Resilient flow structures for electrochemical cell
View Patent ↗An electrochemical cell is disclosed comprising, a first flow structure, a second flow structure, and a membrane electrode assembly disposed between the first and second flow structures. The electrochemical cell further comprises a pair of bipolar plates, wherein the first flow structure, the second flow structure, and the membrane electrode assembly are positioned between the pair of bipolar plates. The electrochemical cell also includes a spring mechanism, wherein the spring mechanism is disposed between the first flow structure and the bipolar plate adjacent to the first flow structure, and applies a pressure on the first flow structure in a direction substantially toward the membrane electrode assembly.
1. A method of operation for an electrochemical cell comprising:
compressing a first flow structure from a first position to a second position different from the first position, wherein the first flow structure remains substantially in contact with a membrane electrode assembly during transition from the first position to the second position; wherein
during the transition from the first position to the second position a second flow structure on the opposite side of the membrane electrode assembly remains substantially in contact with the membrane electrode assembly; and
pressurizing the first flow structure causes the transition of the first flow structure from the first position to the second position and creates a differential pressure across the membrane electrode assembly;
wherein the first flow structure is constructed of a material having a lower elastic modulus than the second flow structure and a length of the first flow structure is greater than a length of the second flow structure with the length of the first flow structure and the length of the second flow structure is measured along the longitudinal axis.
2. The method according to claim 1 , wherein a cell resistance measurement for the electrochemical cell when operating at a differential pressure up to 14,000 psi is less than 6 times a cell resistance measurement for the electrochemical cell when operating at 0 psi differential pressure.
3. The method according to claim 1 , wherein the second flow structure has a stiffness greater than the first flow structure.
4. The method according to claim 1 , wherein a stiffness of the first flow structure and the second flow structure is measured in a direction substantially parallel to a longitudinal axis running from a center of the first flow structure to a center of the second flow structure.
5. The method according to claim 1 , wherein the first flow structure includes at least two layers of material, and at least one of the at least two layers of material has a stiffness less than that of the second flow structure material.
6. The method according to claim 5 , wherein the at least one second layer has a length greater than the second flow structure or an elastic modulus less than that of the second flow structure.
7. The method according to claim 1 , wherein the first flow structure is on a cathode side of the electrochemical cell and the second flow structure is on an anode side of the electrochemical cell.
8. The method according to claim 1 , wherein the first flow structure comprises at least one of steel wool, a metallic foam, and a wool made of carbon fiber.
9. A method of operation for an electrochemical cell comprising:
compressing a first flow structure from a first position to a second position different from the first position, wherein the first flow structure remains substantially in contact with a membrane electrode assembly during transition from the first position to the second position; wherein
during the transition from the first position to the second position a second flow structure on the opposite side of the membrane electrode assembly remains substantially in contact with the membrane electrode assembly; and
pressurizing the first flow structure causes the transition of the first flow structure from the first position to the second position and creates a differential pressure across the membrane electrode assembly;
wherein the first flow structure includes at least two layers of material, and at least one of the at least two layers of material has a stiffness less than that of the second flow structure material.
10. The method according to claim 9 , wherein the at least one second layer has a length greater than the second flow structure or an elastic modulus less than that of the second flow structure.
11. The method according to claim 9 , wherein the first flow structure is on a cathode side of the electrochemical cell and the second flow structure is on an anode side of the electrochemical cell.
12. The method according to claim 9 , wherein the first flow structure comprises at least one of steel wool, a metallic foam, and a wool made of carbon fiber.
13. A method of operation for an electrochemical cell comprising:
compressing a first flow structure from a first position to a second position different from the first position, wherein the first flow structure remains substantially in contact with a membrane electrode assembly during transition from the first position to the second position; wherein
during the transition from the first position to the second position a second flow structure on the opposite side of the membrane electrode assembly remains substantially in contact with the membrane electrode assembly; and
pressurizing the first flow structure causes the transition of the first flow structure from the first position to the second position and creates a differential pressure across the membrane electrode assembly;
wherein the first flow structure comprises at least one of steel wool, a metallic foam, and a wool made of carbon fiber.
14. The method according to claim 13 , wherein the at least one second layer has a length greater than the second flow structure or an elastic modulus less than that of the second flow structure.
15. The method according to claim 13 , wherein the first flow structure is on a cathode side of the electrochemical cell and the second flow structure is on an anode side of the electrochemical cell.