IP Library Granted Patent US 9,926,224
Granted Patent B2
US 9,926,224 · App. 15/407,124 · Granted Mar 27, 2018

Inorganic fiber with improved shrinkage and strength

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Quick Facts
Patent No.
US 9,926,224
App. No.
15/407,124
Granted
Mar 27, 2018
Kind
B2
Abstract

An inorganic fiber containing silica and magnesia as the major fiber components which further includes an intended strontium oxide additive to improve the thermal stability of the fiber. The inorganic fiber exhibits good thermal performance at 1260° C. and greater for 24 hours or more, retains mechanical integrity after exposure to the use temperature, and exhibits low biopersistence in physiological fluids. Also provided are thermal insulation product forms, methods of preparing the inorganic fiber and of thermally insulating articles using thermal insulation prepared from a plurality of the inorganic fibers.

Claims (22)

1. An inorganic fiber comprising a fiberization product of about 65 to less than 70 weight percent silica, about 14 to about 34 weight percent magnesia, and about 1 to about 5 weight percent strontium oxide.

2. The inorganic fiber of claim 1 , wherein said inorganic fiber comprises the fiberization product of about 65 to less than 70 weight percent silica, about 14 to about 34 weight percent magnesia, and about 2 to about 5 weight percent strontium oxide.

3. The inorganic fiber of claim 1 , wherein said inorganic fiber comprises the fiberization product of about 65 to less than 70 weight percent silica, about 14 to about 34 weight percent magnesia, and about 3 to about 5 weight percent strontium oxide.

4. The inorganic fiber of claim 1 , wherein said inorganic fiber comprises the fiberization product of about 65 to less than 70 weight percent silica, about 14 to about 34 weight percent magnesia, and about 4 to about 5 weight percent strontium oxide.

5. The inorganic fiber of claim 1 , wherein said inorganic fiber comprises the fiberization product of about 65 to less than 70 weight percent silica, about 16 to about 25 weight percent magnesia, and about 1 to about 4 weight percent strontium oxide.

6. The inorganic fiber of claim 1 , wherein said inorganic fiber comprises the fiberization product of about 65 to less than 70 weight percent silica, about 16 to about 25 weight percent magnesia, and about 1 to about 3 weight percent strontium oxide.

7. The inorganic fiber of claim 1 , wherein said inorganic fiber comprises the fiberization product of about 65 to less than 70 weight percent silica, about 16 to about 25 weight percent magnesia, and about 1 to about 2 weight percent strontium oxide.

8. The inorganic fiber of claim 1 , wherein said inorganic fiber comprises the fiberization product of about 65 to less than 70 weight percent silica, about 16 to about 25 weight percent magnesia, and about 1 to about 1 weight percent strontium oxide.

9. The inorganic fiber of claim 1 , wherein said inorganic fiber comprises the fiberization product of about 65 to less than 70 weight percent silica, about 17 to about 21 weight percent magnesia, and about 1 to about 4 weight percent strontium oxide.

10. The inorganic fiber of claim 1 , wherein said inorganic fiber comprises the fiberization product of about 65 to less than 70 weight percent silica, about 17 to about 21 weight percent magnesia, and about 1 to about 3 weight percent strontium oxide.

11. The inorganic fiber of claim 1 , wherein said inorganic fiber comprises the fiberization product of about 65 to less than 70 weight percent silica, about 17 to about 21 weight percent magnesia, and about 1 to about 2 weight percent strontium oxide.

12. The inorganic fiber of claim 1 , wherein said inorganic fiber comprises the fiberization product of about 65 to less than 70 weight percent silica, about 17 to about 21 weight percent magnesia, and about 1 to about 1 weight percent strontium oxide.

13. The inorganic fiber of claim 1 , wherein said inorganic fiber comprises greater than 0 to about 11 weight percent zirconia.

14. The inorganic fiber of claim 1 , wherein said inorganic fiber comprises 1 weight percent or less iron oxide, measured as Fe 2 O 3 .

15. The inorganic fiber of claim 1 , wherein said inorganic fiber comprises substantially no alkali metal oxide.

16. The inorganic fiber of claim 1 , wherein said inorganic fiber has an average diameter of greater than 2 microns.

17. The inorganic fiber of claim 1 , wherein said inorganic fiber exhibits a shrinkage of about 10% or less at 1260° C. for 24 hours.

18. The inorganic fiber of claim 1 , wherein said inorganic fiber exhibits a shrinkage of about 5% or less at 1260° C. for 24 hours.

