Heat stabilized polyamide composition
The invention relates to a polyamide composition comprising: a. A semi-crystalline polyamide; b. An impact modifier in an amount ranging from 1 wt % to 50 wt %; c. A branching agent in an amount ranging from 0.01 to 6.0 wt %; d. An inorganic stabilizer in an amount ranging from 0.01 wt % to 2.0 wt %; e. An organic stabilizer E1 comprising a primary antioxidant group in an amount ranging from 0.01 wt % to 2.0 wt and an organic stabilizer E2 comprising a hindered amine group in an amount ranging from 0.01 wt % to 4.0 wt %; or an organic stabilizer E3 comprising a primary antioxidant group and a hindered amine group in an amount ranging from 0.02 to 6.0 wt %; or a combination of E1, E2 and E3 in a total amount of 0.02 to 6.0 wt %; wherein all wt % are based on the total amount of polyamide composition. The invention also relates to a process for preparing a container by blow molding this composition, as well as use of the container in various applications.
1. A polyamide composition comprising:
(a) a semi-crystalline aliphatic polyamide selected from the group consisting of PA-6, PA-66, PA6/66, PA66/6, PA-410 and blends thereof;
(b) 5 to 50 wt. % of functionalized olefinic rubber having a Tg of lower than 0° C. and containing groups reactive with the polyamide (a) as an impact modifier;
(c) 0.03 to 3.0 wt. % of a branching agent having functional groups that are capable of reacting with amino, amide and/or carboxylic end-groups of the polyamide (a);
(d) 0.01 to 2.0 wt. % of a copper compound and a salt containing a halogenide acid group or a copper complex as an inorganic stabilizer; and
(e) a combination of an organic stabilizer E1 in an amount ranging from 0.1 wt % to 2.0 wt % and an organic stabilizer E2 in an amount ranging from 0.1 wt % to 2.0 wt %; wherein
the organic stabilizer E1 comprises a primary antioxidant group which is a phenolic antioxidant, and the organic stabilizer E2 comprises a hindered amine group derived from a substituted piperidine compound, and wherein
all wt % are based on the total amount of polyamide composition, and wherein
a blow molded part formed of the polyamide composition after heat aging at 200° C. exhibits at least 30 J of energy by an impact falling dart test according to ISO 6603-2 after 20 minutes, 200 minutes and 1000 minutes.
2. The polyamide composition according to claim 1 , wherein the polyamide composition has a melt volume flow rate ranging from 25 to 45 cm 3 /10 min, as measured according to ISO 1133 with 21.6 kg and 275° C.
3. The polyamide composition according to claim 1 , wherein
E1 is present in an amount ranging from 0.1 wt % to 1.0 wt % and E2 is present in an amount ranging from 0.1 wt % to 2.0 wt %, or
E3 is present in an amount ranging from 0.2 to 3.0 wt %, or a combination of E1, E2 and E3 is present in a total amount ranging from 0.2 to 0 wt %.
4. The polyamide composition according to claim 1 , wherein E1 is selected chosen from the group consisting of:
benzenpropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-octadecyl ester;
2,5,7,8-Tetra-methyl-2-(4′,8′,12′-tri-methyl-tri-decyl)-chroman-6-ol;
N,N″-hexamethylene bis (3,5-di-t-butyl-4-hydroxyhydrocinnamamide); ethylenebis(oxyethylene) bis (3-t-butyl-4-hydroxy-5-methylhydrocinnamate);
hexamethylenebis (3,5-di-t-butyl-4-hydroxycinnamate);
4,4′,4″-[(2,4,6-trimethyl-1,3,5-benzenetriyl)tris(methylene)]tris[2,6-bis(1,1-dimethylethyl)-phenol;
bis-[3,3-bis-(4″-hydroxy-3″-t-butylphenyl butanoic acid]-glycol ester:
tris(3,5-di-t-butyl-4-hydroxy benzyl) isocyanurate;
tetrakis[methylene (3,5-di-t-butyl-4-hydroxyhydrocinnamate)] methane; and
3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid ester with 1,3,5-tris (2-hydroxy-ethyl)-iso-cyanurate.
5. The polyamide composition according to claim 1 , wherein a ratio E1:E2 is at least 1:1.5, wherein the ratio is based on weight percentages of total weights of E1 and E2.
6. The polyamide composition according to claim 1 , wherein the composition is free of phosphites.
7. The polyamide composition according to claim 1 , wherein E1 is a hindered phenolic antioxidant.
8. The polyamide composition according to claim 1 , wherein the composition further comprises a silicone oil in an amount of at least 50 ppm with respect to the total amount of composition.
9. The polyamide composition according to claim 1 , wherein the composition further comprises a nucleating agent.
10. A blow molded container prepared by blow molding a polyamide composition according to claim 1 , wherein after heat aging at 200° C., the blow molded container exhibits at least 30 J of energy by an impact falling dart test according to ISO 6603-2 after 20 minutes, 200 minutes and 1000 minutes.
11. The blow molded container according to claim 10 , wherein the container has a length L, a width W and a depth D as defined in a 3 dimensional Cartesian coordinate system, wherein L is at least 75 cm, and in which L>2W≥D.
12. The blow molded container according to claim 10 , wherein the container is in a form selected from the group consisting of fuel tanks, compressed natural gas tanks, hydrogen tanks, ducts and chemical storage containers.
13. A polyamide composition comprising:
(a) a semi-crystalline aliphatic polyamide selected from the group consisting of PA-6, PA-66, PA6/66, PA66/6, PA-410 and blends thereof;
(b) 5 to 50 wt. % of functionalized olefinic rubber having a Tg of lower than 0° C. and containing groups reactive with the polyamide (a) as an impact modifier;
(c) 0.03 to 3.0 wt. % of a branching agent having functional groups that are capable of reacting with amino, amide and/or carboxylic end-groups of the polyamide (a);
(d) 0.01 to 2.0 wt. % of copper iodide and potassium bromide as inorganic stabilizers; and
(e) a combination of an organic stabilizer E1 in an amount ranging from 0.1 wt % to 2.0 wt % and an organic stabilizer E2 in an amount ranging from 0.1 wt % to 2.0 wt %; wherein
the organic stabilizer E1 comprises a primary antioxidant group which is a phenolic antioxidant, and wherein
the organic stabilizer E2 comprises a hindered amine group derived from a substituted piperidine compound, and wherein
all wt % are based on the total amount of polyamide composition, and wherein
a blow molded part formed of the polyamide composition after heat aging at 200° C. exhibits at least 30 J of energy by an impact falling dart test according to ISO 6603-2 after 20 minutes, 200 minutes and 1000 minutes.
14. The polyamide composition according to claim 13 , wherein the organic stabilizer E1 is present in an amount from 0.1 to 1.0 wt. %.