Yttrium fluoride spray material, yttrium oxyfluoride-deposited article, and making methods
An yttrium fluoride spray material contains Y 5 O 4 F 7 and YF 3 , and has an average particle size of 10-60 μm and a bulk density of 1.2-2.5 g/cm 3 . The Y 5 O 4 F 7 and YF 3 in the yttrium fluoride spray material consist of 30 to 90% by weight of Y 5 O 4 F 7 and the balance of YF 3 . A sprayed coating of yttrium oxyfluoride is obtained by atmospheric plasma spraying of the spray material.
1. A spray material comprising yttrium compounds, the yttrium compounds consisting of 30 to 71% by weight of Y 5 O 4 F 7 and the balance 29 to 70% by weight of YF 3 , with respect to the total of Y 5 O 4 F 7 and YF 3 , and the spray material having an average particle size of 10 to 60 μm and a bulk density of 1.2 to 2.5 g/cm 3 .
2. The spray material of claim 1 having an average particle size of 33 to 60 μm.
3. The spray material of claim 2 having an aspect ratio of up to 2.
4. The spray material of claim 2 having an angle of repose of up to 45°.
5. The spray material of claim 2 obtained by a method comprising the steps of:
mixing 10 to 50% by weight of yttrium oxide having an average particle size of 0.01 to 3 μm with the balance of the ammonium fluoride complex salt of formula: (YF 3 ) 3 NH 4 F.H 2 O having an average particle size of 0.01 to 3 μm, and
granulating and firing the mixture.
6. The spray material of claim 1 having an aspect ratio of up to 2.
7. The spray material of claim 1 having an angle of repose of up to 45°.
8. The spray material of claim 1 obtained by a method comprising the steps of:
mixing 10 to 50% by weight of yttrium oxide having an average particle size of 0.01 to 3 μm with the balance of the ammonium fluoride complex salt of formula: (YF 3 ) 3 NH 4 F.H 2 O having an average particle size of 0.01 to 3 μm, and
granulating and firing the mixture.