MODIFIED ASPHALT BINDERS AND COMPOSITIONS
Binder compositions comprising a bituminous binder and a rheology modifier are disclosed. The rheology modifier comprises a blend of a polyol ester and a C 8 -C 24 free fatty acid component. Asphalt compositions comprising the modified binder compositions are also disclosed. The rheology modifiers help to improve the high-temperature properties of bituminous binders without sacrificing low-temperature performance. The modified binders and asphalt compositions expand the utility of reclaimed asphalt, including reclaimed asphalt shingles and reclaimed asphalt pavement, thereby helping the road construction industry reduce its reliance on virgin, non-renewable materials.
1 . A binder composition comprising:
(a) a bituminous binder; and
(b) 0.05 to 20 wt. %, based on the amount of binder composition, of a rheology modifier which comprises: (i) 5-50 wt. %, based on the amount of rheology modifier, of a polyol ester, and (ii) a C 8 -C 24 free fatty acid component having an acid value of at least 180 mg KOH/g.
2 . The binder composition of claim 1 , wherein the bituminous binder comprises reclaimed asphalt pavement binder, reclaimed asphalt shingle binder, or a mixture thereof, optionally in combination with a virgin binder or a performance-grade binder.
3 . The binder composition of claim 1 , wherein the rheology modifier comprises 50 to 95 wt. % based on the amount of rheology modifier, of the C 8 -C 24 free fatty acid component.
4 . The binder composition of claim 1 , wherein the rheology modifier comprises 10 to 50 wt. % based on the amount of rheology modifier, of the polyol ester and wherein the polyol ester derives from a thermally stable polyol and at least one molar equivalent of a C8-C24 fatty acid.
5 . The binder composition of claim 1 , wherein the polyol ester is selected from the group consisting of triethylolpropane, trimethylolpropane, neopentyl glycol, pentaerythritol, trimethylolpropane tallate, ethylene glycol Monomerate, neopentyl glycol Monomerate, 2-ethylhexyl Monomerate, and glycerol Monomerate, and mixtures thereof.
6 . The binder composition of claim 1 , wherein the C 8 -C 24 free fatty acid component is a tall oil fatty acid.
7 . The binder composition of claim 1 , wherein the rheology modifier has an acid value within the range of 100 to 190 mg KOH/g.
8 . The binder composition of claim 1 , wherein the rheology modifier has an iodine value in the range of 110 to 160 mg 12/g.
9 . The binder composition of claim 1 , wherein the bituminous binder comprises 10-100% of reclaimed asphalt shingle binder.
10 . The binder composition of claim 1 , comprising 50 to 70 wt. % of a performance-grade binder, 0.05 to 20 wt. %, based on the amount of binder composition, of the rheology modifier, and remainder a bituminous binder consisting essentially of reclaimed asphalt shingle binder.
11 . An asphalt composition comprising aggregate and the binder composition of claim 1 .
12 . A paved road surface, road subsurface, runway, driveway, parking lot, road shoulder, bridge, bridge abutment, or unpaved road comprising the asphalt composition of claim 11 .
13 . An asphalt emulsion composition comprising: a) an aqueous phase comprising at least an emulsifying agent, and b) a dispersion phase comprising a bituminous binder and 0.05 to 20 wt. %, based on the amount of bituminous binder, of a rheology modifier which comprises: (i) 5-50 wt. %, based on the amount of rheology modifier, of a polyol ester, and (ii) a C 8 -C 24 free fatty acid component having an acid value of at least 180 mg KOH/g.
14 . The asphalt emulsion composition of claim 13 , wherein the free fatty acid component has an acid value of at least 190 mg KOH/g.
15 . The asphalt emulsion composition of claim 13 , wherein the polyol ester derives from a thermally stable polyol and at least one molar equivalent of a C 8 -C 24 fatty acid.
16 . The asphalt emulsion composition of claim 13 , wherein the thermally stable polyol is selected from the group consisting of triethylolpropane, trimethylolpropane, neopentyl glycol, pentaerythritol, and mixtures thereof.
17 . The asphalt emulsion composition of claim 13 , wherein the rheology modifier is present in an amount of 0.1 to 15 wt. % of the total weight of the asphalt emulsion.
18 . The asphalt emulsion composition of claim 13 , wherein the bituminous binder is present in an amount of 20 to 70 wt. % of the total weight of the asphalt emulsion.
19 . The asphalt emulsion composition of claim 13 , wherein the aqueous phase further comprises an acrylic polymer or copolymer.
20 . A method for rejuvenating asphalt pavement comprising:
applying to the asphalt pavement a composition comprising an aqueous emulsion of at least an emulsifying agent, a bituminous binder; and 0.05 to 20 wt. %, based on the amount of bituminous binder, of a rheology modifier which comprises: (i) 5-50 wt. %, based on the amount of rheology modifier, of a polyol ester, and (ii) a C 8 -C 24 free fatty acid component having an acid value of at least 180 mg KOH/g, and
drying the aqueous emulsion.