Lithium secondary battery
Provided is a lithium secondary battery containing a cathode active material capable of preventing decreases in power and cycle life occurring at the time of adding a sulfur based additive used in order to improve high-temperature storage characteristics to an electrolyte.
1. A lithium secondary battery comprising a cathode, an anode, and a non-aqueous electrolyte,
wherein the non-aqueous electrolyte contains a sulfur based additive, and
the cathode contains a cathode active material containing a lithium-metal oxide particle,
the lithium-metal oxide particle including a core part represented by Chemical Formula 5 and a surface part represented by Chemical Formula 6, a concentration of Ni being decreased in a surface direction within a concentration gradient layer between the core part and the surface part, a concentration of Co being constant between the core part and the surface part and a concentration of Mn being increased in the surface direction between the core part and the surface part:
Li x4 Ni a4 Co b4 Mn c4 O y4 [Chemical Formula 5]
Li x5 Ni a5 Co b5 Mn c5 O y5 [Chemical Formula 6]
wherein in Chemical Formulas 5 and 6, x4, x5, y4, y5, a4, a5, b4, b5, c4, and c5 satisfy 0<x4≤1.1, 0<x5≤1.1, 2≤y4≤2.02, 2≤y5≤2.02, 0.800≤a4≤1.000, 0≤a5≤0.770, 0<b4≤0.11, 0<b5≤0.11, 0≤c4≤0.090, 0.120≤c5≤1.000, 0<a4+b4+c4≤1, and 0≤a5+b5+c5≤1,
wherein the core part has a radius of equal to or greater than 0.6 μm from the center of the lithium-metal oxide particle, and the concentration gradient layer has a width of equal to or greater than 0.2 μm.
2. The lithium secondary battery of claim 1 , wherein the sulfur based additive contained in the non-aqueous electrolyte is 1,3-propane sultone, 1,3-propene sultone, or a mixture thereof.
3. The lithium secondary battery of claim 2 , wherein the sulfur based additive contained in the non-aqueous electrolyte is 1,3-propane sultone, and a content of 1,3 propane sultone is 0.5 to 2.0 wt %.
4. The lithium secondary battery of claim 2 , wherein the sulfur based additive contained in the non-aqueous electrolyte is 1,3-propene sultone, and a content of 1,3 propene sultone is 0.5 to 2.0 wt %.
5. The lithium secondary battery of claim 2 , wherein the sulfur based additive contained in the non-aqueous electrolyte is a mixture of 1,3-propane sultone and 1,3-propene sultone, and a content of the mixture is 1.0 to 4.0 wt %.