IP Library Granted Patent US 10,421,906
Granted Patent B2
US 10,421,906 · App. 15/329,331 · Granted Sep 24, 2019

Liquid-crystal display element

Inventors: Kazunori Maruyama (Kita-adachi-gun, JP); Yoshinori Iwashita (Kita-adachi-gun, JP); Shinji Ogawa (Kita-adachi-gun, JP)
Assignee: DIC CORPORATION
C09K19/3066C09K19/3003C09K19/322C09K19/44G02F1/137G02F1/1337G02F1/1368G02F1/13439G02F1/134309G02F1/136286C09K2019/123C09K2019/301C09K2019/3004C09K2019/3009C09K2019/3016C09K2019/3425G02F2001/13712G02F2001/133738G02F2001/134372G02F2201/121G02F2201/123
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Quick Facts
Patent No.
US 10,421,906
App. No.
15/329,331
Granted
Sep 24, 2019
Kind
B2
Abstract

There is provided a liquid crystal display element. The liquid crystal layer contains a liquid crystal composition between the first substrate and the second substrate. The first common electrode contains a transparent conductive material on the first substrate. The second common electrode contains a transparent conductive material on the second substrate. The pixel electrode contains a transparent conductive material. Distances R between the pixel electrode and the common electrode is smaller than distance G between the first substrate and the second substrate. The common electrode is disposed closer to the first substrate than the pixel electrode over nearly the entire surface of the first substrate. The liquid crystal composition has negative dielectric anisotropy and contains one or two or more compounds selected from the group of compounds represented by General Formula (i), General Formula (ii), and General Formula (iii).

Claims (40)

1. A liquid crystal display element comprising:

a first transparent insulating substrate and a second transparent insulating substrate, which are disposed so as to face each other;

a liquid crystal layer containing a liquid crystal composition, which is interposed between the first substrate and the second substrate;

on the first substrate, a first common electrode containing a transparent conductive material and a plurality of gate bus lines and data bus lines being disposed in a matrix shape;

on the second substrate, a second common electrode containing a transparent conductive material;

for each pixel, a thin film transistor provided at an intersection between the gate bus lines and data bus lines, and a pixel electrode containing a transparent conductive material, which is driven by the thin film transistor; and

alignment film layers which induce homogeneous alignment between the liquid crystal layer and each of the first and second substrates and whose alignment directions are parallel to each other,

wherein a distances R between the pixel electrode and the first common electrode is smaller than a distance G between the first substrate and the second substrate so that the pixel electrode and the first common electrode form fringe electric fields therebetween,

the first common electrode is disposed closer to the first substrate than the pixel electrodes and over nearly the entire surface of the first substrate, and

the liquid crystal composition has negative dielectric anisotropy and contains one or more compounds selected from the group of compounds represented by General Formula (i), General Formula (ii), and General Formula (iii):

wherein R i1 , R i2 , R ii1 , R ii2 , R iii1 and R iii2 each independently represent an alkyl group having 1 to 10 carbon atoms, one or two or more non-adjacent —CH 2 — in the alkyl group may each independently be substituted with —CH═CH—, —O—, —CO—, —COO— or —OCO—,

A i1 , A i2 , A ii1 , A ii2 , A iii1 , and A iii2 each independently represent a group selected from the group consisting of (a) a 1,4-cyclohexylene group (one —CH 2 — or two or more non-adjacent —CH 2 — present in this group may be substituted with —O—), (b) a 1,4-phenylene group (one —CH═ or two or more non-adjacent —CH═ present in the group may be substituted with —N═), and (c) a naphthalene-2,6-diyl group, a 1,2,3,4-tetrahydronaphthalene-2,6-diyl group or a decahydronaphthalene-2,6-diyl group (one —CH═ or two or more non-adjacent —CH═ present in the naphthalene-2,6-diyl group or the 1,2,3,4-tetrahydronaphthalene-2,6-diyl group may be substituted with —N═), and group (a), group (b), and group (c) described above may each independently be substituted with a cyano group, a fluorine atom, or a chlorine atom,

Z i1 , Z i2 , Z ii1 , Z ii2 , Z iii1 and Z iii2 each independently represent a single bond, —OCH 2 —, —CH 2 O—, —OCF 2 —, —CH 2 CH 2 —, or —CF 2 CF 2 —,

Z iii3 represents —CH 2 — or an oxygen atom,

X ii1 represents a hydrogen atom or a fluorine atom,

m i1 , m i2 , m ii1 , m ii2 , m iii1 , and m iii2 each independently represent an integer of 0 to 3,

m i1 +m i2 , m ii1 +m ii2 and m iii1 +m iii2 are 0, 1, 2, or 3, and

in the case where there is a plurality of A i1 to A iii2 and Z i1 to Z iii2 , these may be the same or different.

