Nanocellulose compositions and processes to produce same
View Patent ↗A composition comprising nanocellulose is disclosed, wherein the nanocellulose contains very low or essentially no sulfur content. The nanocellulose may be in the form of cellulose nanocrystals, cellulose nanofibrils, or both. The nanocellulose is characterized by a crystallinity of at least 80%, an onset of thermal decomposition of 300° F. or higher, and a low light transmittance over the range 400-700 nm. Other variations provide a composition comprising lignin-coated hydrophobic nanocellulose, wherein the nanocellulose contains very low or essentially no sulfur content. Some variations provide a composition comprising nanocellulose, wherein the nanocellulose contains about 0.1 wt % equivalent sulfur content, or less, as SO 4 groups chemically or physically bound to the nanocellulose. In some embodiments, the nanocellulose contains essentially no hydrogen atoms (apart from hydrogen structurally contained in nanocellulose itself) bound to the nanocellulose. Various compositions, materials, and products may incorporate the nanocellulose compositions disclosed herein.
1. A composition comprising hydrophobic nanocellulose and lignin, wherein hydrophobicity of said nanocellulose arises from said lignin, wherein said nanocellulose contains about 0.5 wt % sulfur content or less, and wherein said nanocellulose is characterized by a crystallinity of at least 60%.
2. The composition of claim 1 , wherein said nanocellulose contains about 0.1 wt % sulfur content or less.
3. The composition of claim 1 , wherein said nanocellulose contains about 0.5 wt % sodium content or less.
4. The composition of claim 1 , wherein said nanocellulose is in the form of cellulose nanocrystals and/or cellulose nanofibrils.
5. The composition of claim 1 , wherein said nanocellulose is characterized by a crystallinity of at least 80%.
6. The composition of claim 1 , wherein said nanocellulose is characterized by an onset of thermal decomposition of about 300° F. or higher.
7. The composition of claim 1 , wherein said nanocellulose is characterized by a transmittance of less than about 20% at a wavelength of 400 nm.
8. The composition of claim 1 , wherein said nanocellulose is characterized by a transmittance of less than about 30% at a wavelength of 700 nm.
9. A product comprising the nanocellulose composition of claim 1 , wherein said product optionally further comprises a material selected from the group consisting of a polymer, a carbon fiber, graphene, a glass, a solvent, a fluid, a substrate, and combinations thereof.
10. A composition comprising lignin-coated nanocellulose, wherein said nanocellulose contains about 0.5 wt % sulfur content or less, and wherein said nanocellulose is characterized by a crystallinity of at least 60%.
11. The composition of claim 10 , wherein said nanocellulose contains about 0.1 wt % sulfur content or less.
12. The composition of claim 10 , wherein said nanocellulose contains about 0.5 wt % sodium content or less.
13. The composition of claim 10 , wherein said nanocellulose is in the form of cellulose nanocrystals and/or cellulose nanofibrils.
14. The composition of claim 10 , wherein said nanocellulose is characterized by a crystallinity of at least 80%.
15. The composition of claim 10 , wherein said nanocellulose is characterized by an onset of thermal decomposition of about 300° F. or higher.
16. The composition of claim 10 , wherein said nanocellulose is characterized by a transmittance of less than about 20% at a wavelength of 400 nm.
17. The composition of claim 10 , wherein said nanocellulose is characterized by a transmittance of less than about 30% at a wavelength of 700 nm.
18. A product comprising the nanocellulose composition of claim 10 , wherein said product optionally further comprises a material selected from the group consisting of a polymer, a carbon fiber, graphene, a glass, a solvent, a fluid, a substrate, and combinations thereof.