Nitrogen-containing compounds suitable for use in the production of polyurethanes
The present invention provides for the use of nitrogen compounds of formula (I) and/or of corresponding quaternized and/or protonated compounds for production of polyurethanes, compositions containing these compounds and polyurethane systems, especially polyurethane foams, which have been obtained using the compounds.
1. A process for making a polyurethane comprising (1) mixing in a reaction mixture of a polyisocyanate and a polyol a proportion by mass of from 0.01 to 20 parts (pphp), based on 100 parts (pphp) of polyol component of at least one nitrogen compound, or mixtures of the nitrogen compound with corresponding quaternized and/or protonated compounds, wherein this nitrogen compound satisfies formula (VI),
with n=2-12 except for 4, and (2) a pyrrolidine group selected from the group consisting of 1-(2-hydroxyethyl)pyrrolidine, 1-(2-chloroethyl)pyrrolidine, and 1-(2-(pyrrolidin-1-yl)propoxy)propan-2-ol.
2. The process according to claim 1 , wherein the nitrogen compound of one of the formulae (VI) with n=2, 3 or 6 is used as catalyst in the production of polyurethanes or polyurethane foams.
3. The process according to claim 1 , wherein, in the production of the polyurethane or a polyurethane foam, a composition includes at least one nitrogen compound of the formula (VI) with n=6.
4. The process according to claim 1 , wherein the at least one nitrogen compound of the formula (VI), is used in combination with at least one solvent, where the mass ratio of the total amount of catalyst used, comprising all the catalytically active compounds of the formula (VI) and not of the formula (VI), to solvent is from 100:1 to 1:4.
5. A polyurethane foam obtained through the method according to claim 1 , wherein a finished polyurethane foam is a rigid polyurethane foam, a flexible polyurethane foam, a viscoelastic foam, a cold-cure foam (also called high-resilience (HR) foam), a semirigid polyurethane foam, a thermoformable polyurethane foam or an integral foam.
6. An article comprising the polyurethane foam according to claim 4 wherein the article is selected from the group consisting of refrigerator insulation, insulation panel, sandwich element, pipe insulation, spray foam, 1- and 1.5-pack canned foam, imitation wood, modelling foam, floral foam, packaging foam, mattress, furniture cushion, moldable foam for furniture, pillows, rebonded foam, sponge foam, automobile seat cushion, headrest, dashboard, automobile interior, automobile roof liner, sound absorption material, steering wheel, shoe sole, carpet backing foam, filter foam, sealing foam, sealant and adhesive.
7. A process for making a polyurethane comprising (1) mixing in a reaction mixture of a polyisocyanate and a polyol a proportion by mass of from 0.01 to 20 parts (pphp), based on 100 parts (pphp) of polyol component, of at least one nitrogen compound, or mixtures of the nitrogen compound with corresponding quaternized and/or protonated compounds, wherein this nitrogen compound satisfies formula (VI),
with n=2-12 except for 4, and
(2) a pyrrolidine group and diethylene glycol, wherein the pyrrolidine group is a reaction product of pyrrolidine with alkyl halides, a reaction product of pyrrolidine with bischloroalkyl ethers, a reaction product of pyrrolidine with epoxides or epoxide-bearing compounds, or a reaction product of pyrrolidine with alcohols and/or polyols.
8. The process according to claim 7 , wherein the pyrrolidine group is selected from the group consisting of 1-(2-hydroxyethyl)pyrrolidine, 1-(2-chloroethyl)pyrrolidine, and 1-(2-(pyrrolidin-1-yl)propoxy)propan-2-ol.
9. The process according to claim 7 , wherein the nitrogen compound of one of the formulae (VI) with n=2, 3 or 6 is used as catalyst in the production of polyurethanes or polyurethane foams.
10. The process according to claim 7 , wherein, in the production of the polyurethane or a polyurethane foam, a composition includes at least one nitrogen compound of the formula (VI) with n=6.
11. The process according to claim 7 , wherein the at least one nitrogen compound of the formula (VI), is used in combination with at least one solvent, where the mass ratio of the total amount of catalyst used, comprising all the catalytically active compounds of the formula (VI) and not of the formula (VI), to solvent is from 100:1 to 1:4.
12. A polyurethane foam obtained through the method according to claim 7 , wherein a finished polyurethane foam is a rigid polyurethane foam, a flexible polyurethane foam, a viscoelastic foam, a cold-cure foam (also called high-resilience (HR) foam), a semirigid polyurethane foam, a thermoformable polyurethane foam or an integral foam.
13. An article comprising the polyurethane foam according to claim 12 wherein the article is selected from the group consisting of refrigerator insulation, insulation panel, sandwich element, pipe insulation, spray foam, 1- and 1.5-pack canned foam, imitation wood, modelling foam, floral foam, packaging foam, mattress, furniture cushion, moldable foam for furniture, pillows, rebonded foam, sponge foam, automobile seat cushion, headrest, dashboard, automobile interior, automobile roof liner, sound absorption material, steering wheel, shoe sole, carpet backing foam, filter foam, sealing foam, sealant and adhesive.