Anode for lithium secondary battery and lithium secondary battery including the same
View Patent ↗Provided is an anode for a lithium secondary battery composed of a multi-layered structure including an electrode current collector, a first anode active material layer including a first anode active material formed on the electrode current collector, and a second anode active material layer including a second anode active material having relatively lower press density and relatively larger average particle diameter than the first anode active material. Since an anode according to an embodiment of the present invention may include a multi-layered active material layer including two kinds of anode active materials having different press densities and average particle diameters on an electrode current collector, porosity of the surface of the electrode may be improved even after a press process to improve ion mobility into the electrode. Thus, charge characteristics and cycle life of a lithium secondary battery may be improved.
1. A method of preparing an anode, the method comprising:
coating an electrode current collector with a first anode active material slurry including a first anode active material and a binder resin;
forming a first anode active material layer by drying the first anode active material slurry;
coating the first anode active material layer with a second anode active material slurry including a second anode active material and a binder resin;
forming a second anode active material layer by drying the second anode active material slurry; and
pressing the electrode current collector on which the first and second anode active material layers are formed,
wherein the second anode active material has a lower press density and a larger average particle diameter than the first anode material, and
wherein the first anode active material and the second anode active material each comprises crystalline carbon, amorphous carbon or a mixture thereof.
2. A method of preparing an anode, the method comprising:
coating an electrode current collector with a first anode active material slurry including a first anode active material and a binder resin;
coating the first anode active material layer with a second anode active material slurry including a second anode active material and a binder resin;
forming a multi-layered anode active material layer by drying the first and second anode active material slurries; and
pressing the electrode current collector on which the multi-layered anode active material layer is formed,
wherein the second anode active material has a lower press density and a larger average particle diameter than the first anode material, and
wherein the first anode active material and the second anode active material each comprises crystalline carbon, amorphous carbon or a mixture thereof.
3. The method of claim 1 , wherein porosity of the second anode active material layer is relatively higher than porosity of the first anode active material layer.
4. The method of claim 3 , wherein a ratio of the porosity of the first anode active material layer to the porosity of the second anode active material layer before press is in a range of 5:5.1 to 4:6.
5. The method of claim 3 , wherein a ratio of the porosity of the first anode active material layer to the porosity of the second anode active material layer after press is in a range of 5:5.1 to 2:8.
6. The method of claim 1 , wherein a ratio of the average particle diameter of the first anode active material to the average particle diameter of the second anode active material is in a range of 1:9 to 5:5.1.
7. The method of claim 1 , wherein a ratio of the press density of the first anode active material to the press density of the second anode active material is in a range of 1.1:1 to 3:1 under a pressure of 12 MPa to 16 MPa.
8. The method of claim 1 , wherein a ratio of compressive strength of the first anode active material to compressive strength of the second anode active material is in a range of 2:8 to 5:5.1 under a pressure of 12 MPa to 16 MPa.
9. The method of claim 2 , wherein porosity of the second anode active material layer is relatively higher than porosity of the first anode active material layer.
10. The method of claim 9 , wherein a ratio of the porosity of the first anode active material layer to the porosity of the second anode active material layer before press is in a range of 5:5.1 to 4:6.
11. The method of claim 9 , wherein a ratio of the porosity of the first anode active material layer to the porosity of the second anode active material layer after press is in a range of 5:5.1 to 2:8.
12. The method of claim 2 , wherein a ratio of the average particle diameter of the first anode active material to the average particle diameter of the second anode active material is in a range of 1:9 to 5:5.1.
13. The method of claim 2 , wherein a ratio of the press density of the first anode active material to the press density of the second anode active material is in a range of 1.1:1 to 3:1 under a pressure of 12 MPa to 16 MPa.
14. The method of claim 2 , wherein a ratio of compressive strength of the first anode active material to compressive strength of the second anode active material is in a range of 2:8 to 5:5.1 under a pressure of 12 MPa to 16 MPa.