Grip for sporting goods and golf club
View Patent ↗An object of the present invention is to provide a grip for sporting goods containing an acrylonitrile-butadiene based rubber as a base rubber and having an excellent grip performance and sustainability of grip performance under a wet condition. The present invention provides a grip for sporting goods comprising an outermost surface layer formed from a surface layer rubber composition, wherein the surface layer rubber composition contains (A) a base rubber and (B) a resin having a softening point in a range from 5° C. to 120° C., (A) the base rubber contains an acrylonitrile-butadiene based rubber, and (B) the resin is at least one type selected from the group consisting of a hydrogenated rosin ester, a disproportionated rosin ester, an ethylene-vinyl acetate copolymer, a coumarone resin, a phenol resin, a xylene resin and a styrene resin.
1. A grip for sporting goods comprising an outermost surface layer formed from a surface layer rubber composition and an inner layer,
wherein the surface layer rubber composition contains (A) a base rubber and (B) a resin having a softening point in a range from 5° C. to 120° C.,
(A) the base rubber contains an acrylonitrile-butadiene based rubber,
the acrylonitrile-butadiene based rubber is at least one type selected from the group consisting of a carboxyl-modified acrylonitrile-butadiene rubber, a hydrogenated acrylonitrile-butadiene rubber and a carboxyl-modified hydrogenated acrylonitrile-butadiene rubber,
(B) the resin is at least one type selected from the group consisting of a hydrogenated rosin ester, a disproportionated rosin ester, an ethylene-vinyl acetate copolymer, a coumarone resin, a phenol resin, a xylene resin and a styrene resin, and
the inner layer is formed from a rubber composition containing an acrylonitrile-butadiene based rubber as a base rubber.
2. A golf club comprising a shaft, a head provided on one end of the shaft, and a grip provided on another end of the shaft, wherein the grip comprises an outermost surface layer formed from a surface layer rubber composition and an inner layer,
the surface layer rubber composition contains (A) a base rubber and (B) a resin having a softening point in a range from 5° C. to 120° C.,
(A) the base rubber contains an acrylonitrile-butadiene based rubber,
the acrylonitrile-butadiene based rubber is at least one type selected from the group consisting of a carboxyl-modified acrylonitrile-butadiene rubber, a hydrogenated acrylonitrile-butadiene rubber and a carboxyl-modified hydrogenated acrylonitrile-butadiene rubber,
(B) the resin is at least one type selected from the group consisting of a hydrogenated rosin ester, a disproportionated rosin ester, an ethylene-vinyl acetate copolymer, a coumarone resin, a phenol resin, a xylene resin and a styrene resin, and
the inner layer is formed from a rubber composition containing an acrylonitrile-butadiene based rubber as a base rubber.
3. The grip for sporting goods according to claim 1 , wherein an amount of (B) the resin is 2 parts by mass or more and 40 parts by mass or less with respect to 100 parts by mass of (A) the base rubber.
4. The grip for sporting goods according to claim 3 , wherein an amount of the acrylonitrile-butadiene based rubber in (A) the base rubber is 50 mass % or more.
5. The grip for sporting goods according to claim 4 , the acrylonitrile-butadiene based rubber is at least one type selected from the group consisting of a carboxyl-modified acrylonitrile-butadiene rubber and a carboxyl-modified hydrogenated acrylonitrile-butadiene rubber.
6. The grip for sporting goods according to claim 5 , the acrylonitrile-butadiene based rubber is a carboxyl-modified hydrogenated acrylonitrile-butadiene rubber.
7. The grip for sporting goods according to claim 6 , wherein (B) the resin is at least one type selected from the group consisting of the hydrogenated rosin ester, the disproportionated rosin ester, the ethylene-vinyl acetate copolymer and the coumarone resin.
8. The grip for sporting goods according to claim 7 , wherein (B) the resin is at least one type selected from the group consisting of the hydrogenated rosin ester and the ethylene-vinyl acetate copolymer.
9. The grip for sporting goods according to claim 8 , wherein (B) the resin is the hydrogenated rosin ester, and an acid value of the hydrogenated rosin ester is 2 mgKOH/g or more and 200 mgKOH/g or less.
10. The grip for sporting goods according to claim 8 , wherein (B) the resin is the ethylene-vinyl acetate copolymer, and an amount of vinyl acetate in the ethylene-vinyl acetate copolymer is 10 mass % or more and 80 mass % or less.
11. The grip for sporting goods according to claim 8 , wherein a material hardness (Shore A hardness) of the surface layer rubber composition is 30 or more and 80 or less.
12. The grip for sporting goods according to claim 11 , wherein the grip for sporting goods comprises a cylindrical portion composed of a cylindrical inner layer and a cylindrical outer layer covering the cylindrical inner layer,
the cylindrical outer layer is formed from the surface layer rubber composition, and
a density (D in ) of the cylindrical inner layer is lower than a density (D out ) of the cylindrical outer layer.
13. The grip for sporting goods according to claim 12 , wherein the density (D in ) of the cylindrical inner layer ranges from 0.20 g/cm 3 to 0.50 g/cm 3 .
14. The golf club according to claim 2 , wherein an amount of (B) the resin is 2 parts by mass or more and 40 parts by mass or less with respect to 100 parts by mass of (A) the base rubber.
15. The golf club according to claim 14 , wherein an amount of the acrylonitrile-butadiene based rubber in (A) the base rubber is 50 mass % or more.
16. The golf club according to claim 15 , the acrylonitrile-butadiene based rubber is at least one type selected from the group consisting of a carboxyl-modified acrylonitrile-butadiene rubber and a carboxyl-modified hydrogenated acrylonitrile-butadiene rubber.
17. The golf club according to claim 16 , the acrylonitrile-butadiene based rubber is a carboxyl-modified hydrogenated acrylonitrile-butadiene rubber.
18. The golf club according to claim 17 , wherein (B) the resin is at least one type selected from the group consisting of the hydrogenated rosin ester, the disproportionated rosin ester, the ethylene-vinyl acetate copolymer and the coumarone resin.
19. The golf club according to claim 18 , wherein (B) the resin is at least one type selected from the group consisting of the hydrogenated rosin ester and the ethylene-vinyl acetate copolymer.
20. The golf club according to claim 19 , wherein (B) the resin is the hydrogenated rosin ester, and
an acid value of the hydrogenated rosin ester is 2 mgKOH/g or more and 200 mgKOH/g or less.
21. The golf club according to claim 19 , wherein (B) the resin is the ethylene-vinyl acetate copolymer, and
an amount of vinyl acetate in the ethylene-vinyl acetate copolymer is 10 mass % or more and 80 mass % or less.
22. The golf club according to claim 19 , wherein a material hardness (Shore A hardness) of the surface layer rubber composition is 30 or more and 80 or less.
23. The golf club according to claim 22 , wherein the grip comprises a cylindrical portion composed of a cylindrical inner layer and a cylindrical outer layer covering the cylindrical inner layer,
the cylindrical outer layer is formed from the surface layer rubber composition, and
a density (D in ) of the cylindrical inner layer is lower than a density (D out ) of the cylindrical outer layer.
24. The golf club according to claim 23 , wherein the density (D in ) of the cylindrical inner layer ranges from 0.20 g/cm 3 to 0.50 g/cm 3 .