Golf balls having a core layer made from plasticized thermoplastic compositions
Multi-layered golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) comprising a thermoplastic composition, preferably including: a) ethylene acid copolymer, b) plasticizer, and c) cation source. Preferably, a fatty acid ester such as ethyl oleate is used as the plasticizer. The outer core layer is preferably formed from a thermoset composition such as polybutadiene rubber. The core layers have different hardness levels. For example, the inner core can have a positive, zero, or negative hardness gradient. The core assembly preferably has a positive hardness gradient extending across the entire assembly. The core structure and resulting ball have relatively good resiliency at given compressions.
1. A core assembly for a golf ball, comprising:
i) an inner core layer comprising a thermoplastic composition, the inner core having an outer surface hardness (H inner core surface ) and a center hardness (H inner core center ), the H inner core surface being greater than the H inner core center to provide a positive hardness gradient, the thermoplastic composition comprising:
a) an acid copolymer of ethylene and an α,β-unsaturated carboxylic acid, optionally including a softening monomer selected from the group consisting of alkyl acrylates and methacrylates;
b) a plasticizer; and
c) a cation source present in an amount sufficient to neutralize from about 0 to about 100% of all acid groups present in the composition;
and
ii) an outer core layer comprising a thermoset rubber composition, the outer core layer being disposed about the inner core layer and having an outer surface hardness (H outer surface of OC ) and a midpoint hardness (H midpoint of OC ), the H outer surface of OC being the same or less than the H midpoint of OC to provide a zero or negative hardness gradient,
wherein the center hardness of the inner core (H inner core center ) is in the range of about 10 Shore C to about 70 Shore C and the outer surface hardness of the outer core layer (H outer surface of OC ) is in the range of about 25 Shore C to about 95 Shore C to provide a positive hardness gradient across the core assembly.
2. The core assembly of claim 1 , wherein the thermoplastic composition further comprises a non-acid polymer selected from the group consisting of polyolefins, polyamides, polyesters, polyethers, polyurethanes, metallocene-catalyzed polymers, single-site catalyst polymerized polymers, ethylene propylene rubber, ethylene propylene diene rubber, styrenic block copolymer rubbers, alkyl acrylate rubbers, and functionalized derivatives thereof.
3. The core assembly of claim 1 , wherein the thermoset rubber composition comprises polybutadiene.
4. The core assembly of claim 1 , wherein the thermoplastic composition comprises about 3 to about 50% by weight plasticizer.
5. The core assembly of claim 4 , wherein the plasticizer is a fatty acid ester.
6. The core assembly of claim 5 , wherein the plasticizer is ethyl oleate.