Porous electrode substrate, method for manufacturing same, membrane electrode assembly, polymer electrolyte fuel cell, precursor sheet, and fibrillar fibers
Provided is a porous electrode substrate having excellent thickness precision, gas permeability and conductivity, handling efficiency, low production costs and a high carbonization rate during carbonization. Also provided are a method for manufacturing such a substrate, a precursor sheet and fibrillar fiber used for forming such a substrate, along with a membrane electrode assembly and a polymer electrolyte fuel cell that contain such a substrate. The method for manufacturing a porous electrode substrate includes step (1) for manufacturing a precursor sheet in which short carbon fibers (A) and carbon fiber precursor (b) are dispersed, and step (2) for carbonizing the precursor sheet, and the volume contraction rate of carbon fiber precursor (b) in step (2) is 83% or lower. The present invention also relates to a porous electrode substrate obtained by such a manufacturing method, a precursor sheet and fibrillar fiber used for forming the substrate, along with a membrane electrode assembly and a polymer electrolyte fuel cell containing the substrate.
1. A method for manufacturing a porous electrode substrate, the method comprising hot pressing a precursor sheet, wherein said hot pressing is at a temperature ranging from 120 to 200° C. and at a pressure ranging from 20 kPa to 10 MPa and carbonizing the precursor sheet, wherein the precursor sheet comprises short carbon fibers (A) and carbon fiber precursor (b) dispersed therein, wherein a volume contraction rate of the carbon fiber precursor (b) is from 47% to 79% during the carbonizing, wherein the carbonizing is conducted at a temperature of at least 1000° C., and wherein the carbon fiber precursor (b) is at least one of: a short carbon fiber precursor comprising an acrylonitrile-based polymer with 95% by mass or more of acrylonitrile units; and a fibrillar carbon fiber precursor comprising an acrylonitrile-based polymer with 95% by mass or more of acrylonitrile units.
2. The method according to claim 1 , wherein the carbon fiber precursor (b) comprises carbon powder.
3. The method according to claim 1 , further comprising entangling the precursor sheet before the hot pressing.
4. The method according to claim 1 , further comprising oxidizing the precursor sheet between the carbonizing and the hot pressing steps.
5. The method according to claim 1 , wherein the carbonizing is conducted at a temperature of 1000° C. to 3000° C.
6. The method according to claim 1 , wherein the carbonizing is conducted at a temperature of 1000° C. to 2200° C.
7. A porous electrode substrate obtained by the method of claim 1 .
8. A membrane electrode assembly, comprising the porous electrode substrate according to claim 7 .
9. A solid electrolyte polymer fuel cell, comprising the membrane electrode assembly according to claim 8 .