IP Library Granted Patent US 10,344,199
Granted Patent B2
US 10,344,199 · App. 15/415,539 · Granted Jul 9, 2019

Well treatment methods and compositions

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Quick Facts
Patent No.
US 10,344,199
App. No.
15/415,539
Granted
Jul 9, 2019
Kind
B2
Abstract

Provided herein are methods and compositions for treatment of a subterranean wellbore that has become clogged with sludge deposits comprising a synthetic polymer and an oil tar.

Claims (17)

1. A method of restoring the permeability of a wellbore or underground formation wherein the permeability of the wellbore or underground formation has become impeded by sludge comprising a tar deposit or a combination of a tar deposit and a gelled synthetic polymer, the method comprising:

a) introducing an aqueous composition comprising an oxidizer, wherein the oxidizer is hydrogen peroxide or carbamide peroxide, a chelated metal activator, a surfactant selected from the group consisting of ethoxylated castor oil, ethoxylated fatty acids, alcohol sulfates, alcohol ethoxylates, amine N-oxides or a combination thereof, and a stabilizer wherein the stabilizer is urea or citric acid, into the wellbore or underground formation; and

b) contacting the sludge comprising the tar deposit or the combination of a tar deposit and a gelled synthetic polymer, with the aqueous composition for up to about 24 hours to dissolve or substantially dissolve the sludge without the formation of a precipitate, thereby restoring the permeability of the well bore or underground formation.

2. The method of claim 1 , wherein the subterranean environment comprises a geological formation.

3. The method of claim 1 , wherein the oxidizer is hydrogen peroxide.

4. The method of claim 1 , wherein the oxidizer is carbamide peroxide.

5. The method of claim 1 , wherein the oxidizer concentration in the well treatment composition is from about 500 ppm to about 25,000 ppm.

6. The method of claim 1 , wherein the chelated metal activator is selected from the group consisting of FeEDTA, FeDTPA, ferric citrate, ferrous citrate, ferrous isocitrate, ferrous aconitate, ferrous salicylate, zinc gluconate, ferrous lactate, and ferrous gluconate.

7. The method of claim 1 , wherein the aqueous composition further comprises a biocide.

8. The method of claim 1 , wherein the surfactant comprises a mixture of two or more of ethoxylated castor oil, ethoxylated fatty acids, D-limonene, alcohol sulfates, alcohol ethoxylates, or amine N-oxides.

9. The method of claim 1 , wherein the stabilizer is urea.

10. The method of claim 1 , wherein the stabilizer is citric acid.

11. The method of claim 1 , wherein the aqueous composition further comprises a co-solvent selected from the group consisting of methanol, isopropanol, and a mixture of methanol and isopropanol.

12. The method of claim 1 , wherein the sludge is deposited on the surface of the wellbore, filters, or drilling equipment.

13. The method of claim 1 , wherein the surfactant concentration in the well treatment composition is from about 0.5% to about 5%.

14. The method of claim 1 , wherein the surfactant concentration in the well treatment composition is from about 0.5% to about 1%.

15. the method of claim 1 , wherein the pH of the aqueous composition is neutral or alkaline.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 17, 2021
From: PEROXYCHEM LLC
To: EVONIK OPERATIONS GMBH
Reel/Frame 055625/0023 →
RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT R/F 050605/0305 Recorded Feb 3, 2020
From: BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT
To: PEROXYCHEM LLC
Reel/Frame 051777/0957 →
SECURITY INTEREST Recorded Oct 2, 2019
From: PEROXYCHEM LLC
To: BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT
Reel/Frame 050605/0305 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 28, 2018
From: PISANOVA, ELENA; ROVISON, JOHN M.
To: PEROXYCHEM LLC
Reel/Frame 046718/0903 →