Compostable or biobased foams
The present invention describes compostable or biobased foams that are useful for fabricating foamed articles and methods for producing the same. The foams are produced using a compound comprising a compostable or biobased polyester and a blowing agent. Additives including plasticizers and chain extenders are optionally included in the compostable or biobased composition. These foams can be produced using conventional melt processing techniques, such as single and twin-screw extrusion processes. In one embodiment, foamed strand profiles are cooled and cut using conventional strand pelletizing equipment. In another embodiment, foamed beads are produced by cutting the foamed strand at the face of the extrusion die and the foamed bead or strand is subsequently cooled. The resulting compostable or biobased foamed bead has a specific gravity less than 0.15 g/cm 3 and the foam is compostable, as determined by ASTM D6400.
1. A method of making compostable or biobased foam beads comprising:
mixing a biobased polymer and a physical blowing agent that does not contain a volatile organic component in an extruder wherein the extruder has a temperature that is above a melting point of the biobased polymer and wherein a biobased polymer melt is formed;
extruding the biobased polymer melt by forcing the melt through an extrusion die opening to form an extrudate wherein the temperature at an exit of the extrusion die is about 30-50° C. lower than the melting temperature of the biobased polymer melt wherein the blowing agent expands within the extrudate upon exiting the extrusion die opening; and
cutting the extrudate at the face of the die to produce biobased foam beads.
2. The method of claim 1 further comprising cooling the extrudate after exiting the extruder by contacting the extrudate with a cooling agent selected from the group consisting of water, water vapor, air, carbon dioxide, and nitrogen gas.
3. The method of claim 1 further comprising supplying an additive to the mixture of the biobased polymer and the physical blowing agent.
4. The method of claim 3 wherein the additive comprises a compound selected from the group consisting of a chain extender, a plasticizer, an antioxidant, a light stabilizer, a fiber, a foaming additive, an antiblocking agent, a heat stabilizer, an impact modifier, a biocide, a compatibilizer, a tackifier, a colorant, a coupling agent, an antistatic agent, an electrically conductive filler, and a pigment.
5. The method of claim 1 wherein the biobased polymer comprises a polymer selected from the group consisting of polylactic acid, poly-L-lactic acid, poly-D-lactic acid, random copolymer of L-lactic acid and D-lactic acid, stereoregular copolymer of L-lactic acid and D-lactic acid, derivatives thereof, polycaprolactone, polyhydroxybutyric acid, polyhydroxyvaleric acid, polyethylene succinate, polybutylene succinate, polybutylene adipate, polymalic acid, polyglycolic acid, polysuccinate, polyoxalate, polybutylene diglycolate, and polydioxanone.
6. The method of claim 1 wherein the biobased polymer comprises polylactic acid.
7. The method of claim 1 wherein the physical blowing agent comprises a compound selected from the group consisting of water, carbon dioxide, sodium carbonate, calcium carbonate, potassium carbonate, magnesium carbonate, azodicarbonamide, nitrogen, and mixtures thereof.
8. The method of claim 1 wherein the blowing agent comprises about 0.05 to about 90 wt % of the final composition.
9. The method of claim 1 wherein the blowing agent includes a carrier.
10. The method of claim 4 wherein the additive comprises a chain extender and the chain extender comprises a multifunctional reactive polymer.
11. The method of claim 1 further comprising supplying a nucleating agent selected from the group consisting of talc, kaolin, mica, silica, calcium carbonate, barium sulfate, titanium oxide, aluminum oxide, clay bentonite, diatomaceous earth, and azodicarbonamide to the mixture of the biobased polymer and the physical blowing agent.
12. The method of claim 1 wherein the physical blowing agent comprises supercritical carbon dioxide.
13. The method of claim 1 further comprising molding the biobased foam beads into a three-dimensional shaped product by post-expanding the biobased foam bead.
14. The method of claim 1 further comprising pressurizing the biobased foam beads by pressurization of the biobased foam beads with a gas before molding to allow for expansion during molding.
15. The method of claim 1 , wherein the biobased polymer has a molecular weight of up to about 1000 daltons.
16. The method of claim 1 , wherein the biobased polymer has a melting point of no more than about 150° C.
17. The method of claim 1 , wherein the temperature profile from a feed to an exit of the extruder extends from about 210° C. at the feed to about 85° C. at the exit.
18. The method of claim 1 , wherein the temperature profile from a feed to an exit of the extruder extends from about 210° C. at the feed to about 135° C. at the exit.
19. The method of claim 1 , wherein the temperature profile from a feed to an exit of the extruder extends from about 210° C. at the feed to about 150° C. at the exit.