Nonaqueous electrolyte secondary battery
It is an object of the present invention to provide a nonaqueous electrolyte secondary battery in which swelling due to charge-discharge cycling is inhibited. The nonaqueous electrolyte secondary battery including a flat electrode assembly in which a first electrode plate and a second electrode plate having a different polarity from the first electrode plate are wound with a separator provided therebetween.
1. A nonaqueous electrolyte secondary battery comprising a flat electrode assembly in which a first electrode plate and a second electrode plate having a different polarity from the first electrode plate are wound with a separator provided therebetween,
wherein the first electrode plate is disposed on a more inner peripheral side of the electrode assembly than the second electrode plate,
the first electrode plate includes a two-side-exposed core member portion where no active material layer is disposed on either side of a core member and a single-side-exposed core member portion where an active material layer is disposed on only an outer peripheral surface of a core member, the two-side-exposed core member portion and the single-side-exposed core member portion being provided in this order from a winding-start end portion of the first electrode plate,
a collector tab is connected to the two-side-exposed core member portion,
the single-side-exposed core member portion occupies at least one corner portion of two corner portions connecting two straight portions in an innermost periphery of the first electrode plate, and the active material layer disposed on the outer peripheral surface of the single-side-exposed core member portion in the at least one corner portion faces the active material layer disposed on an inner peripheral surface of the second electrode plate with the separator provided therebetween, and
a spacer is disposed on at least part of an inner peripheral surface of the single-side-exposed core member portion in the at least one corner portion.
2. The nonaqueous electrolyte secondary battery according to claim 1 , wherein the spacer is formed of an insulating tape.
3. The nonaqueous electrolyte secondary battery according to claim 2 , wherein the insulating tape does not overlap the collector tab in the thickness direction of the electrode assembly.
4. The nonaqueous electrolyte secondary battery according to claim 2 , wherein the insulating tape has a thickness of ½ or less of the thickness of the collector tab.
5. The nonaqueous electrolyte secondary battery according to claim 1 , wherein one of the first electrode plate and the second electrode plate serves as a positive electrode comprising a positive electrode active material, the other serves as a negative electrode plate comprising a negative electrode active material, and the negative electrode active material comprises a mixture of a graphite and a silicon oxide represented by SiO x .
6. The nonaqueous electrolyte secondary battery according to claim 1 , wherein a collector tab is connected to a two-side-exposed core member portion provided at a winding-start-end portion of the second electrode plate.
7. The nonaqueous electrolyte secondary battery according to claim 1 , wherein the first electrode plate serves as a negative electrode plate, and the second electrode plate serves as a positive electrode plate.