Methods of forming composite material films
Silicon particles for active materials and electro-chemical cells are provided. The active materials comprising silicon particles described herein can be utilized as an electrode material for a battery. In certain embodiments, the composite material includes greater than 0% and less than about 90% by weight of silicon particles. The silicon particles have an average particle size between about 0.1 μm and about 30 μm and a surface including nanometer-sized features. The composite material also includes greater than 0% and less than about 90% by weight of one or more types of carbon phases. At least one of the one or more types of carbon phases is a substantially continuous phase.
1. A method of forming a composite material film, the method comprising:
providing a mixture comprising a precursor and silicon particles; and
pyrolysing the mixture to convert the precursor into one or more types of carbon phases to form the composite material film, wherein at least one of the one or more types of carbon phases comprises hard carbon and is a continuous phase that holds the composite material film together such that the silicon particles are distributed throughout the composite material film, wherein the composite material film comprises silicon carbide between the silicon particles and the hard carbon, and wherein the composite material film is self-supported.
2. The method of claim 1 , further comprising:
casting the mixture on a substrate;
drying the mixture;
removing the dried mixture from the substrate; and
placing the dried mixture in a hot press.
3. The method of claim 1 , wherein providing the mixture comprises providing a mixture comprising greater than 0% to about 90% by weight of the silicon particles, and about 5% to about 80% by weight of the precursor.
4. The method of claim 1 , wherein providing the mixture further comprises providing conductive particles in the mixture.
5. The method of claim 1 , wherein providing the mixture further comprises providing metal particles in the mixture.
6. The method of claim 1 , wherein the silicon particles are homogeneously distributed throughout the composite material film.
7. The method of claim 1 , wherein the silicon particles are in contact with the continuous phase.
8. The method of claim 1 , wherein the silicon particles have an average largest dimension of 10 nm to 40 μm.
9. The method of claim 1 , wherein the at least one of the one or more types of carbon phases that is a continuous phase is electrochemically active and electrically conductive.
10. The method of claim 1 , wherein the one or more types of carbon phases comprises graphite particles.
11. The method of claim 1 , wherein the composite material film is electrochemically active.
12. The method of claim 1 , wherein the composite material film comprises the silicon particles at about 50% to about 90% by weight.