IP Library Granted Patent US 9,910,376
Granted Patent B1
US 9,910,376 · App. 15/355,670 · Granted Mar 6, 2018

Toner formulation having a silane surface treated on its outer surface and method of preparing the same

Inventors: Danielle Renee Ashley (Longmont, CO); Ligia Aura Bejat (Lexington, KY); Michael James Bensing (Lexington, KY); Ashley Schafer Grant (Lexington, KY); Cory Nathan Hammond (Winchester, KY); Rick Owen Jones (Berthoud, CO); John Joseph Kraseski (Lexington, KY); Jing X Sun (Lexington, KY)
Assignee: LEXMARK INTERNATIONAL, INC.
G03G9/09328G03G9/0819G03G9/0827G03G9/08711G03G9/08755G03G9/09307G03G9/09321G03G9/09335G03G9/09342G03G9/09364G03G9/09371G03G9/09392
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Quick Facts
Patent No.
US 9,910,376
App. No.
15/355,670
Granted
Mar 6, 2018
Kind
B1
Abstract

A chemically prepared toner composition according to one example embodiment includes a core including a first polymer binder, a colorant and a release agent; a shell that is formed around the core that includes a second polymer binder; and a borax coupling agent between the core and the shell and an alkoxysilane hydrocarbon or combination of different alkoxysilane hydrocarbons that are bonded to the outer surface of the shell using a hydrolytic deposition process. This successful alkoxysilane hydrocarbon surface treatment on the outer surface of the toner particle results in attaining a desirable charge stability in hot and humid environments and ultimately improving the quality of the toner, especially by reducing toner dusting, toner fuming and ultra-fine particles generation.

Claims (12)

1. A chemically prepared toner composition, comprising:

a core having an outer surface, the core having components including a first polymer binder, a colorant and a release agent;

a borax coupling agent located on the outer surface of the core;

a shell formed around the outer surface of the core and the borax coupling agent, the shell including a second polymer binder, wherein the core, the borax coupling agent and the shell form a toner particle having an outer surface; and

1,3-di-n-octyltetramethyldisiloxane and diethoxydimethylsilane located on the outer surface of the toner particle, wherein alkoxy groups found in the 1,3-di-n-octyltetramethyldisiloxane and the diethoxydimethylsilane covalently bond with functional groups located on the outer surface of the toner particle.

2. The chemically prepared toner of claim 1 , wherein the first polymer binder and the second polymer binder each include a polyester resin.

3. The chemically prepared toner of claim 1 , wherein the first polymer binder and the second polymer binder each include a styrene polymer.

4. A chemically prepared toner composition, comprising:

a core having an outer surface, the core having components including a first polymer binder, a colorant and a release agent;

a borax coupling agent located on the outer surface of the core;

a shell formed around the outer surface of the core and the borax coupling agent, the shell including a second polymer binder, wherein the core, the borax coupling agent, and the shell form a toner particle having an outer surface; and

n-octadecyltrimethoxysilane located on the outer surface of the toner particle, wherein alkoxy groups found in the n-octadecyltrimethoxysilane covalently bond with functional groups located on the outer surface of the toner particle.

Assignments (8)
SECURITY INTEREST Recorded Jan 5, 2026
From: LEXMARK INTERNATIONAL, INC.
To: BANK TRUST COMPANY, NATIONAL ASSOCIATION
Reel/Frame 074202/0192 →
SECURITY INTEREST Recorded Jan 5, 2026
From: LEXMARK INTERNATIONAL, INC.
To: BANK TRUST COMPANY, NATIONAL ASSOCIATION
Reel/Frame 074202/0293 →
SECURITY INTEREST Recorded Sep 23, 2025
From: LEXMARK INTERNATIONAL, INC.
To: CITIBANK, N.A.
Reel/Frame 073007/0118 →
SECURITY INTEREST Recorded Sep 23, 2025
From: LEXMARK INTERNATIONAL, INC.
To: JEFFERIES FINANCE LLC
Reel/Frame 073007/0346 →
RELEASE OF SECURITY INTEREST Recorded Jan 18, 2024
From: CHINA CITIC BANK CORPORATION LIMITED, GUANGZHOU BRANCH, AS COLLATERAL AGENT
To: LEXMARK INTERNATIONAL, INC.
Reel/Frame 066345/0026 →
CORRECTIVE ASSIGNMENT TO CORRECT THE INCORRECT U.S. PATENT NUMBER PREVIOUSLY RECORDED AT REEL: 046989 FRAME: 0396. ASSIGNOR(S) HEREBY CONFIRMS THE PATENT SECURITY AGREEMENT. Recorded Oct 24, 2018
From: LEXMARK INTERNATIONAL, INC.
To: CHINA CITIC BANK CORPORATION LIMITED, GUANGZHOU BRANCH, AS COLLATERAL AGENT
Reel/Frame 047760/0795 →
PATENT SECURITY AGREEMENT Recorded Aug 30, 2018
From: LEXMARK INTERNATIONAL, INC.
To: CHINA CITIC BANK CORPORATION LIMITED, GUANGZHOU BRANCH, AS COLLATERAL AGENT
Reel/Frame 046989/0396 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 28, 2017
From: ASHLEY, DANIELLE RENEE; BEJAT, LIGIA AURA; BENSING, MICHAEL JAMES; DAHLKE, AARON MICHAEL; GRANT, ASHLEY SCHAFER; HAMMOND, CORY NATHAN; JONES, RICK OWEN; KRASESKI, JOHN JOSEPH; SUN, JING X
To: LEXMARK INTERNATIONAL, INC.
Reel/Frame 044231/0851 →