanks for the production of at least parts of dental prosthetic parts, such as a prosthesis, artificial teeth, bridges, or of orthodontic appliances and instruments in medical field.
1. Milling blank made of polymeric prosthetic material,
wherein the prosthetic material is present in the form of a three-dimensional moulded body, optionally being suitable for ablative machining, suitable as a CAD/CAM (computer-aided design/computer-aided manufacturing) milling blank, wherein the moulded body comprises (A) at least one polymer comprising 0.001 to 10% by weight of the moulded body of at least one urethane acrylate or urethane methacrylate polymerized into the polymer and (B) 0.001 to 10% by weight of the moulded body of core-shell particles modified by at least one elastic phase, whereby the moulded body has a fracture toughness of ≥1.9 Mpa m 1/2 and a total fracture work of ≥900 J/m 2 .
2. Milling blank according to claim 1 , wherein the core-shell particles comprise primary particles, whereby the primary particle size has an average particle size of less than or equal to d 50 ≤500 nm to 10 nm.
3. Milling blank according to claim 1 , wherein the core-shell particles comprise aggregates of primary particles, whereby the aggregates have an average particle size of less than or equal to (d 50 ) 400 μm (micrometers).
4. Milling blank according to claim 1 , wherein the distribution of the elastic phase in the modified core-shell particles is selected from possibilities a to d:
a) elastic phase as core in solid outer shell (core-shell-particles);
b) multiple elastic phases as cores in a solid matrix;
c) core-shell particles from a) distributed in solid matrix, and
d) solid core with elastic phase as outer shell.
5. Milling blank according to claim 1 , wherein the unpigmented prosthetic material has a transparency of greater than or equal to 90% (measured against plates having a height of 3 mm).
6. Milling blank according to claim 1 , which additionally comprises one or more substance(s) from the group consisting of fillers, pigments, stabilizers, regulators, antimicrobial additives, UV-absorbing agents, thixotroping agents, catalysts and crosslinkers.
7. Milling blank according to claim 1 , which is single-coloured in tooth colours or is colour-adjusted to the gingiva, or the milling blank is designed multi-coloured, wherein defined areas are designed tooth-coloured and/or defined areas are designed colour-adjusted to the gingiva.
8. Milling blank according to claim 1 , which comprises greater than or equal to 55% by weight PMMA (polymethylmethacrylate), based on the total composition.