IP Library Granted Patent US 10,578,050
Granted Patent B2
US 10,578,050 · App. 15/354,001 · Granted Mar 3, 2020

Thermally insulated steel piston crown and method of making using a ceramic coating

Inventors: Warran Boyd Lineton (Chelsea, MI); Miguel Azevedo (Ann Arbor, MI); Greg Salenbien (Britton, MI)
Assignee: Tenneco Inc.
F02F3/14C23C4/02C23C4/06C23C4/073C23C4/10C23C4/11C23C4/12C23C4/126C23C4/18C23C28/321C23C28/3215C23C28/3455C23C28/36F02F3/0084F02F3/26
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Quick Facts
Patent No.
US 10,578,050
App. No.
15/354,001
Granted
Mar 3, 2020
Kind
B2
Abstract

A piston for a diesel engine is provided. The piston includes a thermal barrier coating applied to a crown formed of steel. A layer of a metal bond material is first applied to a combustion surface of the crown, followed by a gradient structure including a mixture of the metal bond material and a ceramic material, followed by a layer of the ceramic material. The ceramic material includes at least one of ceria, ceria stabilized zirconia, yttria stabilized zirconia, calcia stabilized zirconia, magnesia stabilized zirconia, and zirconia stabilized by another oxide. The thermal barrier coating is applied by a thermal spray process or HVOF. The thermal barrier coating has a porosity of 2% by vol. to 25% vol., based on the total volume of the thermal barrier coating, a thickness of less than 1 mm, and a thermal conductivity of less than 1.00 W/m·K.

Claims (48)

1. A piston, comprising:

a body portion formed of metal;

said body portion including a crown presenting a combustion surface;

a thermal barrier coating applied to said crown and extending from said combustion surface to an exposed surface;

said thermal barrier coating including a mixture of a metal bond material and a ceramic material;

the amount of ceramic material present in the mixture increasing toward said exposed surface, and

said thermal barrier coating has a thermal conductivity of less than 0.5 W/m·K.

2. The piston of claim 1 , wherein a porosity of said ceramic material is 2% by vol. to 25% vol., based on the total volume of said ceramic material.

3. The piston of claim 1 , wherein said thermal barrier coating has a thickness extending from said combustion surface to said exposed surface, and said thickness of said thermal barrier coating is less than 1 mm.

4. The piston of claim 1 , wherein said ceramic material of said thermal barrier coating includes at least one of ceria, ceria stabilized zirconia, yttria stabilized zirconia, calcia stabilized zirconia, magnesia stabilized zirconia, and zirconia stabilized by another oxide.

5. The piston of claim 1 , wherein said ceramic material consists of ceria stabilized zirconia.

6. The piston of claim 1 , wherein said thermal barrier coating includes a layer of said metal bond material applied directly to said combustion surface of said crown, said thermal barrier coating has a thickness extending from said combustion surface to said exposed surface, and 5% to 20% of said thickness of said thermal barrier coating consists of said layer of metal bond material;

said thermal barrier coating includes said mixture applied directly to said layer of metal bond material, the amount of said ceramic material present in said mixture increases continuously from said layer of said metal bond material toward said exposed surface; and

said thermal barrier coating includes a layer of said ceramic material applied directly to said mixture and extending to said exposed surface, and 5% to 50% of said thickness of said thermal barrier coating consists of said layer of said ceramic material.

7. The piston of claim 1 , wherein said metal bond material includes at least one alloy selected from the group consisting of CoNiCrAlY, NiCrAlY, NiCr, NiAl, NiCrAl, NiAlMo, and NiTi.

8. The piston of claim 1 , wherein said combustion surface of said crown to which said thermal barrier coating is applied is free of any features having a radius of less than 0.1 mm.

9. The piston of claim 1 , wherein said thermal barrier coating applied to said combustion surface has a bond strength of at least 2000 psi when tested according to ASTM C633.

10. The piston of claim 1 , wherein said thermal barrier coating is applied to a first portion of said combustion surface and not applied to a second portion of said combustion surface, and said thermal barrier coating has a thickness of not greater than 0.380 mm along said first portion.

