IP Library Granted Patent US 11,844,351
Granted Patent B2
US 11,844,351 · App. 15/338,790 · Granted Dec 19, 2023

Method of treating a glazed ceramic article

Inventor: Nathan Lee Fields (Concord, NC)
Assignee: MICROBAN PRODUCTS COMPANY
A01N59/16A01N25/08C03C8/04C03C8/18C03C2204/02
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Quick Facts
Patent No.
US 11,844,351
App. No.
15/338,790
Granted
Dec 19, 2023
Kind
B2
Abstract

A method of treating a glazed ceramic article comprises applying an antimicrobial composition on top of an outermost surface of a glazed ceramic article. The antimicrobial composition comprises an antimicrobial additive. The antimicrobial composition further comprises a carrier medium. The antimicrobial additive is selected from the group consisting of Bi 2 O 3 , ZnO, Ag 2 CO 3 , Ag 2 O, Zn, Bi, Ag, and a combination thereof.

Claims (22)

1. A method of treating a glazed ceramic article, the method comprising:

applying an antimicrobial. composition on top of an outermost surface of a glazed ceramic article, wherein the antimicrobial composition comprises an antimicrobial additive, wherein the antimicrobial additive is a combination of 30 to 69 weight % ZnO, 30 to 69 weight % Bi 2 O 3 , and 1 to 10 weight % frit containing Ag, and

firing the glazed ceramic article having the antimicrobial composition applied thereon, wherein the application level of the antimicrobial additive on the glazed ceramic article is in a range of 0.5 g/m 2 to 5.0 g/m 2 .

2. The method according to claim 1 , wherein the antimicrobial composition further comprises a carrier medium.

3. The method according to claim 2 , wherein the carrier medium is selected from the group consisting of water, polyethylene glycol, and a combination thereof.

4. The method according to claim 1 , wherein the antimicrobial additive is a combination of 33 weight % ZnO, 66 weight % B 2 O 3 , and 1 weight % frit containing Ag.

5. The method according to claim 1 . wherein the antimicrobial additive is a combination of 66 weight % ZnO, 33 weight % Bi 2 O 3 , and 1 weight % frit containing silver.

6. The method according to claim 1 , wherein the antimicrobial additive is present in the antimicrobial composition in a ratio of solids to carrier medium in a range of 1% to 10%.

7. The method according to claim 1 , wherein the application level of the antimicrobial additive on the glazed ceramic article is in a range of 1.0 g/m 2 to 3.0 g/m 2 .

8. The method according to claim 1 . wherein the antimicrobial composition is applied in a layer.

9. The method according to claim 1 , wherein the application occurs by spray, rotocolor, silicon roller, disc cabin, or inkjet.

10. The method according to claim 1 , wherein the applied antimicrobial diffuses into the body of the glaze.

11. The method according to claim 10 , wherein diffusion occurs according to Fick's Second Law of Diffusion.

12. A method of treating a glazed porcelain tile, the method comprising:

applying an antimicrobial composition on top of an outermost surface of a glazed porcelain tile, wherein the antimicrobial composition comprises an antimicrobial additive, wherein the antimicrobial additive is a combination of 33 weight % ZnO, 66 weight % Bi 2 O 3 , and 1 weight % frit containing Ag, and

firing the glazed porcelain tile having the antimicrobial composition applied thereon.

13. The method according to claim 12 , wherein the antimicrobial composition further comprises a carrier medium.

14. The method according to claim 13 , wherein thecarrier medium is selected from the group consisting of water, polyethylene glycol, and a combination thereof.

15. The method according to claim 12 , wherein the antimicrobial additive is present in the antimicrobial composition in a ratio of solids to carrier medium in a range of 1% to 10%.

16. The method according to claim 12 , wherein an application level of antimicrobial additive on the glazed porcelain tile is in a range of 0.5 g/m 2 to 5.0 g/m 2 .

17. The method according to claim 16 , wherein the application level of the antimicrobial additive on the glazed porcelain tile is in a range of 1.0 g/m 2 to 3.0 g/m 2 .

18. The method of claim 1 , wherein the antimicrobial additive is a combination of 33 weight % ZnO, 66 weight % Bi 2 O 3 , and 1 weight % frit containing Ag.

Assignments (2)
SECURITY AGREEMENT Recorded Feb 5, 2020
From: MICROBAN PRODUCTS COMPANY
To: FIFTH THIRD BANK, NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 051833/0155 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 3, 2016
From: FIELDS, NATHAN LEE
To: MICROBAN PRODUCTS COMPANY
Reel/Frame 040215/0541 →
Continuity (1)
Related Publication 20180116226A1 · May 3, 2018