Cure accelerators for anaerobic curable compositions

1. An anaerobic curable composition comprising

(a) a (meth) acrylate component;

(b) an anaerobic cure-inducing composition; and

(c) an aromatic amide shown in structure I

wherein R and R″ are each independently C 1-10 alkyl, and R′ is H or C 1-10 alkyl, or R and R′ together form a four to seven membered ring fused to the benzene ring, and wherein R′″ is optional, but when R′″ is present, R′″ is halogen, alkyl, alkenyl, cycloalkyl, hydroxyalkyl, hydroxyalkenyl, alkoxy, amino, alkylene- or alkenylene-ether, alkylene (meth) acrylate, carbonyl, carboxyl, nitroso, sulfonate, hydroxyl or haloalkyl.

2. The composition according to claim 1 , wherein the anaerobic cure-inducing composition comprises a hydroperoxide selected from the group consisting of cumene hydroperoxide, para-menthane hydroperoxide, t-butyl hydroperoxide, t-butyl perbenzoate, benzoyl peroxide, dibenzoyl peroxide, 1,3-bis(t-butylperoxyisopropyl)benzene, diacetyl peroxide, butyl 4,4-bis(t-butylperoxy)valerate, p-chlorobenzoyl peroxide, t-butyl cumyl peroxide, t-butyl perbenzoate, di-t-butyl peroxide, dicumyl peroxide, 2,5-dimethyl-2,5-di-t-butylperoxyhexane, 2,5-dimethyl-2,5-di-t-butyl-peroxyhex-3-yne, 4-methyl-2,2-di-t-butylperoxypentane, t-amyl hydroperoxide, 1,2,3,4-tertramethylbutyl hydroperoxide and combinations thereof.

3. The composition according to claim 1 , further comprising at least one accelerator.

4. The composition according to claim 3 , wherein the accelerator is selected from the group consisting of amines, amine oxides, sulfimides, metals and sources thereof, acids, and mixtures thereof.

5. The composition according to claim 3 , wherein the accelerator is selected from the group consisting of triazines, ethanolamine, diethanolamine, triethanolamine, N,N-dimethyl aniline, benzene sulphonimide, cyclohexyl amine, triethyl amine, butyl amine, saccharin, N,N-diethyl-p-toluidine, N,N-dimethyl-o-toluidine, and acetyl phenylhydrazine with maleic acid, and mixtures thereof.

6. The composition according to claim 1 , further comprising at least one stabilizer.

7. The composition according to claim 6 , wherein the stabilizer is selected from the group consisting of benzoquinone, naphthoquinone, anthraquinone, hydroquinone, methoxyhydroquinone, butylated hydroxy toluene, ethylene diamine tetraacetic acid or a salt thereof, and mixtures thereof.

8. A method of using as a cure accelerator for anaerobic curable compositions an aromatic amide shown in structure I:

wherein R and R″ are each independently C 1-10 alkyl, and R′ is H or C 1-10 alkyl or R and R′ together may form a four to seven membered ring fused to the benzene ring, and wherein R′″ is optional, but when R′″ is present, R′″ is halogen, alkyl, alkenyl, cycloalkyl, hydroxyalkyl, hydroxyalkenyl, alkoxy, amino, alkylene- or alkenylene-ether, alkylene (meth)acrylate, carbonyl, carboxyl, nitroso, sulfonate, hydroxyl or haloalkyl, comprising the steps of:

(a) providing an anaerobic curable composition comprising a (meth)acrylate component and an anaerobic cure-inducing composition;

(b) providing as a cure accelerator for the anaerobic curable composition an aromatic amide shown in structure I:

wherein R and R″ are each independently C 1-10 alkyl, and R′ is H or C 1-10 alkyl or R and R′ together may form a four to seven membered ring fused to the benzene ring, and wherein R′″ is optional, but when R′″ is present, R′″ is halogen, alkyl, alkenyl, cycloalkyl, hydroxyalkyl, hydroxyalkenyl, alkoxy, amino, alkylene- or alkenylene-ether, alkylene (meth)acrylate, carbonyl, carboxyl, nitroso, sulfonate, hydroxyl or haloalkyl; and

(c) exposing the anaerobic curable composition and the cure accelerator to conditions favorable to cure the composition.

9. The composition of claim 1 , wherein the aromatic amide shown in structure I is elected from N-acetyl tetrahydroquinoline, N-acetyl indoline or N-acetyl, N-methyl aniline.