Fuel cell system and desulfurization system
One embodiment of the present invention is a unique fuel cell system. Another embodiment is a unique desulfurization system. Yet another embodiment is a method of operating a fuel cell system. Other embodiments include apparatuses, systems, devices, hardware, methods, and combinations for fuel cell systems and desulfurization systems. Further embodiments, forms, features, aspects, benefits, and advantages of the present application will become apparent from the description and figures provided herewith.
1. A fuel cell system, comprising:
a fuel cell;
a catalytic reactor having a catalyst including at least one Group VIII noble metal and iron; wherein the catalytic reactor is configured to contact a sulfur-containing hydrocarbon fuel and an oxidant with the catalyst; wherein the catalyst is configured to oxidize sulfur-containing compounds to form sulfur oxides; and wherein the iron concentration in the catalyst is in the range of 0.5% to 40% by weight.
2. The fuel cell system of claim 1 , wherein the iron concentration in the catalyst is in the range of 1% to 30% by weight.
3. The fuel cell system of claim 2 , wherein the iron concentration in the catalyst is in the range of 2% to 10% by weight.
4. The fuel cell system of claim 3 , wherein the iron concentration in the catalyst is in the range of 3% to 7% by weight.
5. The fuel cell system of claim 4 , wherein the iron concentration in the catalyst is in the range of 4% to 6% by weight.
6. The fuel cell system of claim 1 , wherein the at least one Group VIII noble metal concentration in the catalyst is in the range of 0.1% to 5% by weight.
7. The fuel cell system of claim 6 , wherein the at least one Group VIII noble metal is platinum.
8. The fuel cell system of claim 1 , wherein the at least one Group VIII noble metal is platinum.
9. The fuel cell system of claim 1 , further comprising a reformer, wherein the adsorbent is fluidly disposed between the catalytic reactor and the reformer.
10. The fuel cell system of claim 1 further comprising an adsorbent fluidly disposed between the catalytic reactor and the fuel cell, wherein the adsorbent is configured to adsorb the sulfur oxides, and wherein the catalytic reactor and the adsorbent are operative to remove sulfur-containing compounds from the sulfur-containing hydrocarbon fuel prior to supplying the hydrocarbon fuel to the fuel cell.
11. A desulfurization system, comprising:
a catalytic reactor operative to oxidize sulfur-containing compounds in a feed stream having a sulfur-containing hydrocarbon fuel and an oxidant, wherein the catalytic reactor includes a sulfur oxidation catalyst having a Group VIII noble metal as a first active metal and iron as a second active metal; wherein the iron concentration in the sulfur oxidation catalyst is in the range of 0.5% to 40% by weight; and wherein the sulfur oxidation catalyst is configured to oxidize sulfur-containing compounds to form sulfur oxides; and
a sulfur oxide trap in fluid communication with the catalytic reactor, wherein the sulfur oxide trap is configured to capture sulfur oxides from the feed stream.
12. The desulfurization system of claim 11 , wherein the desulfurization system is configured to desulfurize a feed stream having an O 2 /C ratio of about 0.001 to 0.5.
13. The desulfurization system of claim 12 , wherein the desulfurization system is configured to desulfurize a feed stream having an O 2 /C ratio of about 0.001 to 0.05.
14. The desulfurization system of claim 10 , wherein the desulfurization system is configured to desulfurize a feed stream having an O 2 /S ratio of at least 10.
15. The desulfurization system of claim 11 , wherein the catalyst further includes promoter elements configured to promote sulfur oxidation.
16. The desulfurization system of claim 15 , wherein the promoter elements include at least one element selected from Groups IIa-VIIa, Groups Ib-Vb, Lanthanide Series and Actinide Series.
17. The desulfurization system of claim 10 , wherein the at least one Group VIII noble metal concentration in the sulfur oxidation catalyst is in the range of 0.01% to 20% by weight.
18. A desulfurization system, comprising:
a catalytic reactor operative to oxidize sulfur-containing compounds in a feed stream having a sulfur-containing hydrocarbon fuel and an oxidant, wherein the catalytic reactor includes a sulfur oxidation catalyst including a Group VIII noble metal as a first active metal and iron as a second active metal; and wherein the sulfur oxidation catalyst is configured to oxidize sulfur-containing compounds to form sulfur oxides; and
a sulfur oxide trap in fluid communication with and disposed downstream of the catalytic reactor, wherein the sulfur oxide trap is configured to capture sulfur oxides from the feed stream,
wherein a concentration of said iron in the sulfur oxidation catalyst is selected to provide greater desulfurization of the sulfur-containing hydrocarbon fuel than that provided by catalysts having platinum as the only active metal and that provided by catalysts having platinum and other base metals as the active metals.
19. The desulfurization system of claim 18 , wherein the iron concentration is selected to yield at least fifty percent less sulfur breakthrough downstream of the sulfur oxide trap than catalysts having platinum as the only active metal and catalysts having platinum and other base metals as the active metals.
20. The desulfurization system of claim 18 , wherein said catalytic reactor further includes one or more promoter elements selected from the group comprising Groups IIa-VIIa, Groups Ib-Vb, Lanthanide Series and Actinide Series elements, wherein the concentration of said promoter elements in said catalytic reactor is in the range of 0.01% to 10% by weight.