Magnetic recording medium using ϵ-iron oxide particle magnetic powder
View Patent ↗A magnetic recording medium of the present invention includes a non-magnetic substrate, and a magnetic layer containing a magnetic powder. The magnetic powder is constituted by an ε-iron oxide powder. The magnetic layer has a squareness in a thickness direction of 0.65 or more. In a differential curve obtained by differentiating a hysteresis curve in the thickness direction of the magnetic layer, two or more peaks are present. In a case where, out of peaks in the same direction among the above-described peaks, a local maximum of a largest peak in a magnetic field range of +500 oersted [Oe] or more is taken as P 1 and a local maximum of a largest peak in a magnetic field range of −500 oersted [Oe] or more and less than +500 oersted [Oe] is taken as P 2 , a relationship below is satisfied: 0.25≤ P 2/ P 1≤0.60.
1. A magnetic recording medium, comprising a non-magnetic substrate, and a magnetic layer containing a magnetic powder,
wherein the magnetic powder is constituted by an ε-iron oxide powder,
the magnetic layer has a squareness in a thickness direction of 0.65 or more,
the ε-iron oxide powder comprises a high-coercivity magnetic powder having a large particle size and a low-coercivity magnetic powder having a small particle size, and voids between particles of the high-coercivity magnetic powder having a large particle size are filled with particles of the low-coercivity magnetic powder having a small particle size,
in a hysteresis curve in the thickness direction of the magnetic layer, in a case where a point at which, after saturation magnetization in a positive direction is reached by applying a magnetic field in the positive direction to the magnetic layer, saturation magnetization in a direction (negative direction) opposite to the positive direction is reached by applying a magnetic field in the opposite direction (negative direction) is taken as a point A, and a point at which saturation magnetization in the positive direction is reached by applying a magnetic field in the positive direction further from the point A is taken as a point B, two or more peaks are present in a differential curve obtained by differentiating the hysteresis curve from the point A to the point B, and
in a case where, out of the peaks, a local maximum of a largest peak in a magnetic field range of +500 oersted [Oe] or more is taken as P 1 and a local maximum of a largest peak in a magnetic field range of −500 oersted [Oe] or more and less than +500 oersted [Oe] is taken as P 2 , a relationship below is satisfied:
0.25≤ P 2/ P 1≤0.60.
2. The magnetic recording medium according to claim 1 , wherein the magnetic powder has an average particle size of 8 nm or more and 20 nm or less.
3. The magnetic recording medium according to claim 1 , wherein spacing of a surface of the magnetic layer measured using a TSA (tape spacing analyzer) after the surface of the magnetic layer has been washed with n-hexane is 5 nm or more and 15 nm or less.
4. The magnetic recording medium according to claim 1 , further comprising a lubricant layer containing a fluorine-based lubricant or a silicone-based lubricant, on a surface of the magnetic layer.
5. The magnetic recording medium according to claim 1 , wherein the magnetic layer has a thickness of 30 nm or more and 200 nm or less.
6. The magnetic recording medium according to claim 1 , wherein the high-coercivity magnetic powder having a large particle size has a particle size of 8 nm or more and 20 nm or less, and the low-coercivity magnetic powder having a small particle size has a particle size of less than 8 nm.