2. The liquid crystal display element according to claim 1 , further comprising:

one or more of compounds represented by General Formula (IV):

wherein R 44 and R 45 each independently represent an alkyl group having 1 to 8 carbon atoms, one or two or more —CH 2 — in the group may be substituted with —O—, —CH═CH—, —CO—, —OCO—, —COO—, —CF 2 O— or —OCF 2 — as long as an oxygen atom is not directly adjacent to another oxygen atom, one or two or more hydrogen atoms in the group may be independently substituted with a fluorine atom or a chlorine atom,

A 41 to A 43 each independently represent a group selected from the group consisting of (a) a 1,4-cyclohexylene group (one —CH 2 — or two or more non-adjacent —CH 2 — present in the group may be substituted with —O— or —S—) (b) a 1,4-phenylene group (one —CH═ or two or more non-adjacent —CH═ present in the group may be substituted with —N═, and the hydrogen atom present in the group may be substituted with a fluorine atom or a chlorine atom, provided that at least one of adjacent —CH═ represents a hydrogen atom), and (c) a naphthalene-2,6-diyl group, a 1,2,3,4-tetrahydronaphthalene-2,6-diyl group or a decahydronaphthalene-2,6-diyl group (one —CH═ or two or more non-adjacent —CH═ present in the naphthalene-2,6-diyl group, 1,2,3,4-tetrahydronaphthalene-2,6-diyl group or decahydronaphthalene-2,6-diyl group may be substituted with —N═, and the hydrogen atom present in the group may be substituted with a fluorine atom or a chlorine atom, provided that at least one of adjacent —CH═ represents a hydrogen atom),

Z 41 and Z 42 each independently represent a single bond, —CH═CH—, —C≡C—, —CH 2 CH 2 —, —(CH 2 ) 4 —, —OCH 2 —, —CH 2 O—, —OCF 2 —, or —CF 2 O—,

m 41 represents an integer of 0 to 2, and

in the case where there is a plurality of A 41 and Z 41 , these may be the same or different.

3. The liquid crystal display element according to claim 2 , further comprising:

one or more of compounds represented by General Formula (IV-1) as the compound represented by General Formula (IV):

wherein R 411 and R 412 each independently represent an alkyl group having 1 to 8 carbon R 412 atoms, an alkenyl group having 2 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms or an alkenyloxy group having 2 to 8 carbon atoms, A 411 represents a 1,4-phenylene group or a trans-1,4-cyclohexylene group, k represents 1 or 2, and in the case where k is 2, two A's may be the same or different.

4. The liquid crystal display element according to claim 3 , further comprising:

one or more of compounds represented by General Formula (IV-1a) below as the compound represented by General Formula (IV-1):

wherein R 411 and R 412 each independently represent the same meanings as R 411 and R 412 in General Formula (IV-1).

5. The liquid crystal display element according to claim 1 , further comprising:

one or more of compounds represented by General Formula (i-a) as General Formula (i):

wherein A ia1 each independently represent a group selected from the group consisting of (a) a 1,4-cyclohexylene group (one —CH 2 — or two or more non-adjacent —CH 2 — present in this group may be substituted with —O—), (b) a 1,4-phenylene group (one —CH═ or two or more non-adjacent —CH═ present in the group may be substituted with —N═), and (c) a naphthalene-2,6-diyl group, a 1,2,3,4-tetrahydronaphthalene-2,6-diyl group or a decahydronaphthalene-2,6-diyl group (one —CH═ or two or more non-adjacent —CH═ present in the naphthalene-2,6-diyl group or the 1,2,3,4-tetrahydronaphthalene-2,6-diyl group may be substituted with —N═), and group (a), group (b), and group (c) described above may each independently be substituted with a cyano group, a fluorine atom, or a chlorine atom, m ia1 and m ia2 each independently represent 0 or 1, R i1 , R i2 , A i1 , A i2 , Z i1 , and Z i2 each independently represent the same meanings as R i1 , R i2 , A i1 , A i2 , Z i1 , and Z i2 in General Formula (i).

6. The liquid crystal display element according to claim 1 , further comprising:

one or more of compounds in General Formula (i) where Z i1 and Z i2 each represent a single bond.

7. The liquid crystal display element according to claim 1 ,

wherein the pixel electrode has a comb shape or has a slit.

8. The liquid crystal display element according to claim 1 ,

wherein the inter-electrode distance R is zero.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 24, 2024
From: DIC CORPORATION
To: SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIAL CO., LTD.
Reel/Frame 067528/0688 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE NAME PREVIOUSLY RECORDED ON REEL 041092 FRAME 0921. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jul 3, 2019
From: MARUYAMA, KAZUNORI; IWASHITA, YOSHINORI; OGAWA, SHINJI
To: DIC CORPORATION
Reel/Frame 049680/0091 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 26, 2017
From: MARUYAMA, KAZUNORI; IWASHITA, YOSHINORI; OGAWA, SHINJI
To: DIC CORPORATION (TOKYO)
Reel/Frame 041092/0921 →
Priority Claims (1)
JP 2014-153826 · Jul 29, 2014 · national
Continuity (1)
Related Publication 20170210988A1 · Jul 27, 2017