11. The piston of claim 1 , wherein said body portion is formed of steel, said body portion includes no phosphate, and no phosphate is present on said combustion surface of said crown to which said thermal barrier coating is applied;

said crown extends circumferentially about a center axis from an upper end toward a lower end of said body portion;

said combustion surface of said crown includes a combustion bowl extending from an outer rim, and said combustion bowl includes an apex at said center axis;

said crown includes ring grooves located at an outer diameter surface and extending circumferentially about said center axis;

said crown includes ring lands spacing said ring grooves from one another and from said combustion surface;

said combustion surface of said crown to which said thermal barrier coating is applied is free of any features having a radius of less than 0.1 mm, or said crown includes a chamfer extending from said combustion surface to one of said ring lands located adjacent said combustion surface;

said body portion includes a pair of pin bosses spaced from one another about said center axis and depending from said crown to said lower end, each of said pin bosses defining a pin bore;

said body portion includes a pair of skirt sections spacing said pin bosses from one another about said center axis and depending from said crown to said lower end;

said thermal barrier coating is applied to at least one of said ring lands;

said ceramic material of said thermal barrier coating includes at least one of ceria, ceria stabilized zirconia, yttria stabilized zirconia, calcia stabilized zirconia, magnesia stabilized zirconia, and zirconia stabilized by another oxide;

said ceramic material has a porosity of 2% by vol. to 15% by vol., based on the total volume of said ceramic material;

said metal bond material includes at least one alloy selected from the group consisting of CoNiCrAlY, NiCrAlY, NiCr, NiAl, NiCrAl, NiAlMo, and NiTi;

said thermal barrier coating includes said metal bond material in an amount of 5% by vol. to 33% by vol. %, based on the total volume of said thermal barrier coating;

said thermal barrier coating includes a layer of said metal bond material applied directly to said combustion surface of said crown, said thermal barrier coating has a thickness extending from said combustion surface to an exposed surface, and 5% to 20% of said thickness of said thermal barrier coating consists of said layer of said metal bond material;

said thermal barrier coating includes said mixture applied directly to said layer of said metal bond material, 30% to 90% of said thickness of said thermal barrier coating consists of said mixture, the amount of said ceramic material present in said mixture increases continuously from said layer of said metal bond material toward said exposed surface;

said thermal barrier coating includes a layer of said ceramic material applied directly to said mixture and extending to said exposed surface, and 5% to 50% of said thickness of said thermal barrier coating consists of said layer of said ceramic material;

said thickness of said thermal barrier coating is not greater than 0.7 mm;

said thermal barrier coating has a specific heat of 480 J/kg·K to 610 J/kg·K at temperatures between 40 and 700° C.;

said thermal barrier coating applied to said combustion surface has a bond strength of at least 2000 psi when tested according to ASTM C633.

12. The piston of claim 1 , wherein the thermal barrier coating has a thickness of not greater than 0.38 mm.

13. The piston of claim 1 , wherein said exposed surface of said thermal barrier coating has a surface roughness Ra of less than 15 μm and a surface roughness Rz of not greater than ≤110 μm.

14. A piston, comprising:

a body portion formed of metal;

said body portion including a crown;

a thermal barrier coating applied to said crown;

said thermal barrier coating including a mixture of a metal bond material and a ceramic material;

said thermal barrier coating having a thermal conductivity of less than 0.5 W/m·K; and

an outer layer formed of metal applied to said thermal barrier coating.

