CHEMICALLY STRENGTHENED GLASS
The present invention provides a chemically strengthened glass suitable for use in applications in which the chemically strengthened glass is desired to have chemically strengthened properties that differ from surface to surface. The present invention relates to a chemically strengthened glass having a first surface and a second surface which faces the first surface, in which the first surface has a depth of compressive stress layer DOL 1 (μm) which is larger by at least 3 μm than a depth of compressive stress layer DOL 2 (μm) of the second surface, the second surface has a surface compressive stress CS 2 (MPa) which is higher by at least 50 MPa than a surface compressive stress CS 1 (MPa) of the first surface, and the chemically strengthened glass satisfies the following relational expressions (2) and (3): [ Dh ( E )− Dh (1)]<0 (2) [ Dh ( E )− Dh (2)]>0 (3).
1 . A chemically strengthened glass having a first surface and a second surface which faces the first surface,
wherein the first surface has a depth of compressive stress layer DOL 1 (μm) which is larger by at least 3 μm than a depth of compressive stress layer DOL 2 (μm) of the second surface,
the second surface has a surface compressive stress CS 2 (MPa) which is higher by at least 50 MPa than a surface compressive stress CS 1 (MPa) of the first surface, and
the chemically strengthened glass satisfies the following relational expressions (2) and (3):
[ Dh ( E )− Dh (1)]<0 (2)
[ Dh ( E )− Dh (2)]>0 (3)
in which Dh(E) is a depth at which, when an edge surface of the chemically strengthened glass is examined with an EPMA, an integral of replacing-ion X-ray intensity from an outermost surface of the edge surface becomes S(E)/2, where S(E) is an integral of replacing-ion X-ray intensity from the outermost surface of the edge surface to a depth of 80 μm,
Dh(1) is a depth at which, when the first surface of the chemically strengthened glass is examined with an EPMA, an integral of replacing-ion X-ray intensity from an outermost surface of the first surface becomes S(1)/2, where S(1) is an integral of replacing-ion X-ray intensity from the outermost surface of the first surface to a depth of 80 μm, and
Dh(2) is a depth at which, when the second surface of the chemically strengthened glass is examined with an EPMA, an integral of replacing-ion X-ray intensity from an outermost surface of the second surface becomes S(2)/2, where S(2) is an integral of replacing-ion X-ray intensity from the outermost surface of the second surface to a depth of 80 μm.
2 . The chemically strengthened glass according to claim 1 , which satisfies the following relational expression (1):
(CS 1 −CS 2 )×(DOL 1 −DOL 2 )<−1,500 (1).
3 . The chemically strengthened glass according to claim 1 , wherein the depth of compressive stress layer DOL 1 (μm) of the first surface is 15 μm or larger.
4 . The chemically strengthened glass according to claim 1 , wherein the surface compressive stress CS 1 (MPa) of the first surface is 100 MPa or higher.
5 . The chemically strengthened glass according to claim 1 , wherein the depth of compressive stress layer DOL 2 (μm) of the second surface is 5 μm or larger.
6 . The chemically strengthened glass according to claim 1 , wherein the surface compressive stress CS 2 (MPa) of the second surface is 500 MPa or higher.
7 . The chemically strengthened glass according to claim 1 , which has a radius of curvature of 15,000 mm or larger.
8 . The chemically strengthened glass according to claim 1 , which has a radius of curvature of less than 15,000 mm.
9 . The chemically strengthened glass according to claim 1 , which is obtained by chemically strengthening a curved-surface glass substrate.