Hydrophobic silica for electrophotographic toner composition
View Patent ↗The invention relates to a hydrophobic silica powder which is unprecedentedly insensitive to environmental humidity with which electrophotographic toner can possess stable electro static charge that leads to stable quality of printed image. The hydrophobic silica powder has the following physicochemical properties; average primary particle size (D) is 30-2000 nm, B*D<430 nm, while B stands for weight % of adsorbed water vapor on silica (100 weight %) when the partial pressure of water to the equilibrium vapor pressure of water at 25° C. is 80% and D stands for average primary particle size (nm) of the silica powder, B/C<2.7, while C stands for weight % of adsorbed water vapor on silica (100 weight %) when the partial pressure of water to the equilibrium vapor pressure of water at 25° C. is 20%, and carbon content>0.30 wt.-%.
1. A hydrophobic silica powder, which has the following physicochemical properties;
average primary particle size (D) is 30-2000 nm,
65<B*D<430, whilst B stands for weight % of adsorbed water vapor on silica (100 weight %) when the partial pressure of water to the equilibrium vapor pressure of water at 25° C. is 80% and D stands for average primary particle size (nm) of the silica powder,
B/C<2.7, whilst C stands for weight % of adsorbed water vapor on silica (100 weight %) when the partial pressure of water to the equilibrium vapor pressure of water at 25° C. is 20%, and
carbon content (weight %)>0.30.
2. The hydrophobic silica powder according to claim 1 , characterized in that its hydrophobicity is higher than 50%.
3. The hydrophobic silica powder according to claim 1 , characterized in that it is a colloidal silica powder.
4. The hydrophobic silica powder according to claim 1 , characterized in that the aspect ratio is 1.0-1.5.
5. The hydrophobic silica powder according to claim 1 , characterized in that the hydrophobicity is higher than 55%.
6. A process for the preparation of hydrophobic silica according to claim 1 , characterized in that it comprises the following steps:
a. preparation of the silica dispersion,
b. drying the dispersion of step a to obtain hydrophilic silica powder,
c. aging treatment of the silica powder of step b at a temperature between 100 and 170° C. and the temperature of step c is higher than the temperature of step b,
d. hydrophobizing the silica powder of step c.
7. The process for the preparation of hydrophobic silica according to claim 6 , characterized in that the silica dispersion in step a is prepared by reacting an alkoxy silane or alkaline water glass and acid.
8. The process for the preparation of hydrophobic silica according to claim 6 , characterized in that the drying in step b is carried out in a freeze dryer.
9. The process for the preparation of hydrophobic silica according to claim 6 , characterized in that the aging treatment of step c is carried out in a drying oven.
10. The process for the preparation of hydrophobic silica according to claim 6 , characterized in that the hydrophobizing of step d is carried out by spraying a hydrophobing agent on the silica of step c.
11. The process for the preparation of hydrophobic silica according to claim 10 , characterized in that the hydrophobing agent is an alkylsilane, a polydimethyl siloxane or a silazane.
12. A toner composition for electrophotography containing at least one hydrophobic silica powder according to claim 1 .