Well-treatment fluids composition
A well treatment fluid composition that includes a tetrakis(hydroxyorgano)phosphonium salt and 1,3-dimethylol-5,5-dimethylhydantoin. Methods for preparing a well treatment fluid composition and treating a subterranean formation are also presented.
1. A composition consisting of a tetrakis(hydroxyorgano)phosphonium salt, 1,3-dimethylol-5,5-dimethylhydantoin, and optionally one or more members selected from the group consisting of: oxidizing viscosity breakers, quaternary ammonium compounds, and polymers of an unsaturated carboxylic acid or copolymers of an unsaturated carboxylic add with a sulphonic acid, said polymers or copolymers being terminated by a mono- or di-phosphonated unsaturated carboxylic add group or having such monomers incorporated into the polymer backbone, wherein the composition achieves a reduction of bacteria to give a total kill at 5 hour contact time.
2. The composition of claim 1 , wherein the tetrakis(hydroxyorgano)phosphonium salt is selected from the group consisting of tetrakis(hydroxymethyl)phosphonium sulphate, tetrakis(hydroxymethyl)phosphonium chloride, tetrakis(hydroxymethyl)phosphonium phosphate, tetrakis(hydroxymethyl)phosphonium nitrate and tetrakis(hydroxymethyl)phosphonium oxalate.
3. The composition of claim 1 , wherein the composition includes an oxidizing viscosity breaker and the breaker is selected from the group consisting of hydrogen peroxide, sodium persulfate, encapsulated ammonium persulfate, and sodium chlorite.
4. The composition of claim 1 , wherein the mass ratio between the THP salt and 1,3-dimethylol-5,5-dimethylhydantoin is about 1:0.5 to about 1:25.
5. The composition of claim 4 further including at least one oxidizing viscosity breaker.
6. The composition of claim 1 , wherein the composition contains less than 0.2% free formaldehyde after 4 months storage at 50° C.
7. The composition of claim 4 , wherein the composition contains less than 0.2% free formaldehyde after 4 months storage at 50° C.