ULTRA HIGH-VISCOSITY ESTOLIDE BASE OILS AND METHOD OF MAKING THE SAME
Provided herein are methods of making estolide base oils, including those having a high kinematic viscosity. In certain embodiments, an ultra high-viscosity estolide base oil is prepared from hydroxy fatty acids derived from the hydrolysis of a first estolide base oil.
1 - 224 . (canceled)
225 . A composition comprising one or more compounds of Formula I, said composition having an EN selected from an integer or fraction of an integer that is equal to or greater than 5, wherein the EN is the average number of estolide linkages in compounds according to Formula I, and a kinematic viscosity selected from 425 to 550 cSt when measured at 40° C., wherein the one or more compounds are selected from:
wherein
x is, independently for each occurrence, an integer selected from 0 to 20;
y is, independently for each occurrence, an integer selected from 0 to 20;
n is equal to or greater than 0;
R 1 is an optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and
R 2 is an optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched,
wherein each fatty acid chain residue of said at least one compound is independently optionally substituted.
226 . The composition according to claim 225 , wherein
x is, independently for each occurrence, an integer selected from 0 to 14;
y is, independently for each occurrence, an integer selected from 0 to 14;
n is an integer selected from 0 to 20;
R 1 is an optionally substituted C 1 to C 22 alkyl that is saturated or unsaturated, and branched or unbranched; and
R 2 is an optionally substituted C 1 to C 22 alkyl that is saturated or unsaturated, and branched or unbranched, wherein each fatty acid chain residue is unsubstituted.
227 . The composition according to claim 226 , wherein n is an integer selected from 5 to 15.
228 . The composition according to claim 226 , wherein EN is selected from 5 to 20.
229 . The composition according to claim 226 , wherein
x+y is, independently for each chain, an integer selected from 13 to 15; and
n is an integer selected from 0 to 12.
230 . The composition according to claim 228 , wherein R 2 is a branched or unbranched C 1 to C 20 alkyl that is saturated.
231 . The composition according to claim 228 , wherein R 2 is selected from branched C 6 to C 12 alkyl.
232 . The composition according to claim 231 , wherein R 2 is 2-ethylhexyl.
233 . The composition according to claim 228 , wherein R 1 is selected from unsubstituted C 1 to C 20 alkyl that is unbranched and saturated or unsaturated.
234 . The composition according to claim 233 , wherein R 1 is saturated.
235 . The composition according to claim 228 , wherein x is, independently for each occurrence, selected from 7 to 10.
236 . The composition according to claim 228 , wherein x is, independently for each occurrence, selected from 7 and 8.
237 . The composition according to claim 235 , wherein y is, independently for each occurrence, selected from 7 and 8.
238 . The composition according to claim 235 , wherein y is, independently for each occurrence, selected from 5 to 8.
239 . The composition according to claim 236 , wherein y is 0 for each occurrence.
240 . The composition according to claim 237 , wherein said composition has a kinematic viscosity of 450 cSt to 500 cSt at 40° C.
241 . The composition according to claim 226 , wherein said composition exhibits an iodine value (IV) of less than 10 cg/g.
242 . The composition according to claim 226 , wherein said composition exhibits an iodine value (IV) of less than 5 cg/g.
243 . A method comprising contacting a gearbox with the composition according to claim 228 .
244 . A method comprising contacting a wind turbine with the composition according to claim 228 .