19. The inorganic fiber of claim 1 , wherein said inorganic fiber exhibits a shrinkage of about 10% or less at 1400° C. for 24 hours.

20. The inorganic fiber of claim 1 , wherein said inorganic fiber exhibits a shrinkage of about 5% or less at 1400° C. for 24 hours.

21. A method of insulating an article at 1400° C. or greater, including disposing on, in, near or around the article, a thermal insulation material, said insulation material comprising a plurality of inorganic fibers comprising the fiberization product of claim 1 .

22. An inorganic fiber containing article comprising at least one of bulk fiber, blankets, blocks, boards, caulking compositions, cement compositions, coatings, felts, mats, moldable compositions, modules, papers, pumpable compositions, putty compositions, sheets, tamping mixtures, vacuum cast shapes, vacuum cast forms, or woven textiles, braids, cloths, fabrics, ropes, tapes, sleeving, wicking, said inorganic fiber containing article comprises a plurality of inorganic fibers comprising the fiberization product of claim 1 .

Assignments (12)
RELEASE OF FIRST LIEN SECURITY INTEREST IN PATENT COLLATERAL AT REEL/FRAME NO. 47909/0937 Recorded Oct 2, 2024
From: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT
To: UNIFRAX I LLC
Reel/Frame 069103/0582 →
FIRST LIEN PATENT SECURITY AGREEMENT Recorded Oct 2, 2024
From: LYDALL PERFORMANCE MATERIALS (US), INC.; LYDALL INC.; REFRACTORY SPECIALTIES, INCORPORATED; SOUTHERN FELT COMPANY, INC.; UNIFRAX I LLC; STELLAR MATERIALS
To: WILMINGTON SAVINGS FUND SOCIETY, FSB, AS COLLATERAL AGENT
Reel/Frame 069091/0735 →
SECOND LIEN TRADEMARK SECURITY AGREEMENT Recorded Oct 2, 2024
From: LYDALL PERFORMANCE MATERIALS (US), INC.; LYDALL INC.; REFRACTORY SPECIALTIES, INCORPORATED; SOUTHERN FELT COMPANY, INC.; UNIFRAX I LLC; STELLAR MATERIALS
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS SECOND LIEN NOTES COLLATERAL AGENT
Reel/Frame 069091/0923 →
SECURITY INTEREST Recorded Oct 15, 2021
From: LYDALL, INC.; SOUTHERN FELT COMPANY, INC.; LYDALL PERFORMANCE MATERIALS (US), INC.
To: WILMINGTON TRUST
Reel/Frame 057826/0962 →
RELEASE OF SECURITY INTEREST IN PATENT COLLATERAL AT REEL/FRAME NO. 49014/0755 Recorded Oct 4, 2021
From: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT
To: UNIFRAX I LLC
Reel/Frame 057710/0669 →
RELEASE OF SECOND LIEN SECURITY INTEREST RECORDED AT REEL 044393, FRAME 0273 Recorded Dec 17, 2018
From: GOLDMAN SACHS LENDING PARTNERS LLC
To: UNIFRAX I LLC
Reel/Frame 047940/0758 →
RELEASE OF FIRST LIEN SECURITY INTEREST RECORDED AT REEL 042166, FRAME 0201 Recorded Dec 15, 2018
From: GOLDMAN SACHS LENDING PARTNERS LLC
To: UNIFRAX I LLC
Reel/Frame 048919/0384 →
FIRST LIEN PATENT SECURITY AGREEMENT Recorded Dec 14, 2018
From: UNIFRAX I LLC
To: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT
Reel/Frame 047909/0937 →
SECOND LIEN PATENT SECURITY AGREEMENT Recorded Dec 14, 2018
From: UNIFRAX I LLC
To: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT
Reel/Frame 049014/0755 →
SECURITY INTEREST Recorded Nov 7, 2017
From: UNIFRAX I LLC
To: GOLDMAN SACHS LENDING PARTNERS LLC, AS COLLATERAL AGENT
Reel/Frame 044393/0273 →
SECURITY INTEREST Recorded Apr 5, 2017
From: UNIFRAX I LLC
To: GOLDMAN SACHS LENDING PARTNERS LLC
Reel/Frame 042166/0201 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 16, 2017
From: ZHAO, DONGHUI; ZOITOS, BRUCE K.; ANDREJCAK, MICHAEL J.; HAMILTON, JASON M.
To: UNIFRAX I LLC
Reel/Frame 040977/0746 →