Quenched alloy for rare earth magnet and a manufacturing method of rare earth magnet
The present invention is provided with a quenched alloy for rare earth magnet and a manufacturing method of rare earth magnet. It comprises an R 2 T 14 B main phase, wherein R is selected from at least one rare earth element including Nd. The average grain diameter of the main phase in the brachyaxis direction is in a range of 10˜15 μm and the average interval of the Nd rich phase is in a range of 1.0˜3.5 μm. In the fine powder of the above-mentioned quenched alloy, the number of magnet domains of a single grain decreases. Thus, it is easier for external magnetic field orientation to obtain high performance magnet, and the squareness, coercivity and the thermal resistance of the magnet are sufficiently improved.
1. A quenched alloy for rare earth magnet, comprising:
an R 2 Fe 14 B main phase, wherein:
R is selected from at least one rare earth element comprising Nd,
an average grain diameter of a primary crystallization in a brachyaxis direction is in a range of 10.21-14.88 μm,
an average interval of a Nd rich phase is in a range of 1.15-2.77 μm,
the quenched alloy has an average thickness in a range of 0.2-0.4 mm,
counted in weight percent, more than 95% of the quenched alloy has a thickness in a range of 0.1-0.7 mm,
a raw material of the quenched alloy comprises:
R: 13.5 at %-15.5 at %,
B: 5.2 at %-5.8 at %,
Cu: 0.1 at %-0.8 at %,
Al: 0.1 at %-2.0 at %,
an atomic percent of W is in a range of 0.0005 at %-0.03 at %,
T: 0 at %-2.0 at %, T is selected from at least one of the elements Ti, Zr, V, Mo, Co, Zn, Ga, Nb, Sn, Sb, Hf, Bi, Ni, Si, Cr, Mn, S or P, and
remaining components comprise Fe and unavoidable impurity, and
the quenched alloy is obtained by strip casting a molten alloy fluid of the raw material and cooling at a cooling rate between 10 2 ° C./s and 10 4 ° C./s.
2. The quenched alloy for rare earth magnet according to claim 1 , wherein an atomic percent of Cu is in a range of 0.3 at %-0.7 at %.
3. The quenched alloy for rare earth magnet according to claim 1 , wherein the quenched alloy is kept in a material container for 0.5-5 hours in a preservation temperature of 500-700° C. after being cooled to 500-750° C.
4. A manufacturing method of rare earth magnet, comprising:
coarsely crushing a quenched alloy for rare earth magnet to generate a powder, wherein:
the quenched alloy comprises an R 2 T 14 B main phase,
R is selected from at least one rare earth element comprising Nd,
an average grain diameter of a primary crystallization in a brachyaxis direction is in a range of 10.21-14.88 μm,
an average interval of a Nd rich phase is in a range of 1.15-2.77 μm,
the quenched alloy has an average thickness in a range of 0.2-0.4 mm,
counted in weight percent, more than 95% of the quenched alloy has a thickness in a range of 0.1-0.7 mm,
a raw material of the quenched alloy comprises:
R: 13.5 at %-15.5 at %,
B: 5.2 at %-5.8 at %,
Cu: 0.1 at %-0.8 at %,
Al: 0.1 at %-2.0 at %,
an atomic percent of W is in a range of 0.0005 at %-0.03 at %,
T: 0 at %-2.0 at %, T is selected from at least one of the elements Ti, Zr, V, Mo, Co, Zn, Ga, Nb, Sn, Sb, Hf, Bi, Ni, Si, Cr, Mn, S or P, and
remaining components comprise Fe and unavoidable impurity, and
the quenched alloy is obtained by strip casting a molten alloy fluid of the raw material and cooling at a cooling rate between 10 2 ° C./s and 10 4 ° C./s;
finely crushing the powder to fine powder;
placing the fine powder under a magnetic field for pre-orientating and obtaining green compacts under a magnetic field; and
sintering the green compacts in vacuum or in inert gas atmosphere in a temperature of 900° C.-1100° C.
5. The manufacturing method of rare earth magnet according to claim 4 , wherein an atomic percent of Cu is in a range of 0.3 at %-0.7 at %.
6. The manufacturing method of rare earth magnet according to claim 4 , wherein the quenched alloy is kept in a material container for 0.5-5 hours in a preservation temperature of 500-700° C. after being cooled to 500-750° C.