15. The piston of claim 14 , wherein said outer layer includes nickel.

16. The piston of claim 14 , wherein said outer layer has a thickness of 1 to 50 microns.

Assignments (19)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 20, 2025
From: TENNECO INC.
To: FEDERAL-MOGUL POWERTRAIN LLC
Reel/Frame 072553/0043 →
PATENT SECURITY AGREEMENT (ABL) Recorded Apr 7, 2023
From: TENNECO INC.; DRIV AUTOMOTIVE INC.; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL WORLD WIDE LLC; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 063268/0506 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS (FIRST LIEN) Recorded Nov 22, 2022
From: DRIV AUTOMOTIVE INC.; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL WORLD WIDE LLC; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INC.; THE PULLMAN COMPANY
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 061989/0689 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061971/0156 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVE TRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
Reel/Frame 061975/0218 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061975/0031 →
RELEASE OF SECURITY INTEREST Recorded Mar 18, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: FEDERAL-MOGUL PRODUCTS US, LLC, AS SUCCESSOR TO FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL WORLD WIDE, INC., AS SUCCESSOR TO FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC, AS SUCCESSOR TO FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL IGNITION, LLC, AS SUCCESSOR TO FEDERAL-MOGUL IGNITION COMPANY; TENNECO INC., AS SUCCESSOR TO FEDERAL-MOGUL LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 056886/0455 →
RELEASE OF SECURITY INTEREST Recorded Mar 18, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: FEDERAL-MOGUL PRODUCTS US, LLC, AS SUCCESSOR TO FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL WORLD WIDE, INC., AS SUCCESSOR TO FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC, AS SUCCESSOR TO FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL IGNITION, LLC, AS SUCCESSOR TO FEDERAL-MOGUL IGNITION COMPANY; TENNECO INC., AS SUCCESSOR TO FEDERAL-MOGUL LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 058392/0274 →
SECURITY AGREEMENT Recorded Mar 17, 2021
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 055626/0065 →
SECURITY AGREEMENT Recorded Dec 1, 2020
From: TENNECO INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 054555/0592 →
MERGER AND CHANGE OF NAME Recorded Jan 22, 2020
From: FEDERAL-MOGUL LLC; TENNECO INC.
To: TENNECO INC.
Reel/Frame 051583/0820 →
COLLATERAL TRUSTEE RESIGNATION AND APPOINTMENT, JOINDER, ASSUMPTION AND DESIGNATION AGREEMENT Recorded Oct 26, 2018
From: BANK OF AMERICA, N.A., AS CO-COLLATERAL TRUSTEE AND RESIGNING COLLATERAL TRUSTEE
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS CO-COLLATERAL TRUSTEE, SUCCESSOR COLLATERAL TRUSTEE
Reel/Frame 047630/0661 →
RELEASE OF SECURITY INTEREST Recorded Oct 22, 2018
From: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
To: FEDERAL-MOGUL LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL CHASSIS LLC; FEDERAL MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS, INC.
Reel/Frame 047276/0771 →
CONFIRMATORY GRANT OF SECURITY INTERESTS IN UNITED STATES PATENTS Recorded Oct 9, 2018
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVETRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL TRUSTEE
Reel/Frame 047223/0001 →
COLLATERAL TRUSTEE RESIGNATION AND APPOINTMENT AGREEMENT Recorded Apr 3, 2018
From: CITIBANK, N.A., AS COLLATERAL TRUSTEE
To: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 045822/0765 →
GRANT OF SECURITY INTEREST IN UNITED STATES PATENTS Recorded Sep 26, 2017
From: FEDERAL-MOGUL LLC; FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL WORLD WIDE, LLC
To: CITIBANK, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 044013/0419 →
GRANT OF SECURITY INTEREST IN UNITED STATES PATENTS Recorded Jun 23, 2017
From: FEDERAL-MOGUL LLC; FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL WORLD WIDE, INC.
To: CITIBANK, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 042963/0662 →
CHANGE OF NAME Recorded Mar 29, 2017
From: FEDERAL-MOGUL CORPORATION
To: FEDERAL-MOGUL LLC
Reel/Frame 042109/0104 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 22, 2017
From: LINETON, WARRAN BOYD; AZEVEDO, MIGUEL; SALENBIEN, GREG
To: FEDERAL-MOGUL CORPORATION
Reel/Frame 041346/0458 →
Continuity (2)
Provisional Application 62257993 · Nov 20, 2015
Related Publication 20170145952A1 · May 25, 2017