Vacuum insulating glass (VIG) unit with lead-free dual-frit seals and/or methods of making the same
View Patent ↗Certain example embodiments of this invention relate to vacuum insulating glass (VIG) units having improved seals made using two different frit-based edge seal materials, and/or methods of making the same. In certain example embodiments, a first frit material is applied around peripheral edges of first and second glass substrates. The first frit material, which may be bismuth-based in certain example embodiments, is fired with a heat treatment (e.g., thermal tempering) process. A second frit material, which may be VBZ-based in certain example embodiments, is applied and at least partially overlaps with the fired first frit material. The first frit material acts as a primer, and the second frit material helps seal together the VIG unit. The second frit material is fired at a significantly lower temperature that enables the glass to retain the temper or other strength imparted by the heat treatment.
1. A vacuum insulating glass (VIG) unit, comprising:
first and second substantially parallel, spaced apart glass substrates;
a plurality of spacers disposed between the first and second substrates;
an edge seal provided around the periphery of the first and/or second substrates, the first and second substrates, together with the edge seal, defining a cavity therebetween, the cavity being at a pressure less than atmospheric pressure; and
wherein the edge seal is an hermetic seal comprising both a first frit material that is a bismuth oxide based frit material, and a second frit material that is a vanadium oxide based frit material, bismuth oxide and vanadium oxide being the largest components of the first and second frit materials, respectively.
2. The VIG unit of claim 1 , wherein at least one of the first and second glass substrates is thermally tempered.
3. The VIG unit of claim 1 , wherein the first frit material comprises at least 65% bismuth oxide, by weight.
4. The VIG unit of claim 3 , wherein the first frit material comprises 70-80 wt. % bismuth oxide, 2-7 wt. % zinc oxide, 5-15 wt. % silicon oxide, 2-7 wt. % aluminum oxide.
5. The VIG unit of claim 1 , wherein the second frit material comprises vanadium oxide, barium oxide, and zinc oxide, in amounts that total at least 65% by weight.
6. The VIG unit of claim 1 , wherein the second frit material comprises 45-67 wt. % vanadium oxide, 7-25 wt. % barium oxide, and 4-17 wt. % zinc oxide.