Surface-treated positive electrode active material for lithium secondary battery, method for preparing the same, and lithium secondary battery comprising the same
The present disclosure suppresses, by uniformly coating lithium transition metal composite oxide particles with Li w Nb x O y (1≤w≤8, 1≤x≤13, 1≤y≤20), a direct contact between a positive electrode active material and a liquid electrolyte and thereby suppresses a side reaction between the positive electrode active material and the liquid electrolyte, and improves stability at high temperatures and high voltages, and in particular, is effective in enhancing battery performance by forming Li 2 O—Nb 2 O 5 through reacting the coating layer with Li present on the surfaces of the lithium transition metal composite oxide particles.
1. A positive electrode active material for a lithium secondary battery comprising:
lithium transition metal composite oxide particles; and
a coating layer including Li w Nb x O y (1≤w≤8, 1≤x≤13, 1≤y≤20) formed on surfaces of the lithium transition metal composite oxide particles,
wherein the lithium transition metal composite oxide particles are represented by the following Chemical Formula 1:
Li 1+z [Ni a Co b Mn c ]O 2 (0≤ z≤ 0.6, 0.6≤ a≤ 1, 0≤ b, c≤ 1, z+a+b+c= 1), and [Chemical Formula 1]
wherein the coating layer further includes Li 2 O—Nb 2 O 5 ,
wherein the coating layer is included in 0.05% by weight to 3% by weight with respect to a total weight of the positive electrode active material.
2. The positive electrode active material for a lithium secondary battery of claim 1 , wherein the coating layer includes one or more types selected from the group consisting of LiNb 3 O 8 , Li 2 Nb 13 O 13 , Li 2 Nb 2 O 5 , Li 1.9 Nb 2 O 5 , Li 1.7 Nb 2 O 5 , LiNbO 2 , LiNbO 3 , Li 8 Nb 2 O 9 , Li 10 Nb 2 O 10 , Li 3 NbO 4 and Li 4 Nb 6 O 17 .
3. The positive electrode active material for a lithium secondary battery of claim 1 , wherein the Li 2 O—Nb 2 O 5 is formed by reacting the coating layer with Li present on the surfaces of the lithium transition metal composite oxide particles.
4. The positive electrode active material for a lithium secondary battery of claim 1 , wherein the coating layer has a thickness of 10 nm to 500 nm.
5. A positive electrode for a lithium secondary battery comprising:
a positive electrode active material;
a binder;
a conductor;
an additive; and
a solvent,
wherein the positive electrode active material is the positive electrode active material for a lithium secondary battery of claim 1 .
6. A lithium secondary battery comprising:
a positive electrode;
a negative electrode;
a liquid electrolyte; and
a separator,
wherein the positive electrode is the positive electrode for a lithium secondary battery of claim 5 .
7. A battery module comprising the lithium secondary battery of claim 6 as a unit cell.
8. A battery pack comprising the battery module of claim 7 .
9. A device comprising the battery pack of claim 8 .
10. The device of claim 9 , wherein the device is a power tool, electric vehicle, hybrid electric vehicle, plug-in hybrid electric vehicle or a system for power storage.
11. A method for preparing the positive electrode active material for a lithium secondary battery of claim 1 , the method comprising:
a) preparing a reaction raw material of a niobium salt and a lithium salt;
b) depositing a coating layer including Li w Nb x O y (1≤w≤8, 1≤x≤13, 1≤y≤20) on surfaces of lithium transition metal composite oxide particles represented by the following Chemical Formula 1:
Li 1+z [Ni a Co b Mn c ]O 2 (0.1≤ z≤ 0.6, 0.6≤ a≤ 1, 0≤ b, c≤ 1, z+a+b+c= 1), and [Chemical Formula 1]
c) forming Li 2 O—Nb 2 O 5 by reacting the coating layer with Li present on the surfaces of the lithium transition metal composite oxide particles, and
wherein the deposition in the step (b) is carried out using an atomic layer deposition method (ALD).
12. The method for preparing the positive electrode active material for a lithium secondary battery of claim 11 , wherein a thickness of the coating layer deposited on the surfaces of the lithium transition metal composite oxide particles is adjusted to a range of 10 nm to 500 nm by repeating the b) step 1 time to 30 times.