Heavy oil rheology modifiers for flow improvement during production and transportation operations
The present invention generally relates to methods for enhancing production and transportation of heavy and extra-heavy crude oil and for reducing the growth of asphaltene flocculants or hindering their formation, the methods comprising contacting an oil-soluble composition that comprises polyetheramines, tallow amines, tallow diamines, alkylphenol-formaldehyde resins, reaction products of alpha-olefin, maleic anhydride and pentaerythritol, or a combination thereof, with the heavy or extra-heavy crude oil.
1. A method for enhancing the production or transportation of crude oil, the method comprising contacting the crude oil with an oil-soluble composition that reduces the viscosity of the crude oil,
wherein the oil-soluble composition comprises:
a nonyl phenyl polyetheramine and at least one of an alkoxylated t-butyl-nonyl phenol formaldehyde resin, an alkoxylated t-butyl phenol formaldehyde resin, an alkoxylated poly(bisphenol A diglycidyl ether), a nonyl phenol formaldehyde resin, or a dinonyl-nonyl phenol formaldehyde resin.
2. The method of claim 1 , wherein the crude oil is heavy or extra-heavy and has an API gravity of about 5 to about 20.
3. The method of claim 1 , wherein the oil-soluble composition reduces the viscosity of crude oil by from about 5% to about 65% in downstream and upstream production or in transportation pipelines as compared to an otherwise identical crude oil not contacted with the oil-soluble composition.
4. The method of claim 1 , wherein the oil-soluble composition comprises from about 5 wt. % to about 25 wt. % of the alkoxylated t-butyl-nonyl phenol formaldehyde resin, from about 5 wt. % to about 15 wt. % of the nonyl phenyl polyetheramine, from about 50 wt. % to about 80 wt. % of a limonene-containing asphaltene solvent, from about 5 wt. % to about 15 wt. % of a reaction product of α-olefin, maleic anhydride and pentaerithrytol, and from about 0.1 wt. % to about 1 wt. % dodecylbenzenesulfonic acid.
5. The method of claim 1 , wherein the oil-soluble composition comprises from about 5 wt. % to about 25 wt. % of the alkoxylated t-butyl-nonyl phenol formaldehyde resin, from about 5 wt. % to about 15 wt. % of the nonyl phenyl polyetheramine, from about 50 wt. % to about 80 wt. % of a xylene-containing asphaltene solvent, from about 5 wt. % to about 15 wt. % of a polyisobutylene succinic anhydride pentaerithrytol diester, and from about 0.1 wt. % to about 1 wt. % of dodecylbenzenesulfonic acid.
6. The method of claim 1 , wherein the oil-soluble composition comprises from about 2 wt. % to about 15 wt. % of the nonyl phenol formaldehyde resin, from about 2 wt. % to about 15 wt. % of the alkyl phenyl polyetheramine, from about 30 wt. % to about 60 wt. % of an aromatic solvent, and from about 30 wt. % to about 70 wt. % of ethylene glycol monobutyl ether.
7. A method for enhancing the production and transportation of crude oil, the method comprising contacting the crude oil with an oil-soluble composition, wherein the composition reduces the viscosity of the crude oil,
the oil-soluble composition comprises from about 10 wt. % to about 50 wt. % of an alkoxylated t-butyl-nonyl phenol formaldehyde resin, from about 2 wt. % to about 20 wt. % of a nonyl phenol formaldehyde resin; at least one of a nonyl phenyl polyetheramine, a reaction product of α-olefin, maleic anhydride and pentaerithrytol, an ethoxylated tallow amine; and further comprises, a dinonyl-nonyl phenol formaldehyde resin, an ethoxylated tallow diamine, a xylene-containing asphaltene solvent, a limonene-containing asphaltene solvent, a polyisobutylene succinic anhydride pentaerithrytol diester, dodecylbenzenesulfonic acid, an aromatic solvent, an alcohol or a combination thereof.
8. The method of claim 7 , wherein the oil-soluble composition comprises from about 10 wt. % to about 50 wt. % of the alkoxylated t-butyl-nonyl phenol formaldehyde resin, from about 2 wt. % to about 20 wt. % of the nonyl phenol formaldehyde resin, from about 1 wt. % to about 10 wt. % of the nonyl phenyl polyetheramine, from about 15 wt. % to about 25 wt. % of the limonene-containing asphaltene solvent, from about 1 wt. % to about 7 wt. % of the reaction product of α-olefin, maleic anhydride and pentaerithrytol, and from about 0.05 wt. % to about 0.15 wt. % of dodecylbenzenesulfonic acid.
9. The method of claim 7 , wherein the oil-soluble composition comprises from about 10 wt. % to about 50 wt. % of the alkoxylated t-butyl-nonyl phenol formaldehyde resin, from about 2 wt. % to about 20 wt. % of the nonyl phenol formaldehyde resin, from about 1 wt. % to about 7 wt. % the ethoxylated tallow amine, from about 15 wt. % to about 35 wt. % of the limonene-containing asphaltene solvent, and from about 0.05 wt. % to about 0.15 wt. % of dodecylbenzenesulfonic acid.
10. The method of claim 7 , wherein the oil-soluble composition comprises from about 10 wt. % to about 50 wt. % of the alkoxylated t-butyl-nonyl phenol formaldehyde resin, from about 2 wt. % to about 20 wt. % of the nonyl phenol formaldehyde resin, from about 1 wt. % to about 7 wt. % of the ethoxylated tallow amine, from about 15 wt. % to about 35 wt. % of the xylene-containing asphaltene solvent, from about 1 wt. % to about 7 wt. % of the polyisobutylene succinic anhydride pentaerithrytol diester, and from about 0.05 wt. % to about 0.15 wt. % of dodecylbenzenesulfonic acid.
11. The method of claim 7 , wherein the oil-soluble composition comprises from about 10 wt. % to about 50 wt. % of the alkoxylated t-butyl-nonyl phenol formaldehyde resin, from about 2 wt. % to about 20 wt. % of the nonyl phenol formaldehyde resin, from about 5 wt. % to about 15 wt. % of the ethoxylated tallow diamine, and from about 15 wt. % to about 35 wt. % of the limonene-containing asphaltene solvent.
12. The method of claim 7 , wherein the oil-soluble composition comprises from about 10 wt. % to about 50 wt. % of the alkoxylated t-butyl-nonyl phenol formaldehyde resin, from about 2 wt. % to about 20 wt. % of the nonyl phenol formaldehyde resin, from about 1 wt. % to about 7 wt. % of the nonyl phenyl polyetheramine, and from about 15 wt. % to about 35 wt. % of the limonene-containing asphaltene solvent.
13. The method of claim 7 , wherein the oil-soluble composition comprises from about 10 wt. % to about 50 wt. % of the alkoxylated t-butyl-nonyl phenol formaldehyde resin, from about 2 wt. % to about 20 wt. % of the nonyl phenol formaldehyde resin, and from about 5 wt. % to about 15 wt. % of the nonyl phenyl polyetheramine.
14. The method of claim 7 , wherein the oil-soluble composition comprises from about 10 wt. % to about 50 wt. % of the alkoxylated t-butyl-nonyl phenol formaldehyde resin, from about 2 wt. % to about 20 wt. % of the nonyl phenol formaldehyde resin, from about 2 wt. % to about 10 wt. % of the dinonyl-nonyl phenol formaldehyde resin, from about 15 wt. % to about 35 wt. % of the xylene-containing asphaltene solvent, and from about 1 wt. % to about 7 wt. % of the reaction product of α-olefin, maleic anhydride and pentaerithrytol.