Dual-terminated polyamide for high speed spinning application
Methods of producing a polyamide filaments and fibers are provided. The methods include providing a dual-terminated polyamide and spinning the dual-terminated polyamide at a speed of 3500 m/min to 8000 m/min to form a fiber. In one embodiment, the polyamide has an amine endgroup concentration of 25 mmol/kg to 40 mmol/kg and a carboxyl endgroup concentration of 18 mmol/kg to 50 mmol/kg. Fibers and yarns comprising polyamide filaments and fibers formed from the method are also disclosed.
1. A method of producing a plurality of fibers, the method comprising:
providing a dual-terminated polyamide-6 (PA-6) having an amine endgroup concentration of 25 mmol/kg to 40 mmol/kg, a carboxyl endgroup concentration of 18 mmol/kg to 50 mmol/kg, and a relative viscosity of 2.6 RV to 3.0 RV; and
spinning the dual-terminated polyamide-6 (PA-6) at a speed of 3500 m/min to 8000 m/min to form the fibers.
2. The method of claim 1 , wherein spinning includes heating the dual-terminated polyamide-6 (PA-6) to a temperature of 230° C. to 300° C.
3. The method of claim 1 , wherein spinning includes extruding the dual-terminated polyamide-6 (PA-6) through a spinneret including tri-lobal shape holes, wherein the tri-lobal shape holes define an R value of 0 to 0.1 mm.
4. The method of claim 1 , wherein the polyamide fibers each comprises a plurality of filaments, and the polyamide fibers have a denier per filament of 1.5 to 5.
5. The method of claim 1 , wherein the dual-terminated polyamide-6 (PA-6) includes amine endgroups and carboxyl endgroups with different, chemically distinct terminators.
6. The method of claim 1 , wherein the dual-terminated polyamide-6 (PA-6) has an amine endgroup concentration of 27 mmol/kg to 37 mmol/kg.
7. The method of claim 1 , wherein the dual-terminated polyamide-6 (PA-6) has an amine endgroup concentration of 30 mmol/kg to 35 mmol/kg.
8. The method of claim 1 , wherein the dual-terminated polyamide-6 (PA-6) has a carboxyl endgroup concentration of 20 mmol/kg to 40 mmol/kg.
9. The method of claim 1 , wherein the dual-terminated polyamide-6 (PA-6) has a carboxyl endgroup concentration of 22 mmol/kg to 30 mmol/kg.
10. The method of claim 1 , wherein the dual-terminated polyamide-6 (PA-6) has a relative viscosity of 2.7 RV to 3.0 RV.
11. The method of claim 1 , wherein the dual-terminated polyamide-6 (PA-6) has a relative viscosity of 2.8 RV to 3.0 RV.
12. The method of claim 1 , wherein the dual-terminated polyamide-6 (PA-6) has a polydispersity index less than 1.8.
13. The method of claim 1 , wherein the dual-terminated polyamide-6 (PA-6) has an extractables content of less than 0.8 wt. %.
14. The method of claim 1 , wherein prior to the spinning step, the dual-terminated polyamide-6 (PA-6) is heated to a temperature of 240° C. to 300° C.
15. The method of claim 1 , wherein prior to the spinning step, the dual-terminated polyamide-6 (PA-6) is heated to a temperature of 250° C. to 290° C.
16. The method of claim 1 , wherein the spinning step is carried out at a speed of 4000 m/min to 6000 m/min.
17. The method of claim 4 , wherein the polyamide fibers each comprises a plurality of filaments, and the polyamide fibers have a denier per filament of 1.7 to 5.
18. The method of claim 4 , wherein the polyamide fibers each comprises a plurality of filaments, and the polyamide fibers have a denier per filament of 1.7 to 3.