Method for testing cycle life of positive electrode active material for secondary battery
The present disclosure provides a method for testing a cycle life of a positive electrode active material for a secondary battery capable of predicting and assessing a cycle life of a positive electrode active material with high accuracy and excellent reliability in a short period of time using a simple method.
1. A method for testing a cycle life of a positive electrode active material for a secondary battery comprising:
(a) preparing a half-cell having a positive electrode and a negative electrode, wherein the positive electrode includes a positive electrode active material and the negative electrode includes lithium;
(b) charging the half-cell to 4.4 V to 4.5 V under a constant current condition, maintaining the half-cell for 5 hours to 10 hours in a voltage range of 4.4 V to 4.5 V at 50° C. to 80° C., and discharging the half-cell to 3.0 V under a constant voltage condition to complete a charge/discharge cycle, and measuring discharge capacity of the charge/discharge cycle;
(c) repeating step (b) for 5 to 10 charge/discharge cycles; and
(d) calculating a discharge capacity retention rate at each charge/discharge cycle with respect to discharge capacity at the first charge/discharge cycle using the measured discharge capacity at each charge/discharge cycle.
2. The method for testing a cycle life of a positive electrode active material for a secondary battery of claim 1 , wherein the charging step in each charge/discharge cycle is carried out under a constant current condition of 0.2 C to 0.5 C.
3. The method for testing a cycle life of a positive electrode active material for a secondary battery of claim 1 , wherein the maintaining step in each charge/discharge cycle is carried out for 8 hours to 10 hours in a voltage range of 4.45 V to 4.5 V at 60° C. to 70° C.
4. The method for testing a cycle life of a positive electrode active material for a secondary battery of claim 1 , wherein the positive electrode active material includes a lithium composite metal oxide having layered structure.
5. The method for testing a cycle life of a positive electrode active material for a secondary battery of claim 4 , wherein the lithium composite metal oxide is doped with any one, or two or more elements selected from the group consisting of Al, Cu, Fe, V, Cr, Ti, Zr, Zn, Ta, Nb, Mg, B, W and Mo.