Concentrated and working strength aqueous flexographic developers
Flexographic printing members are prepared by developing an exposed flexographic printing member precursor with an aqueous flexographic developer. The aqueous flexographic developer comprises: a) a fatty acid composition consisting of one or more saturated or unsaturated fatty acids or alkali metal salts thereof, each saturated or unsaturated fatty acid or alkali metal salt thereof independently having 12 to 20 carbon atoms, the fatty acid composition being present in an amount of 0.25-2.0 weight %, and at least 85 weight % of the fatty acid composition is composed of one or more C 18 mono- or poly-unsaturated fatty acids or alkali metal salts thereof; b) an aminopolycarboxylic acid or alkali metal salt thereof in an amount of 0.05-0.30 weight %; c) a buffer compound in an amount of 05-0.60 weight %; and d) water. Such aqueous flexographic developers can also be provided in concentrated form and appropriately diluted before or during use.
1. A flexographic developer concentrate for processing an imaged flexographic printing member precursor, comprising:
a) a fatty acid composition consisting of one or more saturated or unsaturated fatty acids or alkali metal salts thereof, each saturated or unsaturated fatty acid or alkali metal salt thereof independently having 12 to 20 carbon atoms, the fatty acid composition being present in an amount of at least 10 weight % and up to and including 60 weight %,
wherein at least 85 weight % of the fatty acid composition is composed of one or more C 18 mono- or poly-unsaturated fatty acids or alkali metal salts thereof;
b) one or more aminopolycarboxylic acids or alkali metal salts thereof in an amount of at least 1.5 weight % and up to and including 15 weight %;
c) a buffer compound in an amount of at least 3.5 weight % and up to and including 25 weight %; and
d) water in an amount of up to and including 85 weight %, based on the total weight of the flexographic developer concentrate,
all amounts being based on the total weight of the flexographic developer concentrate,
the flexographic developer concentrate having a pH of at least 9.8 and up to and including 11.2 and a viscosity of at least 100 centipoises and up to and including 900 centipoises, and further comprising at least 1.5 weight % and up to and including 15 weight % of a glycol and poly-glycol mono-ether co-solvent having a molecular weight of less than 150, the amount being based on the total weight of the flexographic developer concentrate.
2. The flexographic developer concentrate of claim 1 , wherein the fatty acid composition consists essentially of oleic acid or an alkali metal salt thereof in an amount of at least 85 weight % and up to and including 90 weight %, based on the total weight of the fatty acid composition.
3. The flexographic developer concentrate of claim 1 , wherein the buffer compound is a carbonate.
4. The flexographic developer concentrate of claim 1 , wherein the fatty acid composition is present in an amount equal to or less than 25 weight %, based on the total weight of the flexographic developer concentrate.
5. The flexographic developer concentrate of claim 1 , comprising ethylenediamine tetracarboxylic acid or an alkali metal salt thereof in an amount of at least 1.5 weight % and up to and including 10 weight %, based on the total weight of the flexographic developer concentrate.
6. The flexographic developer concentrate of claim 1 , wherein:
a) the fatty acid composition consists essentially of oleic acid or an alkali metal salt thereof in an amount of at least 90 weight % and up to and including 100 weight % of the fatty acid composition, and the fatty acid composition is present in an amount of equal to or less than 25 weight %;
b) ethylenediamine tetracarboxylic acid or an alkali metal salt thereof is present as the one or more aminopolycarboxylic acids or alkali metal salts thereof in an amount of at least 1.5 weight % and up to and including 10 weight %;
c) a carbonate is present as the buffer compound in an amount of at least 4 weight % and up to and including 8 weight %; and
d) water is present in an amount of at least 60 weight % and up to and including 80 weight %;
all amounts being based on the total weight of the flexographic developer concentrate.
7. A solid flexographic developer concentrate, consisting essentially of:
a) a fatty acid alkali metal salt composition consisting of one or more saturated or unsaturated fatty acid alkali metal salts, each saturated or unsaturated fatty acid alkali metal salt thereof independently having 12 to 20 carbon atoms, the fatty acid alkali metal salts composition being present in an amount of up to and including 60 weight %,
wherein at least 85 weight % and up to and including 95 weight % of the fatty acid alkali metal salt composition is composed of one or more C 18 mono- or poly-unsaturated fatty acids or alkali metal salts thereof;
b) one or more aminopolycarboxylic acids or alkali metal salts thereof in an amount of up to and including 15 weight %;
c) a buffer compound in an amount of up to and including 25 weight %, and
optionally a glycol or poly-glycol mono-ether co-solvent, enzyme, fluorescent whitening agent, perfume, biocide, fungicide, defoaming agent, colorant, bleach, bleach activator, or surfactant,
all amounts being based on the total weight of the solid flexographic developer concentrate.