Organic electroluminescent element, display device and lighting device
View Patent ↗Disclosed is an organic electroluminescent device having long life, while exhibiting high luminous efficiency. Also disclosed are an illuminating device and a display, each using such an organic electroluminescent device. In the organic electroluminescent device, a compound represented by the general formula (A) which is suitable as a host material for a phosphorescent metal complex is used at least in one sublayer of a light-emitting layer.
1. An organic electroluminescent element comprising a substrate having thereon at least an anode and a cathode, and a light emitting layer between the aforesaid anode and the aforesaid cathode, wherein at least one light emitting layer incorporates a compound represented by Formula (A):
wherein A1 and A2 each represent a hydrogen atom or a nitrogen-atom containing substituent, provided that at least one of A1 and A2 represents one selected from the group consisting of a carbazolyl group, a carbolinyl group; represented by Formula (a), and a diarylamino group; X and Y each represents O; L1 and L2 each represent a divalent linking group; and L3 represents a divalent linking group selected from the group consisting of carboline ring, a diazacarbazole ring, a triazole ring, a pyrrole ring, a pyridine ring, a pyrazine ring, a quinoxaline ring, a triophene ring, an oxadiazole ring, and an indole ring; n represents an integer of 1 or 2; n1 and n2 each represent an integer of 1 or 2; and n3 and n4 each represent 0 or 1;
Wherein X 1 -X 8 each represent a nitrogen atom or —C(Ra)═; at least one of the aforesaid X 1 -X 8 represents —C(Ra)═, wherein Ra is a hydrogen atom; and Ra and Rb each represent a hydrogen atom or a substituent.
2. The organic electroluminescent element of claim 1 , wherein the at least one of A1 and A2 represents a carbazolyl group or a diarylamino group.
3. The organic electroluminescent element of claim 1 ,
wherein L3 represents a divalent linking group selected from the group consisting of a pyridine ring and an oxadiazole ring.
4. The organic electroluminescent element of claim 1 , wherein L3 represents a divalent linking group derived from a pyridine ring.
5. The organic electroluminescent element of any claim 1 , wherein the aforesaid light emitting layer incorporates a phosphorescence emitting metal complex.
6. The organic electroluminescent element of claim 4 , wherein the aforesaid phosphorescence emitting metal complex is an Ir complex.
7. The organic electroluminescent element of claim 4 , wherein the aforesaid phosphorescence emitting metal complex is represented by Formula (B):
wherein R 1 represents a substituent; Z represents a group of non-metal atoms necessary for forming a 5-7 numbered ring; n 1 represents an integer of 0 -5; B 1 - B5 each represents a carbon atom, a nitrogen atom, an oxygen atom, or a sulfur atom and at least one represents a nitrogen atom; M 1 represents a metal of Groups 8 -10 in the element periodic table; X 1 and X 2 each represents a carbon atom, a nitrogen atom, or an oxygen atom; L 1 represents a group of atoms which form a bidentate ligand with X 1 and X 2 ; m1 represents 1, 2, or 3; and m2 represents 0, 1, or 2, provided that a sum of m1 and m2 is 2 or 3.
8. The organic electroluminescent element of claim 6 , wherein m2 of the phosphorescence emitting metal complex represented by the aforesaid Formula (B) is 0.
9. The organic electroluminescent element of claim 7 , wherein a nitrogen-containing heterocyclic ring formed by phosphorescence emitting metal complexes B 1 -B 5 in the aforesaid Formula (B) is an imidazole ring.
10. The organic electroluminescent element of claim 1 , emitting white light.
11. A display device provided with the organic electroluminescent element of claim 1 .
12. An illuminating device provided with the organic electroluminescent element of claim